Chapters Covered: 4 + 5 on Solutions and Chemical Reactions
Reminder: Sections 4.1 – 4.3 were discussed in Chapter 3 in General Chemistry I.
Everyday Chemistry: Chemistry is present all around us, especially in culinary applications, such as baking.
Baking Insight: Many chemical reactions/processes occur during cookie baking, from mixing the ingredients to enjoying the final product.
Define and describe: solution properties, concentration units, and perform calculations.
Calculate solution concentrations, including Molarity, mass percentage, and parts-per-million.
Definition: Homogeneous mixtures consisting of a solute (minority component) and a solvent (majority component).
Common Usage: Aqueous solutions (water as solvent).
Concentrated vs Dilute: Relative terms indicating solute amount; quantitative analysis provided by Molarity (M).
Example provided: Preparing a solution based on molarity.
Example 1: Calculate the molarity of 75.6 g of acetic acid in 665 mL of vinegar.
Example 2: Determine grams of CaCl2 in 250.0 mL of a 0.200 M calcium chloride solution.
Concept: Diluting concentrated stock solutions to desired concentrations by adding solvent.
Key Insight: Dilution does not change the total moles of solute.
Dilution Equation: M1V1 = M2V2, applicable only to dilution of the same chemical.
Derive and balance equations from narrative reactions.
Definition: Written representation of a chemical reaction; reactants on left, products on right.
Balancing Requirement: Coefficients adjust to maintain atom equality.
Phases Notation: (s), (l), (g), (aq) indicating state of matter.
Special Symbols: Indicate conditions like heat (∆).
Define and classify common chemical reaction types.
Precipitation: Products create a solid from two aqueous solutions based on solubility rules.
Acid-Base: Acid reacts with base to create salt and water; follows net ionic equations reflecting core reactants.
Gas Evolution: Reactions where gas is produced in an aqueous solution.
Oxidation-Reduction (Redox): Involves electron transfer; oxidation is loss, reduction is gain.
Objectives: Predict products from precipitation and acid-base reactions.
Write reactants.
Split into ions.
Switch partners.
Apply solubility rules to predict formation of precipitate.
Compute oxidation states and balance reactions in various conditions.
Rules for determining oxidation numbers; oxidation states must be assigned to track electron transfer during reactions.
Mass Percentage: Common in products; formulated as: mass percentage = (mass of component/total mass of solution) x 100%.
Conversions: Used for practical applications, e.g., in consumer products.
Extremely low concentrations often represented as parts per million (ppm) or parts per billion (ppb).
Example highlighting the significant impact of chemical concentration on public health, illustrating ppm dangers.
Considerable chemistry occurs in daily life, including in baking cookies.
Understanding solutions and chemical reactions is crucial for both academic settings and real-life applications.