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Chapter13:Acid and Bases 

Arrhenius concept - acids produce hydrogen ions in aqueous solution, while bases produce hydroxide ions
Brønsted–Lowry model - an acid is a proton (H+) donor, and a base is a proton acceptor

conjugate base - everything that remains of the acid molecule after a proton is lost
conjugate acid - formed when the proton is transferred to the base
conjugate acid–base pair - two substances related to each other by the donating and accepting of a single proton

13.1 Molecular model

 13.2 Equilibrium expressionKa - acid dissociation constant

Brønsted–Lowry model is not limited to aqueous solutions but also reactions in gas phase

Acid strength - equilibrium position of its dissociation(ionization) reaction

strong acid - equilibrium lies far to the right

weak acid - equilibrium lies far to the right
”strong acid yields a weak conjugate base”

13.4 completely ionized vs mostly undissociated

diprotic acid - acid having two acidic protons

ex. H2SO4
oxyacids - acidic proton is attached to an oxygen atom

ex. H3PO4, HNO2, HOCL

Organic acids - acids with a carbon atom backbone, commonly contain the carboxyl group
ex. acetic acid (CH3COOH), benzoic acid (C6H5COOH)

monoprotic acids - acid having one acidic protons

Ka values of Common monoprotic acids

Vinegar contains acetic acid and is used in salad dressings. What if acetic acid was a strong acid instead of a weak acid? Would it be safe to use vinegar as a salad dressing?


amphoteric - can behave either as an acid or as a base
Water is the most common amphoteric substance

autoionization of waterKw - ion-product constant (or the dissociation constant for water)

a neutral solution, where H = OH

an acidic solution, where H > OH

a basic solution, where H < OH

Value of Kw at water at 25C

pH scale - represent solution acidity
pH formula and vice versaacid–base equilibria - must focus on the solution components and their chemistry
”focus on the major species, those solution components present in relatively large amounts”\

  1. PROBLEM SOLVING STRATEGY (Solving Acid-Base and Equilibrium Problems)

PROBLEM SOLVING STRATEGY (Solving Weak Acids and Equilibrium Problems)

Calcium hydroxide, Ca(OH)2, often called slaked lime

“Kb always refers to the reaction of a base with water to form the conjugate acid and the hydroxide ion“
Values of Kb for some common weak bases

polyprotic acid always dissociates in a stepwise manner, one proton at a time

triprotic acid - acid having three acidic protons

Stepwise dissociation constants for common polyprotic acids

What if the three values of Ka for phosphoric acid were closer to each other in value? Why would this complicate the calculation of the pH for an aqueous solution of phosphoric acid?

Salt or ionic compound

Salts that consist of the cations of strong bases and the anions of strong acids have no effect on [H+] when dissolved in water

salts in which the anion is not a base and the cation is the conjugate acid of a weak base produce acidic solutions

Acid-base properties of Various Type of Salts Oxyacids and their Ka valuesLewis Acid-base model - An even more general model for acid–base behavior
Lewis acid - an electron-pair acceptor

Lewis base - an electron-pair donor
Three models of Acids and Bases Chap13 pg572

common ion effect - shift in equilibrium position that occurs because of the addition of an ion already
involved in the equilibrium reaction
buffered solution - resists a change in its pH when either hydroxide ions or protons are added
effect of buffer solution

acid dissociation equilibrium expression Henderson–Hasselbalch equation

buffering capacity - amount of protons or hydroxide ions the buffer can absorb without a significant change in pH

“The pH of a buffered solution is determined by the ratio [A-]y[HA]. The capacity of a buffered solution is determined by the magnitudes of [HA] and [A-]“

pKa of the weak acid to be used in the buffer should be as close as possible to the desired pH




















Chapter13:Acid and Bases 

Arrhenius concept - acids produce hydrogen ions in aqueous solution, while bases produce hydroxide ions
Brønsted–Lowry model - an acid is a proton (H+) donor, and a base is a proton acceptor

conjugate base - everything that remains of the acid molecule after a proton is lost
conjugate acid - formed when the proton is transferred to the base
conjugate acid–base pair - two substances related to each other by the donating and accepting of a single proton

13.1 Molecular model

 13.2 Equilibrium expressionKa - acid dissociation constant

Brønsted–Lowry model is not limited to aqueous solutions but also reactions in gas phase

Acid strength - equilibrium position of its dissociation(ionization) reaction

strong acid - equilibrium lies far to the right

weak acid - equilibrium lies far to the right
”strong acid yields a weak conjugate base”

13.4 completely ionized vs mostly undissociated

diprotic acid - acid having two acidic protons

ex. H2SO4
oxyacids - acidic proton is attached to an oxygen atom

ex. H3PO4, HNO2, HOCL

Organic acids - acids with a carbon atom backbone, commonly contain the carboxyl group
ex. acetic acid (CH3COOH), benzoic acid (C6H5COOH)

monoprotic acids - acid having one acidic protons

Ka values of Common monoprotic acids

Vinegar contains acetic acid and is used in salad dressings. What if acetic acid was a strong acid instead of a weak acid? Would it be safe to use vinegar as a salad dressing?


amphoteric - can behave either as an acid or as a base
Water is the most common amphoteric substance

autoionization of waterKw - ion-product constant (or the dissociation constant for water)

a neutral solution, where H = OH

an acidic solution, where H > OH

a basic solution, where H < OH

Value of Kw at water at 25C

pH scale - represent solution acidity
pH formula and vice versaacid–base equilibria - must focus on the solution components and their chemistry
”focus on the major species, those solution components present in relatively large amounts”\

  1. PROBLEM SOLVING STRATEGY (Solving Acid-Base and Equilibrium Problems)

PROBLEM SOLVING STRATEGY (Solving Weak Acids and Equilibrium Problems)

Calcium hydroxide, Ca(OH)2, often called slaked lime

“Kb always refers to the reaction of a base with water to form the conjugate acid and the hydroxide ion“
Values of Kb for some common weak bases

polyprotic acid always dissociates in a stepwise manner, one proton at a time

triprotic acid - acid having three acidic protons

Stepwise dissociation constants for common polyprotic acids

What if the three values of Ka for phosphoric acid were closer to each other in value? Why would this complicate the calculation of the pH for an aqueous solution of phosphoric acid?

Salt or ionic compound

Salts that consist of the cations of strong bases and the anions of strong acids have no effect on [H+] when dissolved in water

salts in which the anion is not a base and the cation is the conjugate acid of a weak base produce acidic solutions

Acid-base properties of Various Type of Salts Oxyacids and their Ka valuesLewis Acid-base model - An even more general model for acid–base behavior
Lewis acid - an electron-pair acceptor

Lewis base - an electron-pair donor
Three models of Acids and Bases Chap13 pg572

common ion effect - shift in equilibrium position that occurs because of the addition of an ion already
involved in the equilibrium reaction
buffered solution - resists a change in its pH when either hydroxide ions or protons are added
effect of buffer solution

acid dissociation equilibrium expression Henderson–Hasselbalch equation

buffering capacity - amount of protons or hydroxide ions the buffer can absorb without a significant change in pH

“The pH of a buffered solution is determined by the ratio [A-]y[HA]. The capacity of a buffered solution is determined by the magnitudes of [HA] and [A-]“

pKa of the weak acid to be used in the buffer should be as close as possible to the desired pH