Chemistry Lecture Notes Review

Chemistry Basics

  • Chemistry is defined as the study of chemicals, specifically atoms and molecules.

Atoms

  • Atoms are the basic units of chemistry; they are extremely small, fundamental objects that make up all matter.
  • Atoms are composed of three types of particles:
    • Protons: Positively charged particles.
    • Neutrons: Neutrally charged particles.
      • Both protons and neutrons are located in the nucleus, which is the central part of the atom.
    • Electrons: Negatively charged particles that orbit the nucleus.

Elements

  • Elements are different types of atoms.
  • They are distinguished from one another based on the specific number of protons found within the atom's nucleus.
  • Elements are denoted using a one or two-letter symbol.
  • All known elements are listed on the periodic table.
  • Examples:
    • Any atom with 19 protons is considered Potassium (K).
    • Any atom with exactly 13 protons is Aluminum (Al).

Ions

  • Ions are chemicals (atoms or molecules) that have an unequal number of protons and electrons, resulting in a net electrical charge.
  • They are referred to as "charged chemicals".
  • The charge of an ion is indicated by a positive or negative number written in superscript above the elemental symbol.
    • Cations: Positively charged chemicals. They have more protons than electrons (or fewer electrons than protons).
      • Example: Al^{3+} indicates an aluminum ion with 3 more protons than electrons.
    • Anions: Negatively charged chemicals. They have more electrons than protons (or fewer protons than electrons).
      • Example: N^{3-} indicates a nitrogen ion with a -3 charge, meaning it has 3 more electrons than protons. An atom of nitrogen normally has 7 protons, so N^{3-} has 10 electrons.
      • Example: O^{2-} indicates an oxygen ion with a -2 charge, meaning it has 2 more electrons than protons. An atom of oxygen normally has 8 protons, so O^{2-} has 10 electrons.

Molecules

  • Molecules are chemicals formed when two or more atoms are chemically bonded together.
  • They are denoted using elemental symbols written next to each other.
  • Numbers written in subscript indicate the number of each atom of the element to their left.
  • Examples:
    • H_{2}O: A water molecule, composed of 2 Hydrogen atoms and 1 Oxygen atom, for a total of 3 atoms.
    • H{2}O{2}: A hydrogen peroxide molecule, composed of 2 Hydrogen atoms and 2 Oxygen atoms, for a total of 4 atoms.
    • O^{2+}: Represents a charged molecule with 1 more electron than protons (likely a typo in the original for O^{2+} vs O^{+} given the example of 8 protons + 1 electron making it O^{-} for 8 protons and 9 electrons, or 7 protons and 8 electrons for O^{+}). Assuming the intent from the image was a charged species with an imbalance.

Chemical Bonds

  • Chemical bonds are the forces or attractions that hold molecules together.
  • There are four types of molecules, but two common types of chemical bonds are discussed:

A. Ionic Bonds

  • Ionic bonds are formed between a cation (positively charged ion) and an anion (negatively charged ion).
  • When a cation and an anion come within close proximity, their opposite charges attract each other, causing them to stick together and form a molecule held by an ionic bond.
  • Examples:
    • Na^{+} (sodium cation) + Cl^{-}(chloride anion) $\rightarrow$ NaCl (sodium chloride molecule, table salt).
    • Na^{+} (sodium cation) + OH^{-}(hydroxide anion) $\rightarrow$ NaOH (sodium hydroxide molecule, lye).

B. Covalent Bonds

  • Covalent bonds form when neighboring atoms share electrons.
  • These bonds are established as electrons orbit around neighboring atoms, leading to shared electron density that holds the atoms together.
  • Examples:
    • N_{2} (nitrogen molecule): Formed by two nitrogen atoms sharing electrons. This is an example of a nonpolar covalent bond.
    • H_{2}O (water molecule): Formed by hydrogen and oxygen atoms sharing electrons. This is an example of a polar covalent bond.
  • Two types of covalent bonds exist:
    • Nonpolar Covalent Bonds: Occur when electrons are shared equally between two neighboring atoms. The electrons spend equal amounts of time orbiting both atoms.
    • Polar Covalent Bonds: Occur when there is an unequal sharing of electrons between neighboring atoms. Electrons spend more time orbiting one atom than the other, leading to a partial negative charge on the atom attracting more electrons and a partial positive charge on the other atom.

Compounds

  • A compound is a molecule made up of two or more different types of elements.
  • Examples:
    • H_{2}O (water)
    • NaCl (sodium chloride)

Chemical Reactions

  • A chemical reaction involves the formation, breakdown, or rearrangement of chemical bonds and/or molecules.
  • An arrow between chemical names or formulas indicates that a reaction is occurring.
  • Reactants: Chemicals located to the left of the arrow.
  • Products: Chemicals located to the right of the arrow.
  • A plus sign (+) between two chemicals (reactants or products) means that the chemicals are separate.
  • Examples:
    • A + B $\rightarrow$ AB (A and B are reactants, AB is the product).
    • H{2} + O $\rightarrow$ H{2}O (Hydrogen and Oxygen are reactants, Water is the product).

Mixtures

  • Mixtures are created when two or more chemicals are present and mixed together.
  • There are two basic types of mixtures:
    • Heterogeneous Mixture: Occurs when components or chemicals are distributed unequally within the mixture.
      • Example 1: Soil, where different components like sand, clay, and organic matter are not uniformly distributed.
      • Example 2: Salt and water where the salt has not fully dissolved or clumped unevenly.

Solubility in Water

  • Molecules containing one or more covalent bonds are generally able to dissolve in water.
  • Molecules made up only of non-covalent interactions (the transcript seems to indicate 'non covalent won't dissolve', this phrasing is a bit ambiguous, but generally polar covalent bonds are necessary for water solubility to form hydrogen bonds, while purely nonpolar covalent molecules like oils do not dissolve).
  • Molecules containing ionic bonds are commonly known as "salts". When mixed with water (H_{2}O), molecules with ionic bonds will typically dissolve.