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Intermolecular forces
Covalent bonds are not affected when a molecular substance boils
Intermolecular forces of attraction between molecules are weaker than covalent bonds and are easily overcome
Van der Waals forces
Random electron movement means electron density is not evenly distributed forming a dipole on one side
This induces a dipole in another molecule
The delta+ and delta- attract
Permanent dipole-dipole interactions
If two molecules are polar the delta+ region of one is attracted to the delta- region of the other
Hydrogen bonding
Hydrogen bonds only form with fluoride, oxygen or nitrogen
Lone pair on electronegative atom forms bonds hydrogen atom of another molecule
→ Strongest intermolecular force