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Chem 102 ch.1-ch.6

Topic 1:

Periodic table elements:

  1. H - Hydrogen

  2. He - Helium

  3. Li - Lithium

  4. Be - Beryllium

  5. B - Boron

  6. C - Carbon

  7. N - Nitrogen

  8. O - Oxygen

  9. F - Fluorine

  10. Ne - Neon

  11. Na - Sodium

  12. Mg - Magnesium

  13. Al - Aluminum, Aluminium

  14. Si - Silicon

  15. P - Phosphorus

  16. S - Sulfur

  17. Cl - Chlorine

  18. Ar - Argon

  19. K - Potassium

  20. Ca - Calcium

  21. Sc - Scandium

  22. Ti - Titanium

  23. V - Vanadium

  24. Cr - Chromium

  25. Mn - Manganese

  26. Fe - Iron

  27. Co - Cobalt

  28. Ni - Nickel

  29. Cu - Copper

  30. Zn - Zinc

  31. Ga - Gallium

  32. Ge - Germanium

  33. As - Arsenic

  34. Se - Selenium

  35. Br - Bromine

  36. Kr - Krypton

  37. Rb - Rubidium

  38. Sr - Strontium

  39. Y - Yttrium

  40. Zr - Zirconium

  41. Nb - Niobium

  42. Mo - Molybdenum

  43. Tc - Technetium

  44. Ru - Ruthenium

  45. Rh - Rhodium

  46. Pd - Palladium

  47. Ag - Silver

  48. Cd - Cadmium

  49. In - Indium

  50. Sn - Tin

  51. Sb - Antimony

  52. Te - Tellurium

  53. I - Iodine

  54. Xe - Xenon

Units:

1in= 2.54 cm

1cm= 10-2 meters

1mg= 10-3 gram

1kg= 1,000 grams

giga

G

109

1,000,000,000 (billion)

mega

M

106

1,000,000(million)

kilo

k

103

1,000 (thousand)

hecto

h

102

100 (hundred)

deka

dk

101

10 (ten)

deci

d

10-1

0.1 (tenth)

centi

c

10-2

0.01 (hundredth)

milli

m

10-3

0.001 (thousandth)

micro

μ

10-6

0.000001 (millionth)

nano

n

10-9

0.0000000001 (billionth)

pico

p

10-12

0.00000000001 (trillionth)

femto

f

10-15

0.000000000000001 (quadrillionth)

Topic 2:

  • Atomic #=#of protons

  • #of protons=#of electrons

  • Charged Atom=Ion

  • Ionic= metal+nonmetal

    TRANSFER of electrons between the atoms(IONS)

  • Covalent= nonmetal+ nonmetal

    SHARING of electrons between nonmetal and nonmetal atoms

  • Isotopes: elements w/diff # of neutrons

  • d4 atoms: Cr & Mo have s1d5 electron configuration

  • All of the d9 atoms have an s1d10 electron configuration

Topic 3:

  • ALL bonding is based on electrostatic interactions between the negatively charged electrons of one atom & the positively charged nucleus of the other

Compounds can be divided into 2 groups: Binary vs. non binary

Binary: Composed of 2 and ONLY 2 different types of atoms

Not Binary: Composed of more than 2 types of atoms

Ions: when atoms gain or lose electrons they form ions

→lose electrons= cations(positive)

  • usually on the left side of the periodic table

→gain electrons=anions (negative)

  • usually on the right side of the periodic table

NH4+

ammonium ion

OH-

hydroxide ion

CN-

cyanide ion

SO42-

sulfate ion

O22-

peroxide ion

CNO-

cyanate ion

HSO4-

hydrogen sulfate ion

C2H3O2-

acetate ion

SCN-

thiocyanate ion

SO32-

sulfite ion

ClO4-

perchlorate ion

CO32-

carbonate ion

NO3-

nitrate ion

ClO3-

chlorate ion

HCO3-

hydrogen carbonate

NO2-

nitrite ion

ClO2-

chlorite ion

C2O42-

oxalate ion

PO43-

phosphate ion

ClO-

hypochlorite ion

S2O32-

thiosulfate ion

HPO42-

hydrogen phosphate

CrO42-

chromate ion

Hg22+

mercury(I) ion

H2PO4-

dihydrogen phosphate

Cr2O72-

dichromate ion

H3O+

hydronium ion

PO33-

phosphite ion

MnO4-

permanganate ion

NH3

ammonia

Naming Compounds:

Prefixes for COVALENT compounds:

  • Mono-1

  • di-2

  • tri-3

  • tetra-4

  • penta-5

  • hexa-6

  • hepta-7

  • octa-8

  • nona-9

  • deca-10

    prefix→ name of 1st element→ prefix→ name of 2nd element + -ide

    Naming IONIC compounds:

    IF the cation is a single metal + nonmetal that forms only one type of ion (like sodium Na+ or Ca² +) you use: Example: NaCl → NaCl is named sodium chloride.

    IF the cation can form multiple charges (like iron, copper, etc.), specify the charge using Roman numerals.Example: FeCl2

  • FeCl2​ is named iron(II) chloride (since iron has a +2 charge).

  • For single nonmetals: name of metal + name of nonmetal & change the ending to -ide

  • For polyatomic ions, use the name of the ion as is.

Topic 4:

  • Electronegativity increases as you go up and across the periodic table

  • Non-polar= similar electronegativities

    → ex: F-F

    Since both atoms have the same electronegativity, there is no difference in electron density.

  • Polar=large electronegativity difference

    → ex: Ge-F

Bonding:

  • Carbon will always want to make 4 bonds

  • Nitrogen will always want to make 3 bonds

  • Oxygen will always want to make 2 bonds

  • Halogens and Hydrogen will always want to make 1 bond

7 diatomic molecules: H2, N2, 02, F2, CI2, Br2, I2

→start w/ H, find element 7 on the P.T. to find the other 6

-draw a 7 to find the other 6 elements aside from H

Topic 5:

Kinetic energy: due to MOTION (KE= ½ mv²)

Potential energy: due to POSITION (PE=mgh)

Combustion reactions are exothermic: Combustion→ surroundings get hot→ heat is absorbed

ΔE=ΔH

Δ E= change in internal energy of the system

ΔH= change in enthalpy of the system

Exothermic: Δ H= — (negative)

→ heat is being released because it’s coming down

ΔH< 0

Endothermic:

ΔH= + (positive)

→ heat is higher because it’s coming in

heat is abosrbed

ΔH >0

Chem 102 ch.1-ch.6

Topic 1:

Periodic table elements:

  1. H - Hydrogen

  2. He - Helium

  3. Li - Lithium

  4. Be - Beryllium

  5. B - Boron

  6. C - Carbon

  7. N - Nitrogen

  8. O - Oxygen

  9. F - Fluorine

  10. Ne - Neon

  11. Na - Sodium

  12. Mg - Magnesium

  13. Al - Aluminum, Aluminium

  14. Si - Silicon

  15. P - Phosphorus

  16. S - Sulfur

  17. Cl - Chlorine

  18. Ar - Argon

  19. K - Potassium

  20. Ca - Calcium

  21. Sc - Scandium

  22. Ti - Titanium

  23. V - Vanadium

  24. Cr - Chromium

  25. Mn - Manganese

  26. Fe - Iron

  27. Co - Cobalt

  28. Ni - Nickel

  29. Cu - Copper

  30. Zn - Zinc

  31. Ga - Gallium

  32. Ge - Germanium

  33. As - Arsenic

  34. Se - Selenium

  35. Br - Bromine

  36. Kr - Krypton

  37. Rb - Rubidium

  38. Sr - Strontium

  39. Y - Yttrium

  40. Zr - Zirconium

  41. Nb - Niobium

  42. Mo - Molybdenum

  43. Tc - Technetium

  44. Ru - Ruthenium

  45. Rh - Rhodium

  46. Pd - Palladium

  47. Ag - Silver

  48. Cd - Cadmium

  49. In - Indium

  50. Sn - Tin

  51. Sb - Antimony

  52. Te - Tellurium

  53. I - Iodine

  54. Xe - Xenon

Units:

1in= 2.54 cm

1cm= 10-2 meters

1mg= 10-3 gram

1kg= 1,000 grams

giga

G

109

1,000,000,000 (billion)

mega

M

106

1,000,000(million)

kilo

k

103

1,000 (thousand)

hecto

h

102

100 (hundred)

deka

dk

101

10 (ten)

deci

d

10-1

0.1 (tenth)

centi

c

10-2

0.01 (hundredth)

milli

m

10-3

0.001 (thousandth)

micro

μ

10-6

0.000001 (millionth)

nano

n

10-9

0.0000000001 (billionth)

pico

p

10-12

0.00000000001 (trillionth)

femto

f

10-15

0.000000000000001 (quadrillionth)

Topic 2:

  • Atomic #=#of protons

  • #of protons=#of electrons

  • Charged Atom=Ion

  • Ionic= metal+nonmetal

    TRANSFER of electrons between the atoms(IONS)

  • Covalent= nonmetal+ nonmetal

    SHARING of electrons between nonmetal and nonmetal atoms

  • Isotopes: elements w/diff # of neutrons

  • d4 atoms: Cr & Mo have s1d5 electron configuration

  • All of the d9 atoms have an s1d10 electron configuration

Topic 3:

  • ALL bonding is based on electrostatic interactions between the negatively charged electrons of one atom & the positively charged nucleus of the other

Compounds can be divided into 2 groups: Binary vs. non binary

Binary: Composed of 2 and ONLY 2 different types of atoms

Not Binary: Composed of more than 2 types of atoms

Ions: when atoms gain or lose electrons they form ions

→lose electrons= cations(positive)

  • usually on the left side of the periodic table

→gain electrons=anions (negative)

  • usually on the right side of the periodic table

NH4+

ammonium ion

OH-

hydroxide ion

CN-

cyanide ion

SO42-

sulfate ion

O22-

peroxide ion

CNO-

cyanate ion

HSO4-

hydrogen sulfate ion

C2H3O2-

acetate ion

SCN-

thiocyanate ion

SO32-

sulfite ion

ClO4-

perchlorate ion

CO32-

carbonate ion

NO3-

nitrate ion

ClO3-

chlorate ion

HCO3-

hydrogen carbonate

NO2-

nitrite ion

ClO2-

chlorite ion

C2O42-

oxalate ion

PO43-

phosphate ion

ClO-

hypochlorite ion

S2O32-

thiosulfate ion

HPO42-

hydrogen phosphate

CrO42-

chromate ion

Hg22+

mercury(I) ion

H2PO4-

dihydrogen phosphate

Cr2O72-

dichromate ion

H3O+

hydronium ion

PO33-

phosphite ion

MnO4-

permanganate ion

NH3

ammonia

Naming Compounds:

Prefixes for COVALENT compounds:

  • Mono-1

  • di-2

  • tri-3

  • tetra-4

  • penta-5

  • hexa-6

  • hepta-7

  • octa-8

  • nona-9

  • deca-10

    prefix→ name of 1st element→ prefix→ name of 2nd element + -ide

    Naming IONIC compounds:

    IF the cation is a single metal + nonmetal that forms only one type of ion (like sodium Na+ or Ca² +) you use: Example: NaCl → NaCl is named sodium chloride.

    IF the cation can form multiple charges (like iron, copper, etc.), specify the charge using Roman numerals.Example: FeCl2

  • FeCl2​ is named iron(II) chloride (since iron has a +2 charge).

  • For single nonmetals: name of metal + name of nonmetal & change the ending to -ide

  • For polyatomic ions, use the name of the ion as is.

Topic 4:

  • Electronegativity increases as you go up and across the periodic table

  • Non-polar= similar electronegativities

    → ex: F-F

    Since both atoms have the same electronegativity, there is no difference in electron density.

  • Polar=large electronegativity difference

    → ex: Ge-F

Bonding:

  • Carbon will always want to make 4 bonds

  • Nitrogen will always want to make 3 bonds

  • Oxygen will always want to make 2 bonds

  • Halogens and Hydrogen will always want to make 1 bond

7 diatomic molecules: H2, N2, 02, F2, CI2, Br2, I2

→start w/ H, find element 7 on the P.T. to find the other 6

-draw a 7 to find the other 6 elements aside from H

Topic 5:

Kinetic energy: due to MOTION (KE= ½ mv²)

Potential energy: due to POSITION (PE=mgh)

Combustion reactions are exothermic: Combustion→ surroundings get hot→ heat is absorbed

ΔE=ΔH

Δ E= change in internal energy of the system

ΔH= change in enthalpy of the system

Exothermic: Δ H= — (negative)

→ heat is being released because it’s coming down

ΔH< 0

Endothermic:

ΔH= + (positive)

→ heat is higher because it’s coming in

heat is abosrbed

ΔH >0

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