Chemistry Lecture Review

Chemistry Fundamentals

  • Chemistry is the study of matter and the changes it undergoes.

  • Matter is anything that occupies space and has mass.

Classification of Matter

  • Matter is broadly classified into Mixtures and Pure Substances.

Mixtures

  • A mixture is a combination of two or more substances in which the substances retain their distinct identities.

  • Mixtures can be separated into their pure components by physical methods.

    • Examples of physical separation means: distillation, magnets, strain (like straining pasta).

  • Types of Mixtures:

    • Homogeneous mixture: The composition of the mixture is the same throughout.

      • Examples: soft drink, milk, solder.

    • Heterogeneous mixture: The composition is not uniform throughout.

      • Examples: oil and water, cement, iron filings in sand.

Pure Substances

  • A substance is a form of matter that has a definite composition and distinct properties.

    • Examples: liquid nitrogen, gold ingots, silicone crystals.

  • Pure substances are classified into Elements and Compounds.

Elements
  • An element is a substance that cannot be separated into simpler substances by chemical means.

  • There are 117 elements that have been identified.

    • 82 elements occur naturally on Earth (e.g., gold, aluminum, lead, oxygen, carbon, sulfur).

    • 35 elements have been created by scientists (e.g., technetium, americium, seaborgium).

  • Table 1.1: Some Common Elements and Their Symbols

    • Aluminum (Al), Arsenic (As), Barium (Ba), Bismuth (Bi), Bromine (Br), Calcium (Ca), Carbon (C), Chlorine (Cl), Chromium (Cr), Cobalt (Co), Copper (Cu).

    • Fluorine (F), Gold (Au), Hydrogen (H), Iodine (I), Iron (Fe), Lead (Pb), Magnesium (Mg), Manganese (Mn), Mercury (Hg), Nickel (Ni), Nitrogen (N).

    • Oxygen (O), Phosphorus (P), Platinum (Pt), Potassium (K), Silicon (Si), Silver (Ag), Sodium (Na), Sulfur (S), Tin (Sn), Tungsten (W), Zinc (Zn).

Compounds
  • A compound is a substance composed of atoms of two or more elements chemically united in fixed proportions.

  • Compounds can only be separated into their component elements by chemical means (e.g. fluoride, quartz, dry ice - carbon).

The Three States of Matter

  • Matter can exist in different states: Solid, **Liquid__, and Gas (implied).

Types of Changes

  • Physical change: A change that does not alter the composition or identity of a substance.

    • Examples: Ice melting, sugar dissolving in water.

  • Chemical change: A change that alters the composition or identity of the substance involved.

    • Example: Hydrogen burns in air to form water.

Mass and Weight

  • Mass: A measure of the quantity of matter.

    • The SI unit of mass is the kilogram (kg).

    • Conversion: 1 \text{ Kg} = 1000 \text{ g} = 1 \times 10^3 \text{ g}.

  • Weight: The force that gravity exerts on an object.

    • Formula: \text{Weight} = c \times \text{mass}, where c is the acceleration due to gravity.

    • Example: A 1 \text{ Kg} bar weighs 1 \text{ Kg} on Earth (where c \approx 1.0) but weighs 0.1 \text{ Kg} on the Moon (where c \approx 0.1).

Derived SI Units

Volume

  • The SI derived unit for volume is the cubic meter (m³).

Density

  • The SI derived unit for density is kg/m

Ions

  • An ion is an atom, or group of atoms, that has a net positive or negative charge.

Cation

  • An ion with a positive charge.

  • Formed when a neutral atom loses one or more electrons.

  • Example: A neutral sodium atom (Na) has 11 protons and 11 electrons. If it loses one electron, it becomes a sodium cation (Na^+}) with 11 protons and 10 electrons, resulting in a net +1 charge.

Anion

  • An ion with a negative charge.

  • Formed when a neutral atom gains one or more electrons.

  • Example: A neutral chlorine atom (Cl) has 17 protons and 17 electrons. If it gains one electron, it becomes a chloride anion (Cl^-$) with 17 protons and 18 electrons, resulting in a net -1 charge.

Types of Ions

  • Monatomic ion: Contains only one atom.

    • Examples: Na^+ , Cl^-, Ca^{2+}, O^{2-}, Al^{3+}, N^{3-}.

  • Polyatomic ion: Contains more than one atom.

    • Examples: OH^- (hydroxide), CN^- (cyanide), NH4^+ (ammonium), NO3^- (nitrate).

Prefixes for Numerical Quantities

  • mono-: 1

  • di-: 2

  • tri-: 3

  • tetra-: 4

  • penta-: 5

  • hexa-: 6

  • hepta-: 7

  • octa-: 8

  • nona-: 9

  • deca-: 10$$

NO2 - Nitrite

NO3 - Nitrate

OH^- - Hydroxide

NH4+ - Ammonium

PO4³- - Phosphate

CO3²- - Carbonate

SO3²- - Sulfite

SO4²- - Sulfate

C2H3O2 - Acetate

HCO3- - Hydrogen Carbonate (Bicarbonate)