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Chapter 21: Chemical Reactions

Section 1: Chemical Changes

  • Describing Chemical Reactions

    • Chemical Reaction: a change in which one or more substances are converted into new substances.

    • Reactants: The substances that react.

    • Products: The new substances produced.

  • Conservation of Mass

    • The total mass of the products always equals the total mass of the reactants.

  • Writing Equations

    • Chemical Equation: a way to describe a chemical reaction using chemical formulas and other symbols.

    • Chemical equations make it easier to calculate the quantities of reactants that are needed and the quantities of products that are formed.

  • Unit Managers

    • Atoms are rearranged but never lost or destroyed.

    • Coefficients: represent the number of units of each substance taking part in a reaction.

    • Knowing the number of units of reactants enables chemists to add the correct amounts of reactants to a reaction.

    • Rust can seriously damage iron structures because it crumbles and exposes more iron to the air.

      • Unlike rust, aluminum oxide adheres to the aluminum surface, forming an extremely thin layer that protects the aluminum from further attack.

      • Copper is another metal that corrodes when it is exposed to air, forming a blue-green coating called a patina.

Section 2: Chemical Equations

  • Balanced Equations

    • The formulas in a chemical equation must accurately represent the compounds that react.

    • Balancing an equation doesn’t change what happens in a reaction—it simply changes the way the reaction is represented.

    • Balanced Chemical Equation: has the same number of atoms of each element on both sides of the equation.

Section 3: Classifying Chemical Reactions

  • Types of Reactions

    • Chemists have defined five main categories of chemical reactions: combustion, synthesis, decomposition, single displacement, and double displacement.

    • Combustion Reaction: occurs when a substance reacts with oxygen to produce energy in the form of heat and light.

      • Combustion reactions also produce one or more products that contain the elements in the reactants.

    • Synthesis Reaction: two or more substances combine to form another substance.

    • A decomposition reaction is just the reverse of a synthesis.

      • Decomposition Reaction: occurs when one substance breaks down, or decomposes, into two or more substances.

        • Most decomposition reactions require the use of heat, light, or electricity.

    • Single-Displacement Reaction: When one element replaces another element in a compound.

    • A metal will replace any less active metal.

    • Double-Displacement Reaction: the positive ion of one compound replaces the positive ion of the other to form two new compounds.

      • A double-displacement reaction takes place if a precipitate, water, or a gas forms when two ionic compounds in solution are combined.

    • Precipitate: an insoluble compound that comes out of solution during this type of reaction.

    • One characteristic that is common to many chemical reactions is the tendency of the substances to lose or gain electrons.

    • Oxidation: describes the loss of electrons

    • Reduction: describes the gain of electrons.

    • Chemical reactions involving electron transfer of this sort often involve oxygen, which is very reactive, pulling electrons from metallic elements.

    • The cause and effect of oxidation and reduction can be taken one step further by describing the substances after the electron transfer.

Section 4: Chemical Reactions and Energy

  • Chemical Reactions—Energy Exchanges

    • All chemical reactions release or absorb energy.

    • When most chemical reactions take place, some chemical bonds in the reactants are broken, which requires energy.

    • Bond formation releases energy.

  • More Energy Out

    • Exergonic Reactions: Chemical reactions that release energy.

      • Exergonic reaction produces visible light.

    • Exothermic Reaction: When the energy given off in a reaction is primarily in the form of heat.

      • Exothermic reactions provide most of the power used in homes and industries.

  • More Energy In

    • Endergonic Reactions: A chemical reaction that requires more energy to break bonds than is released when new ones are formed.

      • Electricity is often used to supply energy to endergonic reactions.

    • Endothermic Reaction: When the energy needed is in the form of heat

    • Catalyst: a substance that speeds up a chemical reaction without being permanently changed itself.

      • When you add a catalyst to a reaction, the mass of the product that is formed remains the same, but it will form more rapidly. The catalyst remains unchanged and often is recovered and reused.

    • Inhibitors: used to slow down a chemical reaction.

      • One thing to remember when thinking about catalysts and inhibitors is that they do not change the amount of product produced. They only change the rate of production.

Chapter 21: Chemical Reactions

Section 1: Chemical Changes

  • Describing Chemical Reactions

    • Chemical Reaction: a change in which one or more substances are converted into new substances.

    • Reactants: The substances that react.

    • Products: The new substances produced.

  • Conservation of Mass

    • The total mass of the products always equals the total mass of the reactants.

  • Writing Equations

    • Chemical Equation: a way to describe a chemical reaction using chemical formulas and other symbols.

    • Chemical equations make it easier to calculate the quantities of reactants that are needed and the quantities of products that are formed.

  • Unit Managers

    • Atoms are rearranged but never lost or destroyed.

    • Coefficients: represent the number of units of each substance taking part in a reaction.

    • Knowing the number of units of reactants enables chemists to add the correct amounts of reactants to a reaction.

    • Rust can seriously damage iron structures because it crumbles and exposes more iron to the air.

      • Unlike rust, aluminum oxide adheres to the aluminum surface, forming an extremely thin layer that protects the aluminum from further attack.

      • Copper is another metal that corrodes when it is exposed to air, forming a blue-green coating called a patina.

Section 2: Chemical Equations

  • Balanced Equations

    • The formulas in a chemical equation must accurately represent the compounds that react.

    • Balancing an equation doesn’t change what happens in a reaction—it simply changes the way the reaction is represented.

    • Balanced Chemical Equation: has the same number of atoms of each element on both sides of the equation.

Section 3: Classifying Chemical Reactions

  • Types of Reactions

    • Chemists have defined five main categories of chemical reactions: combustion, synthesis, decomposition, single displacement, and double displacement.

    • Combustion Reaction: occurs when a substance reacts with oxygen to produce energy in the form of heat and light.

      • Combustion reactions also produce one or more products that contain the elements in the reactants.

    • Synthesis Reaction: two or more substances combine to form another substance.

    • A decomposition reaction is just the reverse of a synthesis.

      • Decomposition Reaction: occurs when one substance breaks down, or decomposes, into two or more substances.

        • Most decomposition reactions require the use of heat, light, or electricity.

    • Single-Displacement Reaction: When one element replaces another element in a compound.

    • A metal will replace any less active metal.

    • Double-Displacement Reaction: the positive ion of one compound replaces the positive ion of the other to form two new compounds.

      • A double-displacement reaction takes place if a precipitate, water, or a gas forms when two ionic compounds in solution are combined.

    • Precipitate: an insoluble compound that comes out of solution during this type of reaction.

    • One characteristic that is common to many chemical reactions is the tendency of the substances to lose or gain electrons.

    • Oxidation: describes the loss of electrons

    • Reduction: describes the gain of electrons.

    • Chemical reactions involving electron transfer of this sort often involve oxygen, which is very reactive, pulling electrons from metallic elements.

    • The cause and effect of oxidation and reduction can be taken one step further by describing the substances after the electron transfer.

Section 4: Chemical Reactions and Energy

  • Chemical Reactions—Energy Exchanges

    • All chemical reactions release or absorb energy.

    • When most chemical reactions take place, some chemical bonds in the reactants are broken, which requires energy.

    • Bond formation releases energy.

  • More Energy Out

    • Exergonic Reactions: Chemical reactions that release energy.

      • Exergonic reaction produces visible light.

    • Exothermic Reaction: When the energy given off in a reaction is primarily in the form of heat.

      • Exothermic reactions provide most of the power used in homes and industries.

  • More Energy In

    • Endergonic Reactions: A chemical reaction that requires more energy to break bonds than is released when new ones are formed.

      • Electricity is often used to supply energy to endergonic reactions.

    • Endothermic Reaction: When the energy needed is in the form of heat

    • Catalyst: a substance that speeds up a chemical reaction without being permanently changed itself.

      • When you add a catalyst to a reaction, the mass of the product that is formed remains the same, but it will form more rapidly. The catalyst remains unchanged and often is recovered and reused.

    • Inhibitors: used to slow down a chemical reaction.

      • One thing to remember when thinking about catalysts and inhibitors is that they do not change the amount of product produced. They only change the rate of production.