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Periodic Table and Element Families

Family 1A: Alkali Metals

  • Discussion of Group 1 metals, referred to as alkali metals including lithium, sodium, potassium, rubidium, cesium, and francium.

  • Reactivity of Group 1 Metals:

    • Highly reactive due to low ionization energies.

    • Stored in kerosene or mineral oil to prevent reactions with oxygen and moisture in air.

Lithium (Li)
  • Appearance: Dull gray due to oxide/nitride coating.

  • Physical Properties: Soft, can be cut with a knife.

  • Conductivity: Excellent conductor of electricity.

  • Reactivity with water: Floats, undergoes a single displacement reaction producing hydrogen gas and lithium hydroxide.

  • Indicator: Use of phenolphthalein turns pink in the presence of lithium hydroxide.

Sodium (Na)
  • Stored similarly under mineral oil to limit oxygen reaction.

  • Appearance: Coated in oxide, much softer than lithium.

  • Reactivity: Rapid reaction with water resulting in hydrogen gas production.

  • Visualization: Metal moves across the surface due to hydrogen gas, exothermic reaction melts sodium, producing sodium hydroxide (indicated by phenolphthalein).

Potassium (K)
  • Stored under mineral oil, coated with gray oxide.

  • Extremely soft, can be easily flattened.

  • Very rapid reaction with water, more vigorous than sodium.

  • Products include potassium hydroxide; identified similarly using phenolphthalein.

General Trends in Group 1A (Alkali Metals)
  • As you move down the group:

    • Reactivity increases.

    • Softness increases.

    • Ionization energy decreases.

Family 2A: Alkaline Earth Metals

  • Discussed properties of alkaline earth metals such as magnesium.

  • Reactivity: Increases across the period; higher ionization energy than group one.

    • Magnesium (Mg):

    • Appearance: Shiny surface, conducts electricity, sinks in water.

    • Reactivity: Slow at room temperature with water; reaction speeds up when heated, eventually producing magnesium hydroxide and steam.

    • Naming Convention: Known as alkaline earth metals, producing highly soluble hydroxides.

Trends in 2A Behaviors
  • Going down the family, elements become more metallic and active.

  • Transition from low reactivity in magnesium (higher ionization energy than sodium) to more vigorous reactions in heavier alkaline earth metals.

Family 8A: Noble Gases

  • Named inactive due to their low reactivity; termed "noble" since they don’t combine easily with other elements.

  • Uses of noble gases like argon in light bulbs to prevent oxidation of filaments.

  • Uses in flash photography, welding (for preventing oxidation), and safety in balloons (helium over hydrogen).

Family 7A: Halogens

  • Elements known for forming salts; includes fluorine, chlorine, bromine, and iodine (with radioactive astatine).

  • Represent phases: gas (F2, Cl2), liquid (Br2), solid (I2).

    • Unique in having all three states within one family.

Sublimation of Iodine
  • Demonstrative properties of iodine showcasing sublimation (change from solid to gas).

  • Deposition when heated and subsequently cooled, leading to colored crystals being formed.

Metal, Non-metal, and Metalloid Classification

  • Segmentation in the periodic table by a jagged black line distinguishing metals and nonmetals, with metalloids located nearby.

  • Metalloid characteristics: electrical conductivity, luster, malleability versus brittleness; notable behaviors regarding conductivity.

  • Conductivity Behavior:

    • Metals: Higher temperature increases resistance; thus, less conductivity.

    • Nonmetals: Higher temperature decreases resistance; thus, better conductivity.

Transition Elements

  • Found in the middle of the periodic table, they possess variable oxidation states, leading to complexity in prediction of their properties relative to other elements.

  • Colorful compounds enhance their visual appeal in experiments compared to more common elements.

    • Noteworthy that transition metal ions often result in vivid colors depending on oxidation state.

  • Formation of Complex Ions (e.g., copperammonia complex).

Lanthanides and Actinides

  • Positioned below the main table; lanthanides often referred to as rare earth metals due to similar chemistries leading to co-occurrence.

    • Notable use in creating strong magnets and other industrial applications.

  • Actinides: Radioactive elements with limited examples in nature (e.g., Uranium, Thorium).

    • Majority are synthetic and carry hazardous implications.

Predictive Power of the Periodic Table

  • Illustrated through predictions of chemical formulas based on family characteristics.

  • Limitations of the Table:

    • Original atomic weight-based organization flawed; with noted exceptions.

    • Hydrogen’s ambiguous classification across different groups.

    • First family members’ deviation from trends noticed with subsequent members.

Conclusion

  • Upcoming lectures to explain the scientific reasons behind trends and behaviors of elements concerning atomic structure.

  • Reference toward structure of atoms will further elucidate periodic trends in chemistry.