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1st Law of Thermodynamics
states that the total amount of energy in the universe is constant; energy cannot be created or destroyed, but it can be transformed and transferred.
2nd Law of Thermodynamics
all energy transfers involve the loss of some amount of energy in an unusable form such as heat, resulting in entropy; entropy of a system is always increasing
Absorption Spectrum
range of wavelengths of electromagnetic radiation absorbed by a given substance
Acetyl CoA
combination of an acetyl group derived from pyruvic acid and coenzyme A, which is made from pantothenic acid (a B-group vitamin)
Action Spectrum
profiles the relative effectiveness of different wavelengths of radiation in driving a process
Activation Energy
energy necessary for reactions to occur
Active Site
specific region of the enzyme to which the substrate binds
ADP
a lower-energy molecule that can be converted into ATP by the addition of a phosphate group
Aerobic Respiration
process in which organisms convert energy in the presence of oxygen
Alcoholic Fermentation
glycolysis followed by the reduction of pyruvate to ethyl alcohol, regenerating NAD+ and releasing carbon dioxide
Allosteric Inhibition
inhibition by a binding event at a site different from the active site, which induces a conformational change and reduces the affinity of the enzyme for its substrate
Allosteric Site
an alternate part of the enzyme that can bind to non–substrate molecules.
Anabolic
pathways that require an input of energy to synthesize complex molecules from simpler ones
Anaerobic respiration
process in which organisms convert energy for their use in the absence of oxygen
ATP
adenosine triphosphate, the cell’s energy currency
ATP Synthase
membrane-embedded protein complex that adds a phosphate to ADP with energy from protons diffusing through it
Autotroph
organism that produces organic molecules from small inorganic compounds
Calvin Cycle
light-independent reactions of photosynthesis that convert carbon dioxide from the atmosphere into carbohydrates using the energy and reducing power of ATP and NADPH
Carbon Dioxide
a gas that is expelled from the body by the respiratory system.
Catabolic
pathways in which complex molecules are broken down into simpler ones
Catalyst
a substance that speeds up a chemical reaction without being consumed in the process
Catalyze
to significantly speed up a chemical reaction by using a catalyst
Cellular Respiration
the metabolic process by which cells convert chemical energy from glucose (food) into usable energy (ATP) through a series of controlled reactions, primarily utilizing oxygen to generate carbon dioxide and water as byproducts
Chemiosmosis
process in which there is a production of adenosine triphosphate (ATP) in cellular metabolism by the involvement of a proton gradient across a membrane
Chlorophyll
green pigment that captures the light energy that drives the light reactions of photosynthesis
Chloroplast
organelle in which photosynthesis takes place
Coenzyme
small organic molecule, such as a vitamin or its derivative, which is required to enhance the activity of an enzyme
Competitive Inhibition
type of inhibition in which the inhibitor competes with the substrate molecule by binding to the active site of the enzyme
Electrochemical Gradient
the diffusion gradient of an ion, representing a type of potential energy that accounts for both the concentration difference of the ion across a membrane and its tendency to move relative to the membrane potential
Electron
a subatomic particle with a single negative electrical charge and a (negligible) mass about 1/2000 that of a neutron or a proton. One or more electrons move around the nucleus of an atom
Electron Acceptor
a compound that can accept a pair of high-energy electrons and transfer them, along with most of their energy, to another molecule
Electron Carrier Molecule
A sequence of electron carrier molecules (membrane proteins) that shuttle electrons during the redox reactions that release energy used to make ATP.
Electron Transport Chain
group of proteins between PSII and PSI that pass energized electrons and use the energy released by the electrons to move hydrogen ions against their concentration gradient into the thylakoid lumen
Endergonic Reaction
a nonspontaneous chemical reaction in which free energy is absorbed from the surroundings
Endothermic
(of a chemical reaction or compound) occurring or formed with absorption of heat
Energy Coupling
process during which energy released by one reaction is used to drive another reaction
Energy decoupling
Exergonic and Endergonic reactions happening separately of each other
Enzyme
catalyst in a biochemical reaction that is usually a complex or conjugated protein
Exergonic Reaction
a spontaneous chemical reaction in which there is a net release of energy
FADH2
electron carrier produced during the Krebs cycle
Fermentation
process of regenerating NAD+ with either an inorganic or organic compound serving as the final electron acceptor; occurs in the absence of oxygen
Glucose
the form of sugar that circulates in the blood and provides the major source of energy for body tissues. When its level is low, we feel hunger.
Glycolysis
process of breaking glucose into two three-carbon molecules with the production of ATP and NADH
Granum
stack of thylakoids located inside a chloroplast
Heterotroph
organism that consumes organic substances or other organisms for food
Induced fit
dynamic fit between the enzyme and its substrate, in which both components modify their structures to allow for ideal binding
Inner membrane
The membrane of the mitochondria that is the site of electron transport and chemiosmosis
Inorganic Phosphate
Derived from phosphoric acid, the molecule that forms high-energy bonds for energy storage in nucleotide triphosphates like ATP; also used for enzyme regulation.
Intermembrane Space
the fluid filled space between the inner and outer mitochondrial membranes
Krebs Cycle
series of enzyme-catalyzed chemical reactions of central importance in all living cells
Lactic Acid Fermentation
Glycolysis followed by the reduction of pyruvate to lactate, regenerating NAD+ with no release of carbon dioxide
Light Reactions
the first of two major stages in photosynthesis (preceding the Calvin Cycle). These reactions, which occur on the thylakoid membranes of the chloroplast or on the membranes of certain prokaryotes, convert light energy to chemical energy of ATP and NADPH, releasing oxygen in the process
Metabolism
all the chemical reactions that take place inside cells, including anabolism and catabolism
NAD+
nicotinamide adenine dinucleotide, a coenzyme that cycles easily between oxidized NAD+ and NADH states, thus acting as an electron carrier
NADH
the reduced form of NAD+; an electron-carrying molecule that functions in cellular respiration
NADP+
nicotinamide adenine dinucleotide phosphate, an electron acceptor that, as NADPH, temporarily stores energized electrons produces during the light reactions
NADPH
an electron carrier that provides high-energy electrons for photosynthesis
Negative Feedback
feedback to a control mechanism that increases or decreases a stimulus instead of maintaining it
Optimal Range
the range of environmental factors to which an organism is best adapted
Outer Membrane
the outermost membrane in the mitochondria that protects and holds the form of the organelle.
Oxidative Phosphorylation
production of ATP using the process of chemiosmosis and oxygen
Oxygen
gas that enters the blood through the lungs and travels to the heart to be pumped via arteries to all body cells
Phosphorylation
addition of a high-energy phosphate to a compound, usually a metabolic intermediate, a protein, or ADP
Photosynthesis
series of reactions that use carbon dioxide, water, and light energy to make glucose and oxygen
Photosystem I and II
Light harvesting complexes with its associated electron transport chain. Located in thylakoid membranes and take place during the Light Dependent Reactions.
Product
molecule(s) found on the right side of a chemical equation
Proton (H+)
positively charged particle that resides in the nucleus of an atom; has a mass of one amu and a charge of +1
Pyruvate
three-carbon sugar that can be decarboxylated and oxidized to make acetyl CoA, which enters the citric acid cycle under aerobic conditions; the end product of glycolysis
Reactant
molecule(s) found on the left side of a chemical equation
Ribulose Biphosphate
A five-carbon compound that combines with CO2 in the first step of the Calvin cycle during photosynthesis.
Ribulose Biphosphate Carboxylase
key enzyme involved in the first step of carbon fixation in photosynthesis
Stomata
opening that regulates gas exchange and water evaporation between leaves and the environment, typically situated on the underside of leaves (stoma = singular)
Stroma
fluid-filled space surrounding the grana inside a chloroplast where the light-independent reactions of photosynthesis take place
Substrate Level Phosphorylation
production of ATP from ADP using the excess energy from a chemical reaction and a phosphate group from a reactant
Thylakoid Membrane
The photosynthetic membrane within a chloroplast that contains light gathering pigment molecules and electron transport chains.
Wavelength
distance between consecutive points of equal position (two crests or two troughs) of a wave in a graphic representation; inversely proportional to the energy of the radiation