Acid-Base Titrations

Introduction

  • Titration curve: a graph of volume of base vs. pH, when an acid is titrated with the base.
  • We can also obtain titration curves for volume of ACID added to base, but we will omit those this term.
  • Three types of titrations

  

  1. Strong acid-strong base
  2. Weak acid-strong base
  3. Strong acid-weak base  -  not covered this term.
  • Equivalence Point: the point at which the moles of  acid = the moles of base. 
    •  Since  M x L = moles…
    • At the equivalence point    M x V acid  =   M x V base.
    • Polyprotic acids will have more than one equivalence point,  and the equation above will work only for the FIRST equivalence point. 

Strong Acid-Strong Base Titration

  • The pH is initially very low (only strong acid present).
  • Any titration curve can be considered to have four parts.

  

  1. Initial pH: before base is added. 

      1. For a strong acid, the pH is just – log[HA]  

  1. Acid range: the moles of acid > moles of base.  The pH depends on the molarity of the EXCESS moles of acid.
  2. Equivalence point: for strong acid- strong base, the pH=7
  3. Base range: beyond equivalence point.

      1. Moles base>moles acid.  2. The pH depends on the molarity of excess base.

  • Indicators are weak acids.
    • The weak acid is a different color than its conjugate base.