Organic Chemistry - Alkyne Reactions

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14 Terms

1
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Vicinal Elimination

1) xs NaNH2

2) H2O

<p>1) xs NaNH2</p><p>2) H2O</p>
2
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Geminal Elimination

1) xs NaNH2

2) H2O

<p>1) xs NaNH2</p><p>2) H2O</p>
3
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Hydrohalogenation (two equivalents)

xs HX

<p>xs HX</p>
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Hydrohalogenation (one equivalent)

HX

<p>HX</p>
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Acid-Catalyzed Hydration

H2SO4, H2O

(Hint: Methyl Ketone)

<p>H2SO4, H2O</p><p>(Hint: Methyl Ketone)</p>
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Hydroboration-Oxidation

1) R2BH

2)H2O2, NaOH

(Hint: Aldehyde)

<p>1) R2BH</p><p>2)H2O2, NaOH</p><p>(Hint: Aldehyde)</p>
7
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Halogenation (one equivalent)

X2 (One Equivalent)

CCl4

<p>X2 (One Equivalent)</p><p>CCl4</p>
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Halogenation (two equivalents)

Excess X2

CCl4

<p>Excess X2</p><p>CCl4</p>
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Ozonolysis

1) O3

2) H2O

(First One - Terminal Alkyne)

<p>1) O3</p><p>2) H2O</p><p>(First One - Terminal Alkyne)</p>
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Alkylation

1) NaNH2

2) RX

<p>1) NaNH2</p><p>2) RX</p>
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Dissolving Metal Reduction

Na, NH3 (l)

<p>Na, NH3 (l)</p>
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Hydrogenation

H2

Pt

<p>H2</p><p>Pt</p>
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Hydrogenation with a poisoned catalyst

H2

Lindlar's catalyst

<p>H2</p><p>Lindlar's catalyst</p>
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Lindlar's Catalyst