Rate of Reaction

Simple and Giant Structures in Chemistry

Key Definitions

  • ION: An atom that has lost or gained one or more electrons, resulting in an electric charge.

  • IONIC BOND: The connection formed between ions to create a compound.

  • IONIC COMPOUND: A compound formed when a metal ion and a non-metal ion react.

  • MOLECULE: A particle resulting from atoms bonded together via covalent bonds.

  • COVALENT BOND: A connection formed when atoms share electrons.

  • ELECTRONIC STRUCTURE: Arrangement of electrons in shells around an atom's nucleus.

  • INTERMOLECULAR FORCES: Forces acting between molecules.

  • METALLIC BOND: The attraction between positively charged metal ions and a sea of delocalized electrons, allowing for conductivity and malleability.

Differences Between Ionic and Covalent Compounds

  • Ionic compounds have different structural properties than molecular compounds, impacting their macroscopic physical properties.

  • Physical Properties of Molecular Compounds:

    • Vary based on bonding type.

    • Generally have low melting and boiling points compared to ionic compounds, as melting involves breaking weaker intermolecular forces instead of strong ionic bonds.

Conductivity and Solubility

  • Electrical Conductivity:

    • Covalent compounds: Poor conductivity in solid or liquid state.

    • Ionic compounds: Do not conduct electricity as solids; good conductors when molten or dissolved in solution.

  • Water Solubility:

    • Varies for covalent compounds, depending on molecular structure.

    • Many ionic compounds are highly soluble in water.

Chemical Formulas

  • Covalent compounds: Represent identity and exact number of atoms.

  • Ionic compounds: Represent the simplest ratio of ions in a lattice.

Comparative Table of Ionic and Covalent Compounds

Property

Ionic compounds

Covalent compounds

Type of elements

Metal and nonmetal

Nonmetals only

Bonding

Ionic - attraction between anions and cations

Covalent - sharing of electrons

Representative unit

Formula unit

Molecule

What the formula represents

Ratio of cations to anions

Type and number of atoms

Physical state at room temperature

Solid

Gas, liquid, or solid

Water solubility

Usually high

Variable

Melting and boiling temperatures

Generally high

Generally low

Electrical conductivity

Good when molten or in solution

Poor

State when dissolved in water

Separates into ions

Remains as molecules

Simple Structures in Chemistry

  • Simple Molecules: Groups of atoms bonded by covalent bonds, which can vary in type: monoatomic, diatomic, polyatomic (macromolecules).

Characteristics of Ionic and Covalent Bonds

  • Ionic Bonding: Involves transfer of electrons between atoms; requires donor and acceptor.

  • Covalent Bonding: Involves sharing electrons between atoms with similar electronegativity.

Giant Structures in Chemistry

  • Giant Covalent Structures: Solid substances with very high melting points, all atoms bonded by strong covalent bonds (e.g., diamond, graphite, silicon dioxide).

  • Giant Ionic Structures: Composed of large numbers of metal and non-metal ions in a regular lattice architecture.

Distinction Between Simple and Giant Structures

  • Simple molecular substances are gases, liquids, or low melting point solids.

  • Giant molecular structures are typically high melting point solids and can be ionic, metallic, or giant covalent.

  • Giant Molecules: Known as macromolecules or polymers when formed by many combined molecules.

Comparison of Types of Bonding

Ionic

Covalent

Metallic

Formation

Anion & cation

Shared electrons

Cations in a sea of mobile electrons

Source

Metal + nonmetal

Two nonmetals

Metals only

Melting Point

Relatively high

Relatively low

Generally high

Solubility

Best in water & polar solvents

Best in nonpolar solvents

Generally insoluble

Conductivity

Conduct in solutions

Conduct electricity poorly or not at all

Conduct electricity well

Other Properties

Strong crystal structure

Weak crystal structure

Properties like luster and malleability

Bonds Recap

  • Ionic Bond: Formed between metals and non-metals, involving the transfer of electrons.

  • Covalent Bond: Formed between non-metals, involving electron sharing.

  • Giant Covalent Structure: Formed by covalent bonds among multiple atoms, revealing extensive bonding networks.

Vocabulary Words:

  • Covalent: A type of chemical bond that involves the sharing of electron pairs between atoms.

  • Monoatomic: Consisting of a single atom.

  • Diatomic: Consisting of two atoms from the same or different chemical elements.

  • Polyatomic: Consisting of more than two atoms.

  • Macromolecules: Large, complex molecules, often consisting of many repetitive subunits (such as proteins or nucleic acids).

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