Chemistry CCEA AS Level 2.8 (Energetics)

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17 Terms

1
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What is an exothermic reaction?

A reaction where the enthalpy of the products is less than the enthalpy of the reactants

2
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What is an endothermic reaction?

A reaction in which the enthalpy of the products is greater than the enthalpy of the reactants

3
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What is activation energy?

The energy required to break the bonds in the reactants

4
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What are the standard pressure conditions for enthalpy changes?

1 atm

5
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What is a standard enthalpy change?

The change in heat energy at constant pressure, measured at standard conditions

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What is the standard enthalpy of a reaction?

The enthalpy change when the number of mole of substances, are as written in the equations

7
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What is the standard enthalpy of combustion?

The enthalpy change when one mole of a substance is completely burnt in oxygen under standard conditions

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What is the standard enthalpy change of formation?

The enthalpy change when one mole of compound is formed from its elements under standard conditions

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What is the standard enthalpy change of neutralisation?

The enthalpy change when one mole of water is produced in a neutralisation reaction under standard conditions

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What is the standard enthalpy change of formation for elements?

0 kJmol-1

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What is the equation to calculate enthalpy change in joules?

Q=mcΔT

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What is the equation to calculate enthalpy change in kJmol-1?

ΔH = Q/n

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What does Hess' law state?

The enthalpy change in a reaction is independent of the route it takes, provided the initial and final conditions are the same

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What does the principle of the conservation of energy state?

Energy can neither be created nor destroyed, only changed from one form to another

15
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What is average bond enthalpy?

The energy required to break one mole of a given bond averaged over many compounds

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How is ΔH worked out using average bond enthalpy values?

ΔH = ΣBonds broken - ΣBonds made

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What does the strength of a covalent bond depend on?

The atoms involved and whether the bond is single, double or triple