forces acting between molecules

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3 types of intermolecular forces (weakest to strongest)


  1. Van der Waals- act between all atoms and molecules

  2. Dipole-dipole- certain molecules

  3. Hydrogen bonding- certain molecules


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When does dipole-dipole happen

When molecules are polar

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Van der waals

Temporary dipole-dipole, it increase when more number of e-

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How does van der Waals forces work

Electrons move rapidly and randomly in a molecule

This causes a temporary dipole in a molecule (A)

This repels electrons in a neighbors (B)

This causes B to have a temporary dipole

Molecule A and B now attract FOR an instant

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The strength of van der waals depend on

No of e-

Shape

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For hydrogen bonding to be present it must bond directly to

N,O or F

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Explain what happens in hydrogen bonding

The polar bond between the H and the N/O/F leaves the H nucleus exposed as H only has one electron. Therefore there is a strong attraction from the lone pair on the N/O/F of one molecule to the exposed H nucleus of another molecules. This is simply a strong intermolecular force- it is NOT a bond.