Tempera: a permanent, fast-drying painting medium consisting of colored pigments mixed with a binder medium, usually glutinous material such as egg yolk, or any other oil medium.
Tempera paints: oil-based paints which can be diluted with water and which form an insoluble film on drying.
Unlike in oil paints, tempera paints use oil as the binder, but the oil is homogeneously mixed with water to form an emulsion.
Formation of such emulsions require the presence of an emulsifier or stabilizer.
Emulsions: stable mixtures of two immiscible liquids distributed uniformly in each other. Formation of such emulsions require the presence of an emulsifier or stabilizer.
Emulsifier: usually a long molecule that is partially ionic at one end, so called head (so this end dissolves well in water) and molecular with only covalent bonds in the rest of the molecule (so this part dissolves well in oil).
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Tempera paintings are very long-lasting, and examples from the first century AD still exist. Egg tempera was a primary method of painting until after 1500 when it was superseded by the invention of oil painting.
Water colors: made from very finely ground pigments suspended in water, usually with gum Arabic serving as a binder.
Gouache paints: opaque water colors.
The proportion of pigments to paint vehicle is much greater (sometimes up to 50% of the paint is the pigment – expensive!).
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