Periodic Trends
Discusses trends such as size, volume, and radius of elements including Sodium (Na), Potassium (K), and Cesium (Cs).
Importance of arranging them in terms of increasing size to understand their properties.
Elements compared have different numbers of protons but the same number of electrons, affecting effective nuclear charge (Z_eff).
Effective Nuclear Charge:
Decreases as the actual positive charge (number of protons) increases.
Aluminum has the smallest size among the elements due to its higher number of protons compared to Sodium and Potassium.
Valence Electrons
Arrangement of elements with five valence electrons, differentiating between 3p and 4p orbitals.
4p orbitals are larger due to increasing principal quantum numbers.
As a general rule, elements with the same electron configuration but more protons will be smaller in size.
Steps for Comparing Ions with Different Charges:
Determine the electronic configuration of the ions.
Identify outlier ions with different electron counts or orbits.
Compare the number of protons—more protons generally mean smaller size for the same number of electrons.
Conceptual Questions:
Discussion around halogens and their sizes, emphasizing that smaller sizes yield larger lattice structures.
Comparison of Elements:
Elements discussed include Sodium (Na), Chlorine (Cl), Iodine (I), and Sodium Chloride (NaCl).
Sodium is identified as a metal (b) whereas Iodine is more compact and solid (a). Chlorine is a gas and thus is less packed.
Discusses the naming conventions for ions including sodium as a metal and how compounds like NaCl are structured.
Cation and Anion Naming:
Importance of naming ions correctly, with cations named first followed by anions.
Example: Chlorine changes to Chloride (Cl⁻) when named as an anion.
Nitrogen Ion:
Most stable ion for Nitrogen is N³⁻ (minus three) after gaining three electrons to achieve an octet.
Example: Lithium Sulfide (Li₂S):
Lithium is one of the alkaline metals with a +1 charge, while sulfur has a -2 charge.
To balance charges, two Lithium ions are needed for every Sulfide ion.
Elements and Octet Rule:
Discussion on transition metals like Indium, Tin, Thallium, and Lead that can form cations with multiple charges.
Naming convention for transition metals includes Roman numerals to denote their charge.
Charge of Sulfur:
Sulfur typically has a charge of -2, affirming its electron configuration and participation in ionic bonding.
Reinforces the importance of understanding charges for proper compound formation.