Chem 102 ch.1-ch.6
Periodic table elements:
H - Hydrogen
He - Helium
Li - Lithium
Be - Beryllium
B - Boron
C - Carbon
N - Nitrogen
O - Oxygen
F - Fluorine
Ne - Neon
Na - Sodium
Mg - Magnesium
Al - Aluminum, Aluminium
Si - Silicon
P - Phosphorus
S - Sulfur
Cl - Chlorine
Ar - Argon
K - Potassium
Ca - Calcium
Sc - Scandium
Ti - Titanium
V - Vanadium
Cr - Chromium
Mn - Manganese
Fe - Iron
Co - Cobalt
Ni - Nickel
Cu - Copper
Zn - Zinc
Ga - Gallium
Ge - Germanium
As - Arsenic
Se - Selenium
Br - Bromine
Kr - Krypton
Rb - Rubidium
Sr - Strontium
Y - Yttrium
Zr - Zirconium
Nb - Niobium
Mo - Molybdenum
Tc - Technetium
Ru - Ruthenium
Rh - Rhodium
Pd - Palladium
Ag - Silver
Cd - Cadmium
In - Indium
Sn - Tin
Sb - Antimony
Te - Tellurium
I - Iodine
Xe - Xenon
Units:
1in= 2.54 cm
1cm= 10-2 meters
1mg= 10-3 gram
1kg= 1,000 grams
giga | G | 109 | 1,000,000,000 (billion) |
mega | M | 106 | 1,000,000(million) |
kilo | k | 103 | 1,000 (thousand) |
hecto | h | 102 | 100 (hundred) |
deka | dk | 101 | 10 (ten) |
deci | d | 10-1 | 0.1 (tenth) |
centi | c | 10-2 | 0.01 (hundredth) |
milli | m | 10-3 | 0.001 (thousandth) |
micro | μ | 10-6 | 0.000001 (millionth) |
nano | n | 10-9 | 0.0000000001 (billionth) |
pico | p | 10-12 | 0.00000000001 (trillionth) |
femto | f | 10-15 | 0.000000000000001 (quadrillionth) |
Atomic #=#of protons
#of protons=#of electrons
Charged Atom=Ion
Ionic= metal+nonmetal
→ TRANSFER of electrons between the atoms(IONS)
Covalent= nonmetal+ nonmetal
→ SHARING of electrons between nonmetal and nonmetal atoms
Isotopes: elements w/diff # of neutrons
d4 atoms: Cr & Mo have s1d5 electron configuration
All of the d9 atoms have an s1d10 electron configuration
ALL bonding is based on electrostatic interactions between the negatively charged electrons of one atom & the positively charged nucleus of the other
Compounds can be divided into 2 groups: Binary vs. non binary
Binary: Composed of 2 and ONLY 2 different types of atoms
Not Binary: Composed of more than 2 types of atoms
Ions: when atoms gain or lose electrons they form ions
→lose electrons= cations(positive)
usually on the left side of the periodic table
→gain electrons=anions (negative)
usually on the right side of the periodic table
NH4+ | ammonium ion | OH- | hydroxide ion | CN- | cyanide ion |
SO42- | sulfate ion | O22- | peroxide ion | CNO- | cyanate ion |
HSO4- | hydrogen sulfate ion | C2H3O2- | acetate ion | SCN- | thiocyanate ion |
SO32- | sulfite ion | ClO4- | perchlorate ion | CO32- | carbonate ion |
NO3- | nitrate ion | ClO3- | chlorate ion | HCO3- | hydrogen carbonate |
NO2- | nitrite ion | ClO2- | chlorite ion | C2O42- | oxalate ion |
PO43- | phosphate ion | ClO- | hypochlorite ion | S2O32- | thiosulfate ion |
HPO42- | hydrogen phosphate | CrO42- | chromate ion | Hg22+ | mercury(I) ion |
H2PO4- | dihydrogen phosphate | Cr2O72- | dichromate ion | H3O+ | hydronium ion |
PO33- | phosphite ion | MnO4- | permanganate ion | NH3 | ammonia |
Naming Compounds:
Prefixes for COVALENT compounds:
Mono-1
di-2
tri-3
tetra-4
penta-5
hexa-6
hepta-7
octa-8
nona-9
deca-10
prefix→ name of 1st element→ prefix→ name of 2nd element + -ide
Naming IONIC compounds:
IF the cation is a single metal + nonmetal that forms only one type of ion (like sodium Na+ or Ca² +) you use: Example: NaCl → NaCl is named sodium chloride.
IF the cation can form multiple charges (like iron, copper, etc.), specify the charge using Roman numerals.Example: FeCl2
FeCl2 is named iron(II) chloride (since iron has a +2 charge).
For single nonmetals: name of metal + name of nonmetal & change the ending to -ide
For polyatomic ions, use the name of the ion as is.
Electronegativity increases as you go up and across the periodic table
Non-polar= similar electronegativities
→ ex: F-F
Since both atoms have the same electronegativity, there is no difference in electron density.
Polar=large electronegativity difference
→ ex: Ge-F
Bonding:
Carbon will always want to make 4 bonds
Nitrogen will always want to make 3 bonds
Oxygen will always want to make 2 bonds
Halogens and Hydrogen will always want to make 1 bond
7 diatomic molecules: H2, N2, 02, F2, CI2, Br2, I2
→start w/ H, find element 7 on the P.T. to find the other 6
-draw a 7 to find the other 6 elements aside from H
Kinetic energy: due to MOTION (KE= ½ mv²)
Potential energy: due to POSITION (PE=mgh)
Combustion reactions are exothermic: Combustion→ surroundings get hot→ heat is absorbed
ΔE=ΔH
Δ E= change in internal energy of the system
ΔH= change in enthalpy of the system
Exothermic: Δ H= — (negative)
→ heat is being released because it’s coming down
ΔH< 0
Endothermic:
ΔH= + (positive)
→ heat is higher because it’s coming in
heat is abosrbed
ΔH >0
Periodic table elements:
H - Hydrogen
He - Helium
Li - Lithium
Be - Beryllium
B - Boron
C - Carbon
N - Nitrogen
O - Oxygen
F - Fluorine
Ne - Neon
Na - Sodium
Mg - Magnesium
Al - Aluminum, Aluminium
Si - Silicon
P - Phosphorus
S - Sulfur
Cl - Chlorine
Ar - Argon
K - Potassium
Ca - Calcium
Sc - Scandium
Ti - Titanium
V - Vanadium
Cr - Chromium
Mn - Manganese
Fe - Iron
Co - Cobalt
Ni - Nickel
Cu - Copper
Zn - Zinc
Ga - Gallium
Ge - Germanium
As - Arsenic
Se - Selenium
Br - Bromine
Kr - Krypton
Rb - Rubidium
Sr - Strontium
Y - Yttrium
Zr - Zirconium
Nb - Niobium
Mo - Molybdenum
Tc - Technetium
Ru - Ruthenium
Rh - Rhodium
Pd - Palladium
Ag - Silver
Cd - Cadmium
In - Indium
Sn - Tin
Sb - Antimony
Te - Tellurium
I - Iodine
Xe - Xenon
Units:
1in= 2.54 cm
1cm= 10-2 meters
1mg= 10-3 gram
1kg= 1,000 grams
giga | G | 109 | 1,000,000,000 (billion) |
mega | M | 106 | 1,000,000(million) |
kilo | k | 103 | 1,000 (thousand) |
hecto | h | 102 | 100 (hundred) |
deka | dk | 101 | 10 (ten) |
deci | d | 10-1 | 0.1 (tenth) |
centi | c | 10-2 | 0.01 (hundredth) |
milli | m | 10-3 | 0.001 (thousandth) |
micro | μ | 10-6 | 0.000001 (millionth) |
nano | n | 10-9 | 0.0000000001 (billionth) |
pico | p | 10-12 | 0.00000000001 (trillionth) |
femto | f | 10-15 | 0.000000000000001 (quadrillionth) |
Atomic #=#of protons
#of protons=#of electrons
Charged Atom=Ion
Ionic= metal+nonmetal
→ TRANSFER of electrons between the atoms(IONS)
Covalent= nonmetal+ nonmetal
→ SHARING of electrons between nonmetal and nonmetal atoms
Isotopes: elements w/diff # of neutrons
d4 atoms: Cr & Mo have s1d5 electron configuration
All of the d9 atoms have an s1d10 electron configuration
ALL bonding is based on electrostatic interactions between the negatively charged electrons of one atom & the positively charged nucleus of the other
Compounds can be divided into 2 groups: Binary vs. non binary
Binary: Composed of 2 and ONLY 2 different types of atoms
Not Binary: Composed of more than 2 types of atoms
Ions: when atoms gain or lose electrons they form ions
→lose electrons= cations(positive)
usually on the left side of the periodic table
→gain electrons=anions (negative)
usually on the right side of the periodic table
NH4+ | ammonium ion | OH- | hydroxide ion | CN- | cyanide ion |
SO42- | sulfate ion | O22- | peroxide ion | CNO- | cyanate ion |
HSO4- | hydrogen sulfate ion | C2H3O2- | acetate ion | SCN- | thiocyanate ion |
SO32- | sulfite ion | ClO4- | perchlorate ion | CO32- | carbonate ion |
NO3- | nitrate ion | ClO3- | chlorate ion | HCO3- | hydrogen carbonate |
NO2- | nitrite ion | ClO2- | chlorite ion | C2O42- | oxalate ion |
PO43- | phosphate ion | ClO- | hypochlorite ion | S2O32- | thiosulfate ion |
HPO42- | hydrogen phosphate | CrO42- | chromate ion | Hg22+ | mercury(I) ion |
H2PO4- | dihydrogen phosphate | Cr2O72- | dichromate ion | H3O+ | hydronium ion |
PO33- | phosphite ion | MnO4- | permanganate ion | NH3 | ammonia |
Naming Compounds:
Prefixes for COVALENT compounds:
Mono-1
di-2
tri-3
tetra-4
penta-5
hexa-6
hepta-7
octa-8
nona-9
deca-10
prefix→ name of 1st element→ prefix→ name of 2nd element + -ide
Naming IONIC compounds:
IF the cation is a single metal + nonmetal that forms only one type of ion (like sodium Na+ or Ca² +) you use: Example: NaCl → NaCl is named sodium chloride.
IF the cation can form multiple charges (like iron, copper, etc.), specify the charge using Roman numerals.Example: FeCl2
FeCl2 is named iron(II) chloride (since iron has a +2 charge).
For single nonmetals: name of metal + name of nonmetal & change the ending to -ide
For polyatomic ions, use the name of the ion as is.
Electronegativity increases as you go up and across the periodic table
Non-polar= similar electronegativities
→ ex: F-F
Since both atoms have the same electronegativity, there is no difference in electron density.
Polar=large electronegativity difference
→ ex: Ge-F
Bonding:
Carbon will always want to make 4 bonds
Nitrogen will always want to make 3 bonds
Oxygen will always want to make 2 bonds
Halogens and Hydrogen will always want to make 1 bond
7 diatomic molecules: H2, N2, 02, F2, CI2, Br2, I2
→start w/ H, find element 7 on the P.T. to find the other 6
-draw a 7 to find the other 6 elements aside from H
Kinetic energy: due to MOTION (KE= ½ mv²)
Potential energy: due to POSITION (PE=mgh)
Combustion reactions are exothermic: Combustion→ surroundings get hot→ heat is absorbed
ΔE=ΔH
Δ E= change in internal energy of the system
ΔH= change in enthalpy of the system
Exothermic: Δ H= — (negative)
→ heat is being released because it’s coming down
ΔH< 0
Endothermic:
ΔH= + (positive)
→ heat is higher because it’s coming in
heat is abosrbed
ΔH >0