ION: An atom that has lost or gained one or more electrons, resulting in an electric charge.
IONIC BOND: The connection formed between ions to create a compound.
IONIC COMPOUND: A compound formed when a metal ion and a non-metal ion react.
MOLECULE: A particle resulting from atoms bonded together via covalent bonds.
COVALENT BOND: A connection formed when atoms share electrons.
ELECTRONIC STRUCTURE: Arrangement of electrons in shells around an atom's nucleus.
INTERMOLECULAR FORCES: Forces acting between molecules.
METALLIC BOND: The attraction between positively charged metal ions and a sea of delocalized electrons, allowing for conductivity and malleability.
Ionic compounds have different structural properties than molecular compounds, impacting their macroscopic physical properties.
Physical Properties of Molecular Compounds:
Vary based on bonding type.
Generally have low melting and boiling points compared to ionic compounds, as melting involves breaking weaker intermolecular forces instead of strong ionic bonds.
Electrical Conductivity:
Covalent compounds: Poor conductivity in solid or liquid state.
Ionic compounds: Do not conduct electricity as solids; good conductors when molten or dissolved in solution.
Water Solubility:
Varies for covalent compounds, depending on molecular structure.
Many ionic compounds are highly soluble in water.
Covalent compounds: Represent identity and exact number of atoms.
Ionic compounds: Represent the simplest ratio of ions in a lattice.
Property | Ionic compounds | Covalent compounds |
Type of elements | Metal and nonmetal | Nonmetals only |
Bonding | Ionic - attraction between anions and cations | Covalent - sharing of electrons |
Representative unit | Formula unit | Molecule |
What the formula represents | Ratio of cations to anions | Type and number of atoms |
Physical state at room temperature | Solid | Gas, liquid, or solid |
Water solubility | Usually high | Variable |
Melting and boiling temperatures | Generally high | Generally low |
Electrical conductivity | Good when molten or in solution | Poor |
State when dissolved in water | Separates into ions | Remains as molecules |
Simple Molecules: Groups of atoms bonded by covalent bonds, which can vary in type: monoatomic, diatomic, polyatomic (macromolecules).
Ionic Bonding: Involves transfer of electrons between atoms; requires donor and acceptor.
Covalent Bonding: Involves sharing electrons between atoms with similar electronegativity.
Giant Covalent Structures: Solid substances with very high melting points, all atoms bonded by strong covalent bonds (e.g., diamond, graphite, silicon dioxide).
Giant Ionic Structures: Composed of large numbers of metal and non-metal ions in a regular lattice architecture.
Simple molecular substances are gases, liquids, or low melting point solids.
Giant molecular structures are typically high melting point solids and can be ionic, metallic, or giant covalent.
Giant Molecules: Known as macromolecules or polymers when formed by many combined molecules.
Ionic | Covalent | Metallic | |
Formation | Anion & cation | Shared electrons | Cations in a sea of mobile electrons |
Source | Metal + nonmetal | Two nonmetals | Metals only |
Melting Point | Relatively high | Relatively low | Generally high |
Solubility | Best in water & polar solvents | Best in nonpolar solvents | Generally insoluble |
Conductivity | Conduct in solutions | Conduct electricity poorly or not at all | Conduct electricity well |
Other Properties | Strong crystal structure | Weak crystal structure | Properties like luster and malleability |
Ionic Bond: Formed between metals and non-metals, involving the transfer of electrons.
Covalent Bond: Formed between non-metals, involving electron sharing.
Giant Covalent Structure: Formed by covalent bonds among multiple atoms, revealing extensive bonding networks.
Vocabulary Words:
Covalent: A type of chemical bond that involves the sharing of electron pairs between atoms.
Monoatomic: Consisting of a single atom.
Diatomic: Consisting of two atoms from the same or different chemical elements.
Polyatomic: Consisting of more than two atoms.
Macromolecules: Large, complex molecules, often consisting of many repetitive subunits (such as proteins or nucleic acids).