Chem: Ions, Compounds, and Atoms

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Flashcard Set: Chemistry Chapter 2 Review

Q: What does the atomic number represent?
A: The number of protons in an atom's nucleus.

Q: What is the mass number?
A: The sum of protons and neutrons in the nucleus.

Q: What does the symbol of an element represent?
A: The abbreviation of an element from the periodic table.

Q: How many protons does a neutral atom have?
A: Same as the atomic number.

Q: How many electrons does a neutral atom have?
A: Same as the number of protons.

Q: What is the average atomic mass?
A: The weighted average of all naturally occurring isotopes.

Q: What does the group name tell you?
A: The family of elements with similar chemical properties.

Q: What determines the charge of an ion?
A: The loss or gain of electrons.

Q: How do you determine the number of electrons in an ion?
A: Adjust the protons minus charge (e.g., Na⁺ has 11-1 = 10 electrons).


Isotopes

Q: How are isotopes of the same element alike?
A: They have the same number of protons and same chemical properties.

Q: How are isotopes of the same element different?
A: They have different numbers of neutrons, affecting mass.

Q: Symbol for chlorine-37?
A: 1737Cl^{37}_{17}Cl

Q: Symbol for carbon-12?
A: 612C^{12}_{6}C

Q: Symbol for oxygen-18?
A: 818O^{18}_{8}O

Q: Symbol for uranium-235?
A: 92235U^{235}_{92}U

Q: Symbol for hydrogen-3?
A: 13H^{3}_{1}H

Q: How do you find the number of neutrons in an isotope?
A: Mass number - atomic number.


Atomic Mass Calculation

Q: Formula for calculating atomic mass?
A: (Mass of Isotope 1×Abundance)+(Mass of Isotope 2×Abundance)(\text{Mass of Isotope 1} \times \text{Abundance}) + (\text{Mass of Isotope 2} \times \text{Abundance})

Q: What is the calculated atomic mass of carbon?
A: (12.000×0.9889)+(13.000×0.0111)(12.000 \times 0.9889) + (13.000 \times 0.0111).


Subatomic Particles

Symbol

Protons

Neutrons

Electrons

Charge

Location

p+p^+

1

0

0

+1

Nucleus

n0n^0

0

1

0

0

Nucleus

e−e^-

0

0

1

-1

Electron Cloud


Ions & Their Names

Q: Name of Ca²⁺?
A: Calcium ion

Q: Name of N³⁻?
A: Nitride ion

Q: Symbol for rubidium ion?
A: Rb⁺

Q: Symbol for sulfide ion?
A: S²⁻

Q: Symbol for lead (II) ion?
A: Pb²⁺

Q: Symbol for permanganate ion?
A: MnO₄⁻


Naming Ionic Compounds

Q: Name of BI₃?
A: Boron triiodide

Q: Name of HgCl₂?
A: Mercury(II) chloride

Q: Name of Rb₃PO₄?
A: Rubidium phosphate


Writing Ionic Formulas

Q: Formula for potassium phosphite?
A: K₃PO₃

Q: Formula for copper (II) chlorate?
A: Cu(ClO₃)₂

Q: Formula for zinc sulfide?
A: ZnS


Naming Molecular Compounds

Q: Name of PCl₅?
A: Phosphorus pentachloride

Q: Name of N₂O₄?
A: Dinitrogen tetroxide


Writing Molecular Formulas

Q: Formula for dinitrogen heptaphosphide?
A: N₂P₇

Q: Formula for carbon tetrabromide?
A: CBr₄

Q: Formula for tricarbon hexoxide?
A: C₃O₆


Hydrocarbons

Q: Name of an 8-carbon alkane?
A: Octane (C₈H₁₈)

Q: Name of a 3-carbon alkene?
A: Propene (C₃H₆)

Q: Name of a 1-carbon alkane?
A: Methane (CH₄)


Acids

Q: Name of H₂SO₃?
A: Sulfurous acid

Q: Formula for nitric acid?
A: HNO₃

Q: Formula for hydrochloric acid?
A: HCl

Q: Formula for hydroiodic acid?
A: HI


Hydrates

Q: What does the formula of a hydrate indicate?
A: It shows the water molecules attached to the compound (e.g., CuSO₄·5H₂O).


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Compounds (CH 2-5)

Notes

 

Compounds

Formation of compounds

Ionic compounds

Molecular compounds


Compounds- A chemical combination of two or more different elements joined together in a fixed proportion.


Ex.  H20, CaCO3, NaHCO3   


Types of compounds

  • Binary Compound: a compound containing two elements

Ex. NaCl, CaCl


  • Ternary Compound: compound containing MORE than two elements

Ex. KNO3, NH4OH 


Chemical formulas indicate the number and type of atoms present in a compound


  • A molecular formula shows the EXACT number of atoms of each element in the smallest unit of a substance H20


  • An empirical formula shows the simplest whole-number RATIO of the atoms in a substance


Molecular v. Empirical

  • For some compounds, the empirical formula is the SAME as the molecular formula

EX. CH4 (methane) and NaCl* (sodium chloride)


  * for all ionic compounds, their formula is their empirical formula- they do not form molecules


  • Different compounds can have the same empirical formula

EX. CH is the empirical formula for C2H2 (ethene) and C6H6 (benzene)


Formation of Compounds

Why do atoms combine? 

  • Atoms combine to achieve stability 


How are compounds formed?


  • Atoms must collide

  • The valance electrons of the colliding atoms interact






Valence electrons: Electrons located in the outermost energy levels of an atom


Octet Rule: Atoms will gain, lose, or share electrons in order to fill their outer energy level


  • Most atoms fill with 8 electrons (octet)

  • Hydrogen and Helium fill with 2 (exception)

  • A full valence shell results in chemical stability 

    • Achieve a mobile gas configuration 

  • Whether atoms will transfer electrons or share electrons depends on what atoms are involved


Transfer or Share? 


Metals and nonmetals will transfer electrons

  • ionic compound

  • ionic bond

  • Metals lose (become positive) and nonmetals gain electrons (become negative)



Nonmetals will share electrons with other nonmetals and metalloids

  • molecular compound 

  • Covalent bond



Properties of Compounds



Ionic 

Ex. NaCl 

Ionic bonds-strong bond/attraction between ions

High melting points

Brittle solide @ room temp

Electoryocltes

Soluble in water






TO BE STABLE # HAS TO BE 8


Molecular (Covalent)

Ex. CO2

Covalent bonds-weaker attractipn

Low melting points/boling points

solids/liquids/gases at room temp

Nonelectroyletes. 










Ionic Compound: A compound composed of ions


An ion is an atom, or group of atoms, that has a net positive or negative charge


  • cation – ion with a positive charge

If a neutral atom loses one or more electrons it becomes a cation. 


  • anion – ion with a negative charge

If a neutral atom gains one or more electrons it becomes an anion. 


A monatomic ion contains only ONE atom  (Na+ or Cl-)


A polyatomic ion contains more than one atom (HCO3-bicarbonate) (CN- Cyanide) (OH- hydroxide) 


Determining Charge

  • Ions have either gained or lost electrons in order to have a full valence

  • Typically 8 electrons


Using the valence for the atom, determine whether it is easier to gain or lose in order to make 8


Valence? 

  • Use the periodic table

  • Atoms in the same group have the same valence


(on the periodic table to show the valenece electrons) 








Charge? 


Naming Cations

  • If the charge is always the same (representative elements/Group A), just write the name of the element

    • K+  potassium ion\

    • ZINC 2+

    • SILVER 1+ (TRICK THAT WAINSCOTT JEWELRY IS HER NUMBER ONE CHOICE) 

      • ZINC AND SLIVER NEVER GET ROMAN NUMERALS. ZINC IS ALWAYS +2 AND SILVER IS ALWAYS 1+. NO ROMAN NUMERALS


  • Transition metals can have more than one type of charge, so we use Roman numerals to indicate what the charge is

    • Cr2+ chromium (II) ion

    • SN (TIN) +PB (LEAD) NEED A ROMAN NUMERAL


Name These

Al3+   

  • AL- ALUMINUM  ION

Ca2+     *CA- CALCIUM ION 

Fe3+     *Fe3+    IRON (III) ION 

Fe2+     *fE 2+ iRON (II) ION 


Naming Anions (DIFFERENT THEN CATIONS) 

  • Always the same

  • Change the element ending to -IDE

Ex.  F1- Fluorine

                                                     -ide Fluoride ion


Name These

Cl1-   

  • CHLPRODE ION

N3-

  • NITRIDE  ION

S2- 

  • SULFIDE ION

P3- 

  • PHOSFIDE  ION


Polyatomic Ions

  • Groups of atoms that are COVALENTLY_ bonded with an overall CHARGE

  • Easiest to just memorize 



Naming Ionic Compounds

  • often a metal + nonmetal

    • Simply name the ion

    • sodium chloride (NaCl), calcium carbonate (CaCO3), magnesium oxide (MgO), potassium bromide (KBr), aluminum chloride (AlCl3), iron (II) oxide (FeO), and copper (II) sulfate (CuSO4)


  • Transition metal ionic compounds

    • indicate charge on metal with numerals

    • iron(III) oxide (Fe2O3), copper(II) chloride (CuCl2), manganese(IV) oxide (MnO2), mercury(II) oxide (HgO), chromium(III) chloride (CrCl3), cobalt(II) bromide (CoBr2), and vanadium(V) fluoride (VF5). 

    • FE CL2


Write the names of the following

Na2Se

KCl 

CaSO4 

Ca3N2

Sc3P2 

PbO2

PbO 

(NH4)2O


Formulas of Ionic Compounds (GET FROM MS. SIEGAL)

The sum of the charges on the cation(s) and anion(s) in each formula unit must equal ________


To Determine the formula:

  1. Write the symbol of each ion including the charge

  2. Find the least common multiple (LCM) for the charges of the ions

3) Determine what factor* you must multiply each charge by in order to get the LCM

* This factor is the subscript in the formula





Molecular Compounds- Compounds that form molecules


Molecular (covalent) Compounds

  • Combination of nonmetals or nonmetals and metalloids

  • A molecule is an aggregate of two or more atoms in a definite arrangement held together by chemical bonds


A diatomic molecule contains only TWO atoms

Ex. H2, N2, O2, Br2, HCl, CO


A polyatomic molecule contains more than two atoms

Ex. O3, H2O, NH3, CH4


The Seven Diatomic Elements (must have two of the same element) 

Br2  I2  N2  Cl2  H2  O2  F2


Naming Molecular Compounds (Inorganic) 


  • Use prefixes to determine the number of atoms of each element present in a molecule

  • The last element always ends in -ide






Some guidelines…

  • The prefix “mono-” may be omitted for the first element in the formula

Ex. PCl3  is  phosphorus trichloride NOT monophosphorus trichloride


  • Avoid vowel combinations of “ao”; omit the ending “a” in the prefix

Ex. Dinitrogen Tetroxide NOT Tetraoxide


Name These

CCl4  carbon tetrachloride 

N2O dinitrogen monoxide 

SF6  sulfur hexafluoride 


Write formulas for these

Remember:  Use prefixes to tell you the number

Arsenic trichloride  ArCl3 

Dinitrogen pentoxide  N2O5 

Tetraphosphorus decoxide  P4 O10

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