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Resting Membrane Potential - Comprehensive Notes

The Brain's Environment: Water, Ions, and Membranes

  • Water is the brain’s major solvent (about 75% of brain mass).

  • Water is a polar molecule: Oxygen pulls more electron density than hydrogen, giving oxygen a partial negative charge and hydrogens a partial positive charge.

  • Polar water molecules form hydration shells around ions, stabilizing them in solution.

  • If water weren't polar, solvation and ion transport in the brain would be drastically different, impacting signaling and homeostasis.

Water, Polarity, and Its Role in Neural Function

  • The polarity of water underlies its solvent properties and enables hydration of ions.

  • Hydration shells (clouds of water around ions) reduce ion–ion interactions and influence ion mobility.

  • Ions love water because the water molecules stabilize their charge through hydration.

Ions and Hydration

  • Ions are atoms or molecules with a net electric charge.

  • Cations: net positive charge (examples: Na⁺, K⁺, Ca²⁺).

  • Anions: net negative charge (example: Cl⁻).

  • In water, ions dissociate and are surrounded by hydration shells; the individual ions are more attracted to water than to each other, forming a hydration sphere.

The Phospholipid Membrane

  • The membrane is a bilayer of phospholipids with a hydrophilic phosphate head (polar) facing water and a hydrophobic lipid tail (nonpolar) forming the interior.

  • Hydrophobic compounds and small uncharged polar molecules can pass through more easily than charged species.

  • Ion passage requires specific pathways in the membrane—typically transmembrane proteins.

Proteins and Amino Acids: Building Blocks for Membrane Transport

  • Proteins are built from amino acids and serve as enzymes, cytoskeleton components, receptors, channels, pumps, etc.

  • Amino acid properties determine mature structure, protein–protein interactions, and interactions with membranes.

  • R-groups (side chains) are unique and drive folding, localization, and function.

Why Would a Protein Be in a Membrane?

  • Amino acids that associate with lipids vs. water vs. charged molecules influence whether a protein embeds in the membrane or resides in the aqueous interior/exterior.

Is the Amino Acid Sequence THAT Important?

  • Ava’s case (context used in the lecture):

    • Her Na⁺/K⁺ pumps are mislocalized to the membrane (ICC showed mislocalization).

    • Her resting membrane potential (RMP) was abnormally high compared to healthy cells.

    • A possible link to the pump’s amino acid sequence being wrong, affecting trafficking and function.

The Na⁺/K⁺ Pump: Structure and Function

  • The Na⁺/K⁺ pump is an ion pump that uses ATP to move ions against their gradients:

    • 3 Na⁺ ions out of the cell per ATP hydrolyzed

    • 2 K⁺ ions into the cell per ATP hydrolyzed

  • The pump is a membrane-spanning protein complex composed of subunits (e.g., ATP1A1 as the alpha subunit; FXYD regulatory subunits exist).

  • The pump’s proper localization to the membrane is crucial for maintaining the resting membrane potential and ion homeostasis.

  • In Ava’s case, mislocalization of the pump would disrupt Na⁺/K⁺ balance and RMP.

Ion Channels vs Ion Pumps

  • Two main membrane-spanning protein types:

    • Ion pumps: consume ATP to move ions against their concentration gradients (e.g., Na⁺/K⁺ ATPase, Ca²⁺ pump).

    • Ion channels: allow ions to diffuse down their electrochemical gradients.

  • Channel types:

    • Voltage-dependent channels open/close in response to membrane potential changes.

    • Ligand-gated channels open/close in response to chemical binding.

  • Characteristics of ion pumps vs channels:

    • Pumps require ATP; channels do not.

    • Pumps move ions against gradients; channels permit passive diffusion down gradients.

    • Channels can be gated; pumps are typically always active (though regulated by cellular signals).

The Resting Membrane Potential: Conceptual Basis

  • Resting membrane potential (RMP) arises from the combined influence of water hydration, membrane permeability, and the distribution of ions across the membrane.

  • Water’s polarity and the inability of ions to move freely through the hydrophobic membrane interior necessitate membrane pathways for ion movement.

  • Specific membrane proteins create selective pathways that determine which ions move more readily.

  • The asymmetry in ion permeabilities and concentrations creates a charge separation across the membrane, establishing an RMP around -70 mV (value varies by neuron).

Nernst Equation: Ion-Specific Equilibrium Potentials

  • The Nernst equation gives the equilibrium potential for a single ion when the membrane is permeable only to that ion.

  • General form (at 37°C):
    E{ ext{ion}} = z imes rac{RT}{F} imes ext{ln}iggl( rac{[ ext{ion}]{ ext{out}}}{[ ext{ion}]_{ ext{in}}}iggr)

  • At 37°C, this is commonly simplified to:
    E{ ext{ion}} = 61.54 imes ext{log}{10}iggl( rac{[ ext{ion}]{ ext{out}}}{[ ext{ion}]{ ext{in}}}iggr)

  • Example: Potassium (K⁺) with typical concentrations shows a resting potential around -80 mV when the membrane were only permeable to K⁺.

  • For K⁺: EK = 61.54 imes ext{log}{10}iggl( rac{[ ext{K}^+]{ ext{out}}}{[ ext{K}^+]{ ext{in}}}iggr)

  • If [K⁺]out = 4 mM and [K⁺]in = 140 mM, then approximately:
    E_K
    oughly
    ightarrow -95 ext{ mV}

  • If [K⁺]out = 40 mM and [K⁺]in = 140 mM, then approximately:
    E_K
    oughly
    ightarrow -33 ext{ mV}

Driving Forces and Current: When Do I Move?

  • A current is generated only if three conditions are met:

    • There must be ions to carry charge (ions present).

    • There must be a passageway (an open/available ion channel).

    • There must be a driving force (concentration gradient and/or voltage).

  • The relation between current, conductance, and driving force:
    I{ ext{ion}} = g{ ext{ion}} (Vm - E{ ext{ion}})

  • In other words, Current = conductance × driving force. If there is no conductance or no driving force, there is no current.

Multiple Ions at Rest: Why Not Just EK or ENa?

  • At rest, multiple ions can move, but not all at their equilibrium potentials because:

    • The membrane is not exclusively permeable to one ion; it has finite permeabilities for several ions.

    • Channels are not always open; there's a baseline permeability for several ions.

  • The resting potential results from the weighted contribution of multiple ions with their respective permeabilities, not simply the sum of independent Nernst potentials.

Goldman-Hodgkin-Katz (GHK) Equation: A Multion View

  • When more than one ion can move at rest, the Goldman equation provides a more comprehensive prediction of Vm by accounting for charge, concentrations, and relative permeabilities:
    Vm = 61.54 imes ext{log}{10}iggl( rac{PK [K^+]{ ext{out}} + P{Na} [Na^+]{ ext{out}}}{PK [K^+]{ ext{in}} + P{Na} [Na^+]{ ext{in}}} iggr)

  • The membrane potential is pulled toward each ion’s equilibrium by its permeability:

    • Potassium permeability (PK) pulls Vm toward EK.

    • Sodium permeability (PNa) pulls Vm toward ENa.

  • Changes in permeability (e.g., channel opening/closing) alter Vm.

  • The full GHK form can include other ions (e.g., Cl⁻) with their permeabilities; the two-ion form is a common simplified version.

How the Goldman Equation Helps Predict the Resting Potential

  • If extracellular potassium concentration [K⁺]out is varied, Vm tends to depolarize (move toward 0 mV) as [K⁺]out increases.

  • The Nernst prediction for Vm when only K⁺ is permeable does not perfectly match actual Vm at rest because other ions (Na⁺, Cl⁻) still carry current.

  • In practice, Vm at rest lies somewhere between the individual ion equilibrium potentials, weighted by their relative permeabilities.

What Ion Sets the Resting Membrane Potential? A Practical View

  • If Na⁺ equilibrium is +62 mV and the resting Vm is around -68 to -70 mV, current arises from a combination of conductances for Na⁺ and K⁺.

  • The ion with the greatest driving force and highest conductance at rest contributes most to the resting current, but it is a balance of all permeant ions.

  • Example questions asked in the lectures:

    • With Vm at -68 mV and E_K ≈ -80 mV, which ion dominates the resting current given their conductances?

    • How does changing extracellular K⁺ alter the driving force for K⁺ and hence Vm?

Potassium Homeostasis in the Brain: Regulation of Extracellular [K⁺]

  • Mechanisms regulating external K⁺ concentration include:

    • The blood–brain barrier restricting ion movement between blood and brain tissue.

    • Potassium spatial buffering by astrocytes: astrocytes take up excess K⁺ and distribute it through their networks.

    • Astrocytes possess pumps to concentrate K⁺ intracellularly and can dissipate it through their extensive processes.

  • This buffering helps prevent excessive depolarization and maintains stable neuronal excitability.

Real-World Context: Learning, Ethics, and Applications

  • The lecture includes a slide on lethal injection to illustrate the physiological consequences of membrane potential disruption and rapid ion flow on vital functions (blood circulation, breathing, heart activity).

  • Understanding ion gradients and membrane potentials is foundational for pharmacology, neurology, and medical ethics discussions about interventions that alter neural activity.

Think, Pair, Share: Quick Review Questions

  • At rest, where are Na⁺ and K⁺ predominantly located relative to the cell?

  • What causes ions to move at rest?

  • Which ion moves the most at rest, and what is the resting membrane potential approximately?

  • How is the resting membrane potential maintained?

Nernst Equation: Quick Practice Revisit

  • For K⁺ (example):

    • If outside = 4 and inside = 140, then
      EK = 61.54 imes ext{log}{10}iggl( rac{4}{140}iggr)
      ightarrow ext{approximately } -95 ext{ mV}

  • If outside = 40 and inside = 140, then
    EK = 61.54 imes ext{log}{10}iggl( rac{40}{140}iggr)
    ightarrow ext{approximately } -33 ext{ mV}

Chapter 3 Learning Objectives ( summarized )

  • Describe ion channels versus pumps, and why some require ATP.

  • Explain the role of amino acids in protein structure and membrane interactions.

  • Describe electrochemical forces and membrane potential V(m).

  • Define diffusion vs. electrostatic (driving) forces.

  • Define equilibrium potential and driving force.

  • Explain when a membrane reaches an ion's equilibrium potential.

  • Understand current flow at EK (as an example).

  • Describe outcomes if an ion is not at its equilibrium potential and the factors that influence this.

  • Distinguish between Nernst and GHK potentials.

  • Explain how resting membrane potential is maintained and why it is around -70 mV (varying by neuron type).

  • Analyze how changing K⁺ or Na⁺ concentrations affects resting membrane potential and action potential.