CHAPTER 21 - SUBSTITUTION REACTIONS OF CARBONYL COMPOUNDS AT THE A CARBON

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14 Terms

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<p>Kinetic versus thermodynamic enolates (21.4)</p><p></p>

Kinetic versus thermodynamic enolates (21.4)


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<p><br>Kinetic versus thermodynamic enolates (21.4)</p>


Kinetic versus thermodynamic enolates (21.4)

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<p>Halogenation at the a carbon</p>

Halogenation at the a carbon

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<p>[1] Halogenation in acid (21.7A)</p><p></p>

[1] Halogenation in acid (21.7A)


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<p>[2] Halogenation in base (21.7B)</p>

[2] Halogenation in base (21.7B)

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<p>[3] Halogenation of methyl ketones in base------The haloform reaction (21.7B) </p>

[3] Halogenation of methyl ketones in base------The haloform reaction (21.7B)

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<p>[1] Elimination to form a,b-unsaturated carbonyl compounds </p>

[1] Elimination to form a,b-unsaturated carbonyl compounds

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<p><br>[2] Halogenation in base (21.7B</p>


[2] Halogenation in base (21.7B

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<p>[2] Nucleophilic substitution</p><p></p>

[2] Nucleophilic substitution


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<p>Alkylation reactions at the a carbon</p>

Alkylation reactions at the a carbon

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<p>[2] Malonic ester synthesis (21.9)</p>

[2] Malonic ester synthesis (21.9)

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<p>[3] Acetoacetic ester synthesis (21.10)</p><p></p>

[3] Acetoacetic ester synthesis (21.10)


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