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Carboxylic acids

  • All have -COOH functional group attached to the first carbon

  • Their general formula is CnH2n+1COOH

  • They dissolve in water and therefore are weakly acidic solutions

  • The 1st two are liquid @ r.t.p. (methanoic acid: nettle and ant stings, ethanoic acid: acid found in vinegar)

  • The suffix is -anoic acid

number of carbons

prefix

1

meth-

2

eth-

3

prop-

4

but-

Due to being weak, organic acids, they undergo the usual acid reactions.

1) acid + alkali → metal salt + water

ethanoic acid + sodium hydroxide → sodium ethanoate + water

CH3COOH + NaOH → CH3COONa + H2O

* note: the salt always ends in “-oate” (e.g. methanoic acid → methanoate)

2) acid + metal carbonate → metal salt + carbon dioxide + water

ethanoic acid + calcium carbonate → calcium ethanoate + carbon dioxide + water

CH3COOH + CaCO3 → (CH3COO)2Ca + CO2 + H2O

*this reaction occurs in the “descaling” of hard water/limescale

a diagram showing some of the basic carboxylic acids and their structure

ES

Carboxylic acids

  • All have -COOH functional group attached to the first carbon

  • Their general formula is CnH2n+1COOH

  • They dissolve in water and therefore are weakly acidic solutions

  • The 1st two are liquid @ r.t.p. (methanoic acid: nettle and ant stings, ethanoic acid: acid found in vinegar)

  • The suffix is -anoic acid

number of carbons

prefix

1

meth-

2

eth-

3

prop-

4

but-

Due to being weak, organic acids, they undergo the usual acid reactions.

1) acid + alkali → metal salt + water

ethanoic acid + sodium hydroxide → sodium ethanoate + water

CH3COOH + NaOH → CH3COONa + H2O

* note: the salt always ends in “-oate” (e.g. methanoic acid → methanoate)

2) acid + metal carbonate → metal salt + carbon dioxide + water

ethanoic acid + calcium carbonate → calcium ethanoate + carbon dioxide + water

CH3COOH + CaCO3 → (CH3COO)2Ca + CO2 + H2O

*this reaction occurs in the “descaling” of hard water/limescale

a diagram showing some of the basic carboxylic acids and their structure