Electron shells and atomic orbitals

Electron shells:

  • Formula for the number of electrons each shell can hold 2n^2
  • Electrons orbit the nucleus in energy levels or electron shells.
  • The energy level is determined by the principal quantum number (n).
  • The larger the value for n the further away from the nucleus the shell is and the higher the energy.
n (quantum number)shellnumber of electrons
11st2
22nd8
33rd18
44th32

Atomic orbitals:

  • Only two electrons can ever be in a single orbital
  • The two electrons must have opposite spins

The s-orbitals:

  • Spherical in shape
  • All shells contain an s-orbital
  • S-orbitals can hold 2 electrons

The p-orbitals:

  • 3D dumbbell shape
  • All shells from n=2 upwards contain 3 p-orbitals
  • There are three p orbitals px, py and pz

D and f-orbitals:

  • 5 d-orbitals (from n=3 upwards)
  • 7 f-orbitals (from n=4 upwards)
Shell (quantum no.)s (no. of orbitals)pdfMax electrons
11N/AN/AN/A2
213N/AN/A8
3135N/A18
4135732

Filling orbitals:

  • Lowest energy orbitals are filled first

  • Sub-shells are filled singly first

  • When all equal energy sub-shells contain one electron they pair up with another electron with an opposite spin