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Chapters_4___5_Chemical_Reactions_Libre_out_of_order

Chapters Overview

  • Chapters Covered: 4 + 5 on Solutions and Chemical Reactions

  • Reminder: Sections 4.1 – 4.3 were discussed in Chapter 3 in General Chemistry I.

Real-Life Chemistry

  • Everyday Chemistry: Chemistry is present all around us, especially in culinary applications, such as baking.

  • Baking Insight: Many chemical reactions/processes occur during cookie baking, from mixing the ingredients to enjoying the final product.

Solution Concentration and Dilution (Sections 4.1-4.3)

Objectives

  • Define and describe: solution properties, concentration units, and perform calculations.

  • Calculate solution concentrations, including Molarity, mass percentage, and parts-per-million.

Solutions

  • Definition: Homogeneous mixtures consisting of a solute (minority component) and a solvent (majority component).

  • Common Usage: Aqueous solutions (water as solvent).

Solution Concentration

  • Concentrated vs Dilute: Relative terms indicating solute amount; quantitative analysis provided by Molarity (M).

Solution Preparation

  • Example provided: Preparing a solution based on molarity.

Concentration Calculations

  • Example 1: Calculate the molarity of 75.6 g of acetic acid in 665 mL of vinegar.

  • Example 2: Determine grams of CaCl2 in 250.0 mL of a 0.200 M calcium chloride solution.

Solution Dilution

  • Concept: Diluting concentrated stock solutions to desired concentrations by adding solvent.

  • Key Insight: Dilution does not change the total moles of solute.

  • Dilution Equation: M1V1 = M2V2, applicable only to dilution of the same chemical.

Writing and Balancing Chemical Equations (Section 5.1)

Objectives

  • Derive and balance equations from narrative reactions.

Chemical Equations

  • Definition: Written representation of a chemical reaction; reactants on left, products on right.

  • Balancing Requirement: Coefficients adjust to maintain atom equality.

Additional Equation Information

  • Phases Notation: (s), (l), (g), (aq) indicating state of matter.

  • Special Symbols: Indicate conditions like heat (∆).

Types of Chemical Reactions (Sections 4.5, 4.6, 5.4)

Objectives

  • Define and classify common chemical reaction types.

Reaction Types

  1. Precipitation: Products create a solid from two aqueous solutions based on solubility rules.

  2. Acid-Base: Acid reacts with base to create salt and water; follows net ionic equations reflecting core reactants.

  3. Gas Evolution: Reactions where gas is produced in an aqueous solution.

  4. Oxidation-Reduction (Redox): Involves electron transfer; oxidation is loss, reduction is gain.

Predicting Chemical Reactions (Sections 5.2-5.3)

  • Objectives: Predict products from precipitation and acid-base reactions.

Steps for Prediction

  1. Write reactants.

  2. Split into ions.

  3. Switch partners.

  4. Apply solubility rules to predict formation of precipitate.

Oxidation-Reduction Reactions (Sections 5.5-5.6)

Objectives

  • Compute oxidation states and balance reactions in various conditions.

Assigning Oxidation States

  • Rules for determining oxidation numbers; oxidation states must be assigned to track electron transfer during reactions.

Mass Percentage and Concentration Conversions

  • Mass Percentage: Common in products; formulated as: mass percentage = (mass of component/total mass of solution) x 100%.

  • Conversions: Used for practical applications, e.g., in consumer products.

Very Dilute Solutions: ppm and ppb

  • Extremely low concentrations often represented as parts per million (ppm) or parts per billion (ppb).

Flint, MI Water Crisis Context

  • Example highlighting the significant impact of chemical concentration on public health, illustrating ppm dangers.

Summary

  • Considerable chemistry occurs in daily life, including in baking cookies.

  • Understanding solutions and chemical reactions is crucial for both academic settings and real-life applications.