Organic Chemistry: Table 3.1 Relative Acid Strengths and Structures

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Vocabulary practice flashcards covering the chemical structures, identity, and highlighted acidic protons of selected Bronsted-Lowry acids from WileyPLUS Table 3.1.

20 Terms

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<p>Hydrobromic Acid ($$HBr$$)</p>

Hydrobromic Acid (HBrHBr)

A strong binary halogen acid depicted in Table 3.1 as Br−HBr-H, possessing a covalent bond to an acidic proton highlighted in red.

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<p>Hydrochloric Acid ($$HCl$$)</p>

Hydrochloric Acid (HClHCl)

A strong mineral acid depicted in Table 3.1 as Cl−HCl-H, featuring an acidic hydrogen atom highlighted in red bonded directly to chlorine.

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<p>Sulfuric Acid ($$H_2SO_4$$)</p>

Sulfuric Acid (H2SO4H_2SO_4)

A diprotic mineral acid depicted in Table 3.1 as H−O−S(=O)2−O−HH-O-S(=O)_2-O-H, showing an acidic proton highlighted in red bonded to an oxygen atom of the sulfonyl core.

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<p>Hydronium Ion ($$H_3O^+$$)</p>

Hydronium Ion (H3O+H_3O^+)

The conjugate acid of water depicted in Table 3.1 as a positively charged oxygen species with three bonded hydrogens, with one acidic proton highlighted in red.

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<p>Anilinium Ion ($$C_6H_5NH_3^+$$)</p>

Anilinium Ion (C6H5NH3+C_6H_5NH_3^+)

An aromatic conjugate acid depicted in Table 3.1 as a benzene ring bonded to a positively charged ammonium group (−NH3+-NH_3^+), with an acidic proton highlighted in red on nitrogen.

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<p>Acetic Acid ($$CH_3COOH$$)</p>

Acetic Acid (CH3COOHCH_3COOH)

A carboxylic acid depicted in Table 3.1 as CH3−C(=O)−O−HCH_3-C(=O)-O-H, featuring a carbonyl group bonded to a hydroxyl group whose acidic proton is highlighted in red.

7
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<p>Hydrogen Sulfide ($$H_2S$$)</p>

Hydrogen Sulfide (H2SH_2S)

A weak binary sulfur acid depicted in Table 3.1 as a bent H−S−HH-S-H structure, with an acidic proton highlighted in red bonded to the sulfur atom.

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<p>Acetylacetone (Pentane-2,4-dione)</p>

Acetylacetone (Pentane-2,4-dione)

A beta-diketone depicted in Table 3.1 with two carbonyl groups flanking a central methylene carbon, where the acidic alpha-hydrogen is highlighted in red.

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<p>Ammonium Ion ($$NH_4^+$$)</p>

Ammonium Ion (NH4+NH_4^+)

The tetrahedral conjugate acid of ammonia depicted in Table 3.1 with a formal positive charge on nitrogen and an acidic proton highlighted in red.

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<p>Phenol ($$C_6H_5OH$$)</p>

Phenol (C6H5OHC_6H_5OH)

An aromatic alcohol depicted in Table 3.1 as a phenyl ring attached to a hydroxyl group, whose acidic phenolic proton is highlighted in red.

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<p>Water ($$H_2O$$)</p>

Water (H2OH_2O)

An amphoteric oxygen hydride depicted in Table 3.1 as bent H−O−HH-O-H, acting as an acid with one acidic proton highlighted in red.

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<p>Ethanol ($$CH_3CH_2OH$$)</p>

Ethanol (CH3CH2OHCH_3CH_2OH)

A primary alcohol depicted in Table 3.1 as an ethyl group bonded to a hydroxyl group, with the acidic hydroxyl proton highlighted in red.

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<p>tert-Butanol ($$(CH_3)_3COH$$)</p>

tert-Butanol ((CH3)3COH(CH_3)_3COH)

A bulky tertiary alcohol (2-methylpropan-2-ol) depicted in Table 3.1 with three methyl groups bonded to a central carbon bearing an −OH-OH group, with the acidic proton highlighted in red.

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<p>Acetone ($$CH_3COCH_3$$)</p>

Acetone (CH3COCH3CH_3COCH_3)

A simple ketone (propan-2-one) depicted in Table 3.1 with a carbonyl group, showing one alpha-carbon hydrogen highlighted in red as an acidic proton.

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<p>Acetylene ($$HC \equiv CH$$)</p>

Acetylene (HC≡CHHC \equiv CH)

An alkyne (ethyne) depicted in Table 3.1 containing a carbon-carbon triple bond, with an spsp-hybridized terminal C-H proton highlighted in red as an acidic site.

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<p>Ammonia ($$NH_3$$)</p>

Ammonia (NH3NH_3)

A nitrogen hydride depicted in Table 3.1 with trigonal pyramidal geometry, functioning as an acid with one of its N-H protons highlighted in red.

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<p>Ethylene ($$H_2C=CH_2$$)</p>

Ethylene (H2C=CH2H_2C=CH_2)

An alkene (ethene) depicted in Table 3.1 containing a planar carbon-carbon double bond, with an sp2sp^2-hybridized C-H proton highlighted in red.

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<p>Ethane ($$CH_3CH_3$$)</p>

Ethane (CH3CH3CH_3CH_3)

A saturated alkane depicted in Table 3.1 containing a carbon-carbon single bond, with an extremely weakly acidic sp3sp^3-hybridized C-H proton highlighted in red.

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Table 3.1 (WileyPLUS Acid Strengths Table)

A reference table from learn.wileyplus.com organized with an 'ACID' column that tabulates acids in descending order of strength from strong mineral acids (HBrHBr, HClHCl) to extremely weak hydrocarbons (CH3CH3CH_3CH_3).

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Acidic Proton Highlighting Convention

The pedagogical notation utilized across Table 3.1 where the specific, most acidic hydrogen atom available for transfer as a proton (H+H^+) is highlighted in red font.