Chemistry Lecture Review
Chemistry Fundamentals
Chemistry is the study of matter and the changes it undergoes.
Matter is anything that occupies space and has mass.
Classification of Matter
Matter is broadly classified into Mixtures and Pure Substances.
Mixtures
A mixture is a combination of two or more substances in which the substances retain their distinct identities.
Mixtures can be separated into their pure components by physical methods.
Examples of physical separation means: distillation, magnets, strain (like straining pasta).
Types of Mixtures:
Homogeneous mixture: The composition of the mixture is the same throughout.
Examples: soft drink, milk, solder.
Heterogeneous mixture: The composition is not uniform throughout.
Examples: oil and water, cement, iron filings in sand.
Pure Substances
A substance is a form of matter that has a definite composition and distinct properties.
Examples: liquid nitrogen, gold ingots, silicone crystals.
Pure substances are classified into Elements and Compounds.
Elements
An element is a substance that cannot be separated into simpler substances by chemical means.
There are 117 elements that have been identified.
82 elements occur naturally on Earth (e.g., gold, aluminum, lead, oxygen, carbon, sulfur).
35 elements have been created by scientists (e.g., technetium, americium, seaborgium).
Table 1.1: Some Common Elements and Their Symbols
Aluminum (Al), Arsenic (As), Barium (Ba), Bismuth (Bi), Bromine (Br), Calcium (Ca), Carbon (C), Chlorine (Cl), Chromium (Cr), Cobalt (Co), Copper (Cu).
Fluorine (F), Gold (Au), Hydrogen (H), Iodine (I), Iron (Fe), Lead (Pb), Magnesium (Mg), Manganese (Mn), Mercury (Hg), Nickel (Ni), Nitrogen (N).
Oxygen (O), Phosphorus (P), Platinum (Pt), Potassium (K), Silicon (Si), Silver (Ag), Sodium (Na), Sulfur (S), Tin (Sn), Tungsten (W), Zinc (Zn).
Compounds
A compound is a substance composed of atoms of two or more elements chemically united in fixed proportions.
Compounds can only be separated into their component elements by chemical means (e.g. fluoride, quartz, dry ice - carbon).
The Three States of Matter
Matter can exist in different states: Solid, **Liquid__, and Gas (implied).
Types of Changes
Physical change: A change that does not alter the composition or identity of a substance.
Examples: Ice melting, sugar dissolving in water.
Chemical change: A change that alters the composition or identity of the substance involved.
Example: Hydrogen burns in air to form water.
Mass and Weight
Mass: A measure of the quantity of matter.
The SI unit of mass is the kilogram (kg).
Conversion: 1 \text{ Kg} = 1000 \text{ g} = 1 \times 10^3 \text{ g}.
Weight: The force that gravity exerts on an object.
Formula: \text{Weight} = c \times \text{mass}, where c is the acceleration due to gravity.
Example: A 1 \text{ Kg} bar weighs 1 \text{ Kg} on Earth (where c \approx 1.0) but weighs 0.1 \text{ Kg} on the Moon (where c \approx 0.1).
Derived SI Units
Volume
The SI derived unit for volume is the cubic meter (m³).
Density
The SI derived unit for density is kg/m
Ions
An ion is an atom, or group of atoms, that has a net positive or negative charge.
Cation
An ion with a positive charge.
Formed when a neutral atom loses one or more electrons.
Example: A neutral sodium atom (Na) has 11 protons and 11 electrons. If it loses one electron, it becomes a sodium cation (Na^+}) with 11 protons and 10 electrons, resulting in a net +1 charge.
Anion
An ion with a negative charge.
Formed when a neutral atom gains one or more electrons.
Example: A neutral chlorine atom (Cl) has 17 protons and 17 electrons. If it gains one electron, it becomes a chloride anion (Cl^-$) with 17 protons and 18 electrons, resulting in a net -1 charge.
Types of Ions
Monatomic ion: Contains only one atom.
Examples: Na^+ , Cl^-, Ca^{2+}, O^{2-}, Al^{3+}, N^{3-}.
Polyatomic ion: Contains more than one atom.
Examples: OH^- (hydroxide), CN^- (cyanide), NH4^+ (ammonium), NO3^- (nitrate).
Prefixes for Numerical Quantities
mono-: 1
di-: 2
tri-: 3
tetra-: 4
penta-: 5
hexa-: 6
hepta-: 7
octa-: 8
nona-: 9
deca-: 10$$
NO2 - Nitrite
NO3 - Nitrate
OH^- - Hydroxide
NH4+ - Ammonium
PO4³- - Phosphate
CO3²- - Carbonate
SO3²- - Sulfite
SO4²- - Sulfate
C2H3O2 - Acetate
HCO3- - Hydrogen Carbonate (Bicarbonate)