15.1 greenhouse gases and 15.2 introducing properties of gases

  • PV=nRT

  • Natural greenhouse gases- CO2 (Carbon dioxide), CH4 (methane), H2O (water)

  • These gases naturally have the ability to absorb and re-emit infrared radiation and heat energy from the sun. 

  • Infrared radiation hits a molecule like carbon dioxide and causes the covelent bonds to vibrate

  • Molecule then re-emits the infrared heat energy in all directions, with some energy going to space, but less than what would of escaped if the atmosphere and its greenhouse gases weren’t present

  • This results in some of the sun's heat energy being trapped in the lower atmosphere, making earth warmer than it would be otherwise

  • Human activities have led to the buildup of extra greenhouse gases in the atmosphere, resulting in a average surface temperature rising as a faster rate than ever called global warming

  • Agriculture, forestry, industry, energy supply, waste and waste water, transportation, commercial buildings, residential buildings, electricity supply, heat supply, livestock and other reasions are activities that increase the greenhouse gas emissions

  • Gasgses that make up out atmosphere have significance in maintaining a suitable clomate for life through the greenhouse effect

  • Gases differ significantly from liquids and solids in terms of volume, shape, compressibilty and ability to mix

  • The particles within a gas can be modelled by the ideal gas approximation

  • Pressure (p) is a property of gas and can be expressed in a number of units

  • Gas : a substance with no fixed shape or volume

  • We assume that The molecules within a gas experience no intermolecular forces, have no volume individually, and exchange no energy when a collision occurs

  • Pressure (p) : the forces exerted by a gas on the walls of the container enclosing it

  • Quantify pressure by identifying the force exerted by the gas per the unit area of the container

  • Pressure(Pa) = Force (N)/area (m^2) 

  • Area is interior surface area of the container that gas collides with

  • 100kPa = 100000Pa = 0.987 atm (weight of the atmosphere above us) (Pa = Pascal)

  • The Standard laboratory conditions (SLC) provides consistent standards under which experiments are conducted

  • The conditions are: temperature of 298K (25C) and Pressure of 100kPa (100000Pa or 0.987atm)

  • Molar volume is the volume of one mole of substance specified at a given temperature and pressure

  • The volume of one mole of ideal gas is always 24.8L mol^-1 at SLC, regardless of the formula or mass of the gaseous substance

  • n = V/Vm (n is mole, V is volume, Vm is 24.8L mol^-1)