Discussing nuclear physics and energy levels.
Importance of understanding notation.
Atoms consist of a central nucleus containing:
Neutrons (n)
Protons (p)
Electrons orbit the nucleus; their details are temporarily less relevant.
The nucleus is significantly smaller than the atomic structure, which is largely empty space.
General representation: Element X
Z (Atomic Number):
Located at the bottom.
Represents the number of protons in the nucleus.
Example: Helium (He) has 2 protons (Z = 2).
Mass Number:
Top number indicating the total number of nucleons (protons + neutrons).
Example: Helium has a mass number of 4 (2 protons + 2 neutrons).
Redundancy in notation:
Helium-4 vs Helium; atomic number is unnecessary if the element's name is known.
Electrons exist in quantized energy levels around the nucleus.
Electrons can be excited by:
Absorbing photons
Applying potential difference (e.g. in fluorescent lights).
Transitioning to lower energy levels results in photon emission.
The relation:
E = hf
E = energy of the photon
h = Planck’s constant (6.63 × 10^-34 J·s)
f = frequency of the photon (Hertz)
Photon energy is quantized and only exists in multiples of Planck's constant.
Various transitions possible between energy levels.
Transition from higher to lower energy results in emitted light.
Different photons emitted correspond to different energy differences:
Larger energy transition = higher frequency = different colors.
Allowed frequencies and wavelengths are specific to the atom's structure.
Wave equation relationship:
For light: c = fλ
c = speed of light
λ = wavelength
Rearranging gives the wavelength as
λ = hc/E
Inversely proportional; higher frequency = smaller wavelength.
Transition causing the smallest wavelength corresponds to the largest frequency and energy:
Use E = hf principle to find the largest energy transition for smallest wavelength.
Example highlighted: Transition A has the largest energy, therefore the smallest wavelength.