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Fullerenes and Carbon Nanotubes

Fullerenes and Carbon Nanotubes

Overview of Carbon Structures
  • Graphene and fullerenes are forms of carbon, distinct from diamond and graphite.

  • Graphene: A single layer of graphite, known as the thinnest material, only one atom thick.

  • Fullerenes: Molecules with hollow shapes, composed of carbon atoms in hexagonal arrangements, sometimes including pentagonal or heptagonal rings.

Properties of Graphene
  • Composed of strong covalent bonds between carbon atoms.

  • High melting point and extremely strong, making it a valuable material in industries.

  • Notable for conducting electricity well due to delocalised electrons that can move freely across its surface.

  • Applications:

    • Aerospace industry

    • Construction materials

    • Mobile devices

Carbon Nanotubes
  • Formed by rolling a layer of graphene into a cylinder.

  • Extremely high length-to-diameter ratios with lengths of several millimetres and widths of a few nanometres.

  • Mechanical properties:

    • High tensile strength, strong under tension, resist stretching.

    • Conduct electricity due to the presence of delocalised electrons.

  • Applications:

    • Nanotechnology

    • Electronics

    • Specialized materials

Fullerenes Explained
  • Fullerenes consist of carbon atoms in hollow shapes based on hexagonal rings.

  • Two prominent examples include:

    • Buckminsterfullerene (C60): The first discovered fullerene made up of 60 carbon atoms.

    • Spherical shape with strong covalent bonds.

    • Exhibits weak intermolecular forces, resulting in low melting point and slippery nature.

    • Potential uses include hydrogen storage for fuel cell vehicles and reducing bacterial growth in water systems.

Uses of Nanotubes
  • Conduct electricity, suitable for tiny electrical circuits in computer chips and electronic devices.

  • Can function as semiconductors or 'miniature wires' in electrical circuits.

  • Serve as components in industrial catalysts, enhancing reaction speed and efficiency due to large surface area.

  • Carbon nanotube fibres are exceptionally strong, utilized in composite materials that reinforce graphite and plastics:

    • Applications include sports equipment (e.g., tennis rackets, golf clubs), significantly strengthening the equipment without adding significant weight.

    • Nanotubes can be stronger than steel (16 times lighter than steel) while maintaining high tensile strength.

  • Future possibilities include the construction of tiny mechanical devices, molecular computers, and exceptionally strong materials.

Conclusion
  • Fullerenes and carbon nanotubes showcase the versatility and strength of carbon in various applications, ranging from consumer products to advanced technological innovations.