⚠️chem midterm study guide

1- states of matter

  • solid- fixed shape and volume, particles touching, not moving

  • liquid- fixed volume, unfixed shape, particles touching and moving a little

  • gas- no fixed volume or shape, particles far apart and moving a lot

  • plasma- no fixed volume or shape, particles far apart and moving a lot

shape

volume

particles

particles

solid

fixed shape

fixed volume

touching

not moving

liquid

unfixed shape

fixed volume

touching a little

moving a little

gas

unfixed shape

unfixed volume

far apart

moving a lot

plasma

unfixed shape

unfixed volume

far apart

moving a lot

1- properties of and changes in matter

  • physical property

  • anything you can see without changing the substance

  • ex. transparency, boiling point, density, elasticity, malleability, brittleness, melting point

  • chemical property

    • you can only see by changing the substance

    • ex. flammability, ability to rust, reactivity with vinegar

  • physical change

    • when the identity of the substance doesn’t change (reversible)

    • ex. shattering, melting, separating (sand from gravel), dissolving, mixing, evaporating

  • chemical change

    • when the identity of the substance changes (irreversible), during a chemical reaction

    • ex. rusting, bleaching, cooking, burning, exploding

  • extensive property

    • depends on how much matter there is

    • ex. mass, weight, volume

  • intensive property

    • doesn’t matter how much matter there is

    • ex. color, combustibility, density, melting point, malleability

chemical reaction

  • 5 signs:

    • formation of a gas

    • color change/ emission of light

    • odor change

    • temp change

    • formation of a precipitate

  • parts of a reaction

    • reactant, yield arrow, product. the compound on top of the yield arrow is the catalyst- it speeds up the reaction time.

Law of conservation of mass: in a closed system, mass cannot be created or destroyed

1- elements, compounds, and mixtures

Matter is classified into Pure Substances and Mixtures.

  • Pure Substance- only one type of molecule, ex. water. can be elements or compounds.

    • element- an atom with specific characteristics, ex. hydrogen, iron, copper

      • can be metals or nonmetals, can’t be broken down further

    • compound- a molecule made of different atoms, ex. H2O, Na2

      • can be broken down into molecules using chemical charges

      • can be molecular, ionic, or intermetallic compounds

  • ! ! pure substances can’t be broken down by physical means like distillation, filtration, chromatography, or evaporation ! !

  • Mixture- combo of 2 substances, not chemically bonded. can be solutions or heterogeneous mixtures. Can be separated through physical changes.

    • solution (aka homogenous)- a group of molecules that are evenly distributed, ex. gasoline, air, and soda

  • heterogeneous mixture- a solution that is unevenly distributed, ex. cereal/ milk, raisin bread

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2- precision and accuracy

  • precision- the extent to which a series of measurements of the same quantity made in the same way agree with each other, not necessarily accurate.

  • accuracy- the extent to which a measurement approaches the true value of a quantity

to find percent error: [(experimental - accepted) / accepted] * 100

to find percent error:

🔎 look at page #9 in binder

2- significant figures

any digit in a measurement that is known with certainty, plus one final digit that’s slightly estimated

  • rule 1- all nonzero digits are significant, ex. 254 has 3 sigfigs

  • rule 2- zeros in between nonzeros are significant, ex. 2001 has 4 sigfigs

  • rule 3- trailing zeros are only significant with a decimal after, ex. 2000.0 has 3 sigfigs

  • rule 4- zeros in front of a nonzero don’t count, regardless of decimal, ex. 00.0004 has 1 sigfig

rules of rounding

  • round up if trailing # is above 5………….. so 4566.89 rounded to 4 sigfigs is 4567

  • leave it alone if trailing # is below 5…… so 4564.45 rounded to 4 sigfigs is 4564

for math operations (x / + -)

  • always round according to the # with the least amount of decimal places (least accurate)

(10.3) x (0.01345) = 0.138535 → 0.139

🔎 **look at binder page #6,7,8,10 for more examples


2- scientific notation

  • used when numbers are super big or super small, like atoms or planets

  • numbers are written as a product (multiply) of 2 numbers, a **coefficient

** and 10 raised to a power.4500 →**4.5

** x 10³, coefficient is4.5coefficient must be from 1 - 9.**can’t be 10!!***if the # is greater than 10, exponent is positive and is = to the amount of spaces the decimal is moved left to write the # in scientific notation4.500 → 4.5 x 10³⤴⤴⤴ (move 3 times right, so power of 3)if the # is less than 10, the exponent wll be negative and is = to the amount of spaces the decimal is moved right.00012 → 1.2 x 10⁻⁴12 → 1.2 x 10¹.000,0007 → 7 x 10⁻⁷490 → 4.9 x 10²1000 →1 x 10³.987 → 9.87 x 10-¹1000 000 → 1 x 10⁶0.0375 → 3.75 x 10⁻²0.01 → 1 x 10⁻²596 → 5.96 x 10².001257 → 1.26 x 10⁻³0.000595 → 5.95 x 10⁻⁴2- density

mass**:

  • ** theamount of matter an object contains. Doesn’t change unless you add/remove matterfind with a balance, use grams

volume**:

  • ** theamount of space an object occupiesfind with liquid or a ruler, use mL for liquids or cm³ for solids or L for gases

density**:

** thecompactness of the molecules or particles of a substancemore compact molecules = greater densitythe relationship between an object’s mass and volume==mass== **/ volume = density

    • **remember:mL - volumeg - mass

g/mL org/cm³ org/L- density🔎 look at page # 17, 18, 19~~~~3- history of the atom

scientist/s

experiment/model

year

description/ discovery

Democritus/Dalton- the atom

n/a

1808

**billiards ball-

** small, hard sphereJJ Thompson- electrons

cathode ray tube

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**plum pudding-

** electron “plums“ in a positive “pudding“Ernest Rutherford- atom mostly empty space, nucleus, protons on nucleus

gold foil experiment

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**nuclear model-

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** nucleus with electron shellNiehls Bohr- atomic energy levelsBohr’s atomic model**planetary model-

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** electron shell is made of layers/orbitsHeisenberg & Schroedinger- electron cloud and orbitalsHeisenberg uncertainty principle**quantum model-

1932

** (electron cloud)- there’s certain waves in the cloud?? what??James Chadwick- neutronsquantum model w/ neutrons**modern model-

** discovered neutrons, current model used today🔎 look at page # 293- atomic structure

atom

  • the smallest particle of an element that still has the chemical properties of the element

nucleus

  • very small thing in the center of the atom

  • made of at least one proton (p+) and usually at least 1 neutron (n*)

  • surrounding the nucleus is a cloud of electrons (e-)

protons, neutrons, and electrons are called **Subatomic Particles

**protons (p+)

  • located in nucleus, positive charge, big and heavy

neutrons (n)*

  • located in nucleus, no charge, big and heavy

electrons (e-)

  • outside the nucleus, negative charge, tiny and light

3- isotopes and ions

isotopes

  • 2 atoms with different # of neutrons

  • protons never changes

  • neutrons can change

  • have the same atomic #, different mass #s

ions

  • an atom with a charge, # of electrons change

  • if atom loses electrons, atom is + and (vice versa)

  • protons, neutrons, atomic # and atomic mass stay the same

hyphen notation

  • (element name) dash (mass number)

  • ex. uranium-235

isotope notation (nuclear symbol)

  • top - mass #……….. bottom - atomic #

  • ex. U²³⁵₉₂ (pretend like that’s lined up)

nuclide- general term for a specific isotope of an element (probably don’t need to know this)

3- atomic #, atomic mass, mass number

**atomic #

** = protonsin a neutral atom, protons = electrons**mass #

** = protons + neutrons**atomic mass

** = the decimal in the element box**neutrons

** = mass # - atomic #electron configuration

periodic table

metals, nonmetals, and metalloids

periodic trends

valence electrons

cations and anions

nomenclature (ionic and molecular compounds; acids)

  1. **states of matter

  2. ****properties of and changes in matter

  3. ****elements, compounds, and mixtures

  4. precision and accuracysignificant figuresscientific notationdensityhistory of the atom

  5. ****atomic structure

  6. isotopes and ionsatomic #, atomic mass, mass numberelectron configurationperiodic table

  7. ****metals, nonmetals, and metalloids

  8. ****periodic trends

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