optical isomerism

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11 Terms

1
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what are stereoisomers

same structural formula, different spatial arrangement

2
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why do E/Z isomers have restricted rotation

because of a double bond

3
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what is a chiral carbon

carbon that has 4 different groups attached

<p>carbon that has 4 different groups attached </p>
4
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what are optical isomers

non-superimposable mirror images

5
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how does plane-polarised light rotate

only in one direction

vertically, horizontally or anything in between

6
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difference between normal light and plane polarised light

normal light roattes in all directions

plane-polarised light roattes only in one

7
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what can optical isomers do to be able to call them optically active

rotate plane polarised light

8
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in what direction do 2 enantiomers rotate plane-polarised light

in opposite directions

9
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define racemic mixture

contains equal quantities (50:50) of each enantiomer of an optically active compound

10
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why do racemates not show any optical activity

2 enantiomers cancel each out other light-rotating effect

11
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why is racemic mixture 50:50 of each enantiomer

when 2 molecules react there is an equal chance of a bond both above and beyond the planar