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CHEM: LEC 1 Atoms & Bonds

DISREGARD THIS NOTE

Chemistry 1 Study Guide

Basic Chemistry

Basic Atomic Model

Element Notation

Rings = Energy Levels (can be labeled 1, 2, … or K, L, …)

Outermost Electron = Valence Electron

Outermost Ring = Valence Shell

X = C = Element Symbol

A = 12 = Mass Number = # of protons + # of neutrons

Z = 6 = # of protons = # of electrons

Electron Configuration

Sublevels

Orbitals

Number of Electrons

s

1

2

p

3

6

d

5

10

f

7

14

Oxidation Numbers

Description

Rules

Examples

Knowing the oxidation number and the charge of one of the elements in the compound allows us to solve for the charge of the other element,

Charge of H = +1

Charge of O = -2 (except for in hydrogen peroxide)

CO32-

Given: OX#O = -2; OX#Net = -2

Find: OX#C = ? = x

x + 3(-2) = -2

x - 6 = -2

x = -2 + 6

x = 4

H2O2

Given: OX#H = +1; OX#Net = 0

Find: OX#0 = ? = x

2(+1) + 2(x) = 0

2 + 2x = 0

2x = -2

x = -1

Isotopes vs. Ions

Isotopes

Ions

Same element but with a different number of neutrons

Same element but with a different number of valence electrons

Given: Mass Number = 12; # of protons = 6

# of protons & electrons = 6

# of neutrons = 12 - # of protons = 6

Given: Mass Number = 13; # of protons = 6

# of protons & electrons = 6

# of neutrons = 13 - # of protons = 7

Types of Bonds

Ionic Bond

Covalent Bond

Electron donating; between one nonmetal and metal

Electron sharing; between two nonmetals

Naming Compounds

Description

Rule

Example

Binary Compounds

(Compounds with two elements)

Cation + Anion in ide ending

K+ = Potassium (Cation)

O2- = Oxygen (Anion)

K2O = Potassium Oxide

Ternary/Tertiary Compounds (Compounds with three elements)

Cation + Anion

Na+ = Sodium (Cation)

PO43- = Phosphate (Anion)

Na3PO4 = Sodium Phosphate

Binary Acids

(Anion is NOT a compound)

Hydro + Anion in ic ending + Acid

H+ = Hydrogen (Cation)

Cl- = Chlorine (Anion)

HCl = Hydrochloric Acid

Acids with Anion in ate Ending

Anion in ic ending + Acid

H+ = Hydrogen (Cation)

SO42- = Sulfate (Anion)

H2SO4 = Sulfuric Acid

Acids with Anion in ite Ending

Anion in ous ending + Acid

H+ = Hydrogen (Cation)

NO2- = Nitrite (Anion)

HNO2 = Nitrous Acid

Covalent Compounds

(Compounds Composed of Only Nonmetals)

Use mono, di, tri, etc.

C = Carbon

O = Oxygen

CO = Carbon Monoxide

CO2 = Carbon Dioxide

Elements with Different Ions/Different Oxidation Numbers

Lower Oxidation Number = ous ending

Higher Oxidation Number = ic ending

Fe2+ = Ferrous

Fe3+ = Ferric

Pb2+ = Plumbous

Pb4+ = Plumbic

Compounds with a Different Number of Oxygen

Lower Oxygen Number = ite ending

Higher Oxygen Number = ate ending

PO33- = Phosphite

PO43- = Phosphate

Types of Reactions

Type

Description

Example

Single Displacement Reaction

Only one element in the compound is replaced by another

2 Al (s) + 6 HCl (g) → 2 AlCl3 (aq) + 3 H2 (g)

Double Displacement Reaction

Reactants and products switch their ions

3 NaOH (aq) + FeCl3 (aq) → 3 NaCl (aq) + Fe(OH)3 (s)

Combination Reaction/Synthesis

Two reactants result in one product

Na2O + H2 → 2 NaOH

Decomposition Reaction/Analysis

One reactant results in two products

2KClO3 (s) → 2 KCl (s) + 3 O2 (g)

EXP 2: SOLUTIONS, ACIDS, AND BASES

Chemical Formulas

Chemical Name

Chemical Formula

Chemical Name

Chemical Formula

Iodine

I2

Ferric Chloride

FeCl3

Sodium Thiosulfate

Na2S2O3

Chromic Sulfate

Cr2(SO4)3

Carbon Tetrachloride

CCl4

Calcium Chloride

CaCl2

Chloroform

CHCl3

Zinc Nitrate

Zn(NO3)2

Ethyl Alcohol

CH3CH2OH

Aluminum Sulfate

Al2(SO4)3

Glycerin

C3H8O3

Ammonium Hydroxide

NH4OH

Blue Vitriol (or Cupric Sulfate)

CuSO4

Acetic Acid

CH3COOH

Sodium Hydroxide

NaOH

Hydrochloric Acid

HCl

Ammonium Chloride

NH4Cl

Aluminum Shavings

Al

Marble Chips

CaCO3

A: Solubility of Solids in Liquids

Substance

Iodine

Sand

Table Salt

Sugar

Solubility in Water

Slightly Soluble

(Dissolved faster in chloroform)

Insoluble

Soluble

Soluble

B: Solubility of Liquids in Liquids

Substance

Ethyl Alcohol (CH3CH2OH)

Glycerine

Oil

Solubility in Water

Mixes with water meaning it is a miscible liquid

Does not mix with water, sinks to the bottom

Does not mix with water, remains at the top

C: Unsaturated, Saturated, & Supersaturated Solutions

Unsaturated

Saturated

Supersaturated

Occurred in steps…

  1. Take 1 mL H2O and add a crystal of Na2S2O3

  2. Add more crystals of Na2 S2O3

  3. Add more crystals of Na2 S2O3 and heat

  4. Allow solution to cool, add 1 crystal of Na2 S2O3

Occurred in steps…

  1. Take 1 mL H2O and add a crystal of Na2S2O3

  2. Add more crystals of Na2 S2O3

  3. Add more crystals of Na2 S2O3 and heat

  4. Allow solution to cool, add 1 crystal of Na2 S2O3

Occurred in steps…

  1. Take 1 mL H2O and add a crystal of Na2S2O3

  2. Add more crystals of Na2 S2O3

  3. Add more crystals of Na2 S2O3 and heat

  4. Allow solution to cool, add 1 crystal of Na2 S2O3

D: Exothermic & Endothermic Reactions

Exothermic

Endothermic

Energy RELEASING reaction; solution becomes WARMER

Energy ABSORBING reaction; solution becomes COLDER

Occurred when 10mL H2O added to NaOH (s)

Occurred when 10mL H2O added to NH4Cl (s)

E.a: Properties of Acids & Bases

Taste

Litmus Paper

Indicator

Acetic Acid (CH3COOH)

Sour, vinegar-like

Blue → Red

Methyl Orange (Neon Pink)

Hydrochloric Acid (HCl)

Astringent (dry), less sour

Blue → Red

Methyl Orange (Neon Pink)

Ammonium Hydroxide (NH4OH)

Bitter, acrid (strong & sharp)

Red → Blue

Phenolphthalein (Dark Pink)

Sodium Hydroxide (NaOH)

Bitter

Red → Blue

Phenolphthalein (Light, Clear Pink)

E.b: Relative Activity of Acids

Reacts faster with Al?

Reacts faster with CaCO3?

CH3COOH

NO

HCl

YES

6 HCl (aq) + 2 Al (s) → 2 AlCl3 (aq) + 3 H2 (g)