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types of potential energy
gravitational - higher is more
chemical - energy stored in the bonds
kinetic energy types
thermal - moving molecules
motion - moving something gives it kinetic energy
laws of thermodynamics
energy is conserved not lost or gained
direction of change which way does stuff go naturally (eg. order to disorder)
gibbs free energy
under conditions of constant pressure and temperature
delta S is entropy
reaction wants to move in the direction of positive entropy so that the product has a lower potential energy than the starting point
disorder is favorable
enthalpy
change in potential energy
gibbs free energy measures whether a reaction is favorable
reactions are favorable when delta G is less than zero
favorable conditions
negative delta G
positive delta S
negative delta H
exergonic
negative delta G is lost by the system into its surroundings
endergonic
positive delta G energy is gained (products have more energy than reactants)
homeostasis
balancing the stuff on the inside and outside
ATP phosphorylation
ATP breaks into ADP + phosphate group the energy released can be used to join together with other compounds
bond forms between reactants and phosphate
what doe the signs on S mean
positive s = disorder
negative s = order
cellular respiration requirements
ATp struggles to store energy long term
constantly have to remake ATP because it’s used constantly
ATP has a very low activation energy
diffusion
things travel from high concentration to low concentrations on both sides just because of how things moves randomly
equillibrium
once there are equal concentrations on both sides there is no net diffusion but equal concentrations still move from side to side
ficks law of diffusion
write out the equation
area - a
phigh-plow - difference in partial pressure
d - diffusion coefficient
l - diffusion length between two locations
mass flow
pull in loecules and then diffuse within the lungs
use of pigments in blood
optimize phigh-plow
pigments have a high affinity to oxygen
some organisms modify phigh-plow
endotherm
an organism that generates and regulates its own internal body heat rather than relying on the outside environment
ectotherm
organism that relies on external environment to regulate body temperature
homeothermy
type of regulation that keeps an organisms internal body temperature stable regardless of environmental temperature
poikilotherms
organism that has changing body tmeperature based on the environmental temperature
ecosystem
all organisms and abiotic pools of resources with which they interact
energy flux
movement of energy
energy transfer isn’t 100% efficient
10% of energy from previous level makes it to the next one
biomass goes in the shape of a pyramid (more to less)
r
population growth rate
b
births
d
deaths
N
individuals
delta N
change in population
delta T
change in time
+r versus -r
+r is exponential growth
-r is population decline
density dependent factors
competition for food and resources
factors impacted by population size
disease
hiding places/homes
density-independent factors
environmental, human-caused etc.
not influenced by population size
meanings of differnt r’s
r=0 is stable
r<0 is decline
r>0 is growth
K
carrying capacity
if N is greater than K the population will decrease until N is less than K
r-strategist
maximize the growth rate r by not controlling death rates and by maximizing birth rates
k-strategist
control or limit death rates maintain a viable population by not increasing b, but by reducing d among their offspring so a higher proportion make it to adulthood
niche
particular set of adaptations/ways in which an organism figures our how to live
ecological niche
the way an organism makes its living or the role it plays in the environment
range of tolerance
area where an organism can survive, but it’s not favorable
optimal range
certain areas are more optimal for an organism so they’re more likely to occupy this niche
± interaction
one party benefits and the other doesn’t
mutualism
both organisms benefit from organism interactions +/+
competition
to organisms compete for the same resource
resources to compete over
hiding space
space
food
water
exploitative competition
one organism takes all resources so it’s not available for the others
interference competition
organisms acively compete with each other and try to expel one another from the resource
how does energy coupling work
energetic coupling doesn’t violate the second law of thermodynamics because the overall delta G of the coupled system is negative
fundamental niche
species’ original niche
realized niche
species’ niche after ecological interactions (usually smaller)
inter-specific
between different species’
intra-specific
within a species
trophic cascade
when the top/bottom species population is impacted by one another
top-down
population at top impacts population at bottom
bottom-up
when the population at the bottom impacts the population at the top
endergonic reaction graph

exergonic reaction graph

ATP and substrate level phosphorylation
ATP breaks into ADP and phosphate group the energy released can be used to join together other compounds
bond forms between reactants and phosphate (the bond is high energy)
Free energy associated with ATP drops and free energy associated with the reactant increases
use of glucose in the body
sugar is broken into two 3 carbon sugars called pyruvate
takes place in mitochondria
2 ATP are spent and 4 are produced
bulk flow
transport of a substance over a large distance if an organism can’t use bulk flow, then it has to be smaller in order to keep the length of diffusion short enough to be efficient
tidal flow
air travels in both directions when there is tidal flow. this is a disadvantage when it comes to fick’s law because there is less of a concentration gradient so the amount of diffusion is less.
why is unidirectional flow a pre-req for counter current exchange
unidirectional flow is when air moves in one continuous direction through the system
this is a pre-requisite for countercurrent exchange because the blood has to flow in the opposite direction of the air in order for counter-current exchange to occur
how does counter current exchange increase the amount of air that can be taken from the environment
the concentration gradient remains constant across the entire capillary bed
concurrent flow
maximum of a 50% efficiency of diffusion
blood reaches equilibrium at 50% so diffusion stops
blood and air are flowing in the same direction
initial gas exchange when the concentration between the blood and the air is really different (makes this process really fast)
countercurrent flow
80-90% efficiency because the concentration gradient is maintained
the air and the blood flow in opposite directions
more complex structurally
purpose of the blood pigments
pigments attract and hold the oxygen
the concentration gradient is stronger because of the presence of blood pigments
how blood travels through the mammalian circulatory system
blood comes in from the superior and inferior vena cava
right atrium
tricuspid valve
right ventricle
pulmonary valve
pulmonary artery
lungs (capillaries)
pulmonary veins
left atrium
mitral valve
left ventricle
aortic valve
aorta
arteries
body capillaries
veins
inter-specific competition
competition between two different species
interference competition
organisms physically fight/display aggression/release chemicals signals in order to block others form the shared resources
exploitative competition
indirect interaction that cause the availability of the resource to be diminished
factors that allow competing species’ to avoid competitive exclusion
dividing resources
shifting their behaviors
environmental changes that reduce direct competition