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oligosaccharides functions in food
prebiotic
fructo = mild sweetness + improves mouthfeel
low caloric value
polysaccharides
starch (digestible) and fiber (non-digestible)
starch
digestible
made of glucose
sources = cereal grains, legumes, potatoes
break down in small intestine to be used as an energy source
thickeners and stabilizers
starch gelatinization
starch granules are heated, absorb water, and lose their crystalline structure (irreversible + forms pudding/custard when cooled)
dietary fiber
resist digestion in small intestine
cellulose = plant cell walls
hemicellulose
pectin = fruits + jam making
extends feeling of fullness
regulates blood glucose levels
improves digestion + regular bowel movement (gut health)
fermentation substrate
sources = fruits, vegetables, whole grains
water-holding + fat-binding
thickener, emulsifier, gelling agent
prebiotic + adds volume to food
ways to increase fiber intake
whole-grain breads, pastas, crackers, cookies
food with 3+ grams per serving
skin of fruit and vegetables
fruit over fruit juices
sprinkle ground flaxseed on food
limit white flower intake
proteins
polymers of amino acids
one or more polypeptide folding into a functional structure (3D)
second role = energy source
structural support of proteins
muscle, skin, hair, nails (collagen, keratin, actin)
enzymes
speed up chemical reactions
transport proteins
move substances across membranes
hormones
chemical messengers
insulin
regulates blood sugar levels
peptide bonds
crucial for forming primary structure of proteins
side chains
amino acid sequence (properties are key to protein folding)
determine chemical properties of amino acids
affect solubility and stability
contribute to proteins ability to bind to other molecules
formation of proteins
primary = linear polypeptide chain
secondary = helix, b-sheet
tertiary = 3D folding
quaternary = two or more tertiary structures assemble
9 essential amino acids (THose, HILLs, VALleys, and TRees are My Phevorite)
threonine
histidine
isoleucine
leucine
lysine
valine
tryptophan
methionine phenylalanine
phenylalanine
cysteine
when two link they form disulfide bonds and influence the texture of gluten (dough springiness)
monosodium glutamate (MSG)
enhances umami taste
not found in nature
salt from glutamic acid
produced through fermentation
protein denaturation
alternation of structure without breaking peptide bonds (unfolding)
changes in solubility, firmness, viscosity
“practically irreversible”
more digestible
emulsification, foaming, and gelling functions
hydrolysis of peptide bonds
peptide bonds are broken and amino acids are released
proteases
protein hydrolysis depending on temperature and pH
animal proteins (highly digestible)
meat (complete proteins)
milk + dairy (casein + whey)
eggs (egg whites = gold standard)
fish and seafood (omega-3)
plant proteins
legumes (fiber + minerals)
cereals (lower in protein)
soybeans + soy products = comparable to animal protein quality
PDCAAS
based on content of amino acids, digestibility, and ability to supply essential amino acids
functional properties of proteins
solubility (increased by pectin)
water-holding complex (influences moisture, juiciness, texture)
emulsification
foaming and generation
allergies
happen from proteins that are not broken down by digestive tract
(eggs, fish, shellfish, dairy, wheat, tree nuts, peanuts, soy)
lipids
mostly water insoluble
energy source (9kcal/g) → excessive = fat
structural component in cell membrane
insulation and protection
carrier of fat-soluble vitamins
promotes fullness
sources = oil, margarine, butter, shortenings, meats, nuts, ice cream, milk, mayo, eggs, etc.
triglyceride
basic structure of lipids (glycerol + 3 fatty acids)
simple lipids
oil and fats
formed of triglyceride
primary form of energy storage
complex lipids
additional functional groups
phospho- = phosphate group (egg yolks)
glyco- = sugar groups
derived lipids
from hydrolysis of lipids
saturated fatty acids
linear structure
higher melting point
solid at room temp
crystalize more easily
less prone to oxidation
no double bonds
unsaturated fatty acids
bends/kinks in structure (lose)
lower melting points
liquid at room temp
vulnerable to oxidation
smooth mouthfeel
one or more double bond
cis fats
H atom on same side (health promoting)
trans fats
H atom on opposite sides (unhealthy)
raises LDL and lowers HDL (heart disease risk)
lipid functions
absorbs + retains flavor
texture/mouthfeel
improves palatability
carrier for fat soluble vitamins
source of omega-6 and omega-3 fatty acids
act as emulsifiers
lipid oxidation
chemical reaction of unsaturated fats and oxygen, light, heat, or metals
results in rancidity
reduces shelf-life
lipid oxidation prevention methods
add antioxidants (vitamin E and C)
packaging techniques (vacuum, modified atmosphere, and light blocking)
storage conditions (cool (0-4 C), dry, dark)
vitamins
organic compound
carbon-based
don’t produce energy
must be obtained in diet (not synthesized)
water solube = B and C
fat-soluble = A,D,E,K
minerals
inorganic compound
naturally occurring elements (from Earth)
structural components and vital processes in bodies
vitamin A
sources = orange fruits + vegetables (carrots)
main function = vision
deficiency = night blindness and embryo defects
toxicity = organ damage
vitamin D
sources = sunshine + milk
functions = assist in bone making + maintenance
deficiency = osteomalacia
toxicity = calcium deposits
vitamin E
sources = seeds, nuts, oils
toxicity + deficiency = rare
vitamin K
sources = green leafy vegetables
functions = blood clotting and bone health
toxicity and deficiency = rare
vitamin C
sources = fruits and vegetables (oranges)
functions = immune support + act as antioxidant
vitamin B family sources
whole grains, leafy greens, legumes
water-soluble vitamin deficiencies
thiamin = beriberi
niacin = pellagra (4Ds)
vitamin c = scurvy
mineral functions
bone health
blood health
fluid balance
energy metabolism
antioxidant
make-up of bones
calcium = 99%
phosphorus
magnesium = regulator
iron (blood health)
70% = heme iron = absorbed by body (higher in meat)
green leafy = non-heme
sources = clams, beef, spinach, beans, lentils, chickpeas, mushrooms
deficiency = fatigue, headaches, shortness of breath
sodium
fluid and electrolyte balance
regulates blood pressure
nerve transmission and lowers blood pressure
potassium
fluid balance
lowers blood pressure
heartbeat + muscle contractions
normal nerve transmission
iodine
energy regulation, reproduction and growth
selenium
antioxidant
reasons for hydrogenation
improved oxidative stability (extends shelf life + reduces rancidity)
enhanced heat tolerance (high-heat cooking)
higher melting point
issues of hydrogenation
unsaturated bonds are reversible and the double bonds can be cis or trans fat
retrogradation
starches firm and baked goods lose soft, fresh texture
refrigeration accelerated process
4 C for bread
15-20 C for cake
ways to reduce retrogradation
control storage temp
adjust moisture content
use additives (emulsifiers and enzymes)
use modified starches
role of cysteine in baked goods
forms sulfur bonds which contribute to the development of gluten network, essential for texture and structure of dough