SN1, SN2, E1, and E2 Reaction Mechanisms

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4 Terms

1
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Weakly Basic Nucleophiles Pka=0-15 (I-, Br-, Cl-, N3, RS-, PR3,

R-CO2)

1/2° —> SN2

3° —> SN1/E1

2
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Weak Nucleophiles Pka<0 (H2O, CH3OH, CH3SH, RCO2)

1° —> N.R.

2/3° —>SN1/E1

3
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Strongly Basic Nucleophiles Pka>15 (-OH, CH3O-, -NH2, etc.)

1° —> SN2

2/3° —> E2

4
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Strong but Bulky Base Ex. C(CH3)3O-

1/2/3° —> E2