Organic Chemistry II: Quiz 3 Reactions

KETO-ENOL TAUTOMERISM (BASIC)

-OH (DEPROTANATE TO PROTANATE)

KETO-ENOL TAUTOMERISM (ACIDIC)

H3O+ (PROTANATE TO DEPROTANATE)

ALPHA-HALOGENATION

BASE OR ACID + X2 (I.E BR2)

HALOFORM REACTION

EXCESS X2 + NAOH (OCCURS UNTIL THERE ARE NO ACIDIC PROTONS)

ALDOL ADDITION

BASE OR ACID = -OH GROUP (1-ATTACKING, 2-ALPHA CARBON, 3-ATTACKED)

ALDOL CONDENSATION

BASE OR ACID + HEAT = ALKENE (1-ATTACKING, 2-ALPHA CARBON, 3-ATTACKED)

MIXED ALDOL

NAOH = 4 DIFFERENT PRODUCTS (DEPENDENT ON CONCENTRATION OF ATTACKING AND ATTACKED MOLECULES)

INTRAMOLECULAR ALDOL

NAOH = RING (1ST ALPHA ATTACKS CARBONYL WITHIN SAME MOLECULE)

CLAISEN CONDENSATION

RO (1-KEEPS ESTER, 2-NEW BOND, 3-KETONE+LG)

MICHAEL REACTION

MICHAEL DONOR (NUCLEOPHILE: ENOLATE) + MICHAEL ACCEPTER (ALPHA-BETA UNSAT)

STORK ENAMINE REACTION

NR2 + (THF, H30+)

ELECTROPHILIC ADDITION REACTION

H-BR

DIELS-ALDER CYCLO ADDITION REACTION

TOLUNE + HEAT = RING + KETONE