Law of Conservation of Matter/Mass
States that matter cannot be created or destroyed, only transformed.
Mass refers to the amount of matter in an object, and both concepts are closely related.
Historical misunderstanding:
Early experiments (e.g., rusting iron) led people to think matter was created.
Example: weighing iron before and after rusting showed an increase in mass, misleading conclusions were drawn about matter creation.
Rusting Example:
Fresh steel vs. rusted iron: rusted iron is heavier due to oxygen inclusions forming iron oxide (rust).
Air was once thought to lack substance, leading chemists to neglect gases in reactions.
Misconception about Mass Increase:
Without loss of pieces, rusted iron would weigh more due to absorbed oxygen.
Historical Context:
Antoine Lavoisier proved the conservation of mass through controlled experiments.
Conducted reactions in sealed containers to measure mass before and after reactions.
Showed no net change in mass, thus verifying that matter is conserved.
Sig Figs (Significant Figures):
Importance of precision in measurements.
More significant figures often require higher quality instruments, which are more costly.
Balancing Equations:
Reactants must equal products in mass and number of atoms.
Example of balancing water (H2O) involves ensuring equal counts of hydrogen and oxygen atoms in both reactants and products.
Practice steps:
Start with known elements present in fewer compounds for easier balancing.
Work through coefficients systematically to ensure balance while checking total atoms for each element.
Stoichiometry Basics:
Deals with the ratios in reactions based on reactants and products.
Any recipe analogy reflects the need for precise amounts in chemical reactions.
Limiting reagents: determines the maximum yield of product possible from given reactants.
Always identify the smallest value among calculated yields as the theoretical yield.
Calculating Theoretical Yield:
Convert grams to moles for stoichiometric calculations.
Identify the limiting reagent to find the theoretical yield.
Perform calculations in steps to ensure correct ratios and conversions.
Conversions in Stoichiometry:
Converting grams of reactants to moles is essential for determining yields.
Using molar masses allows the conversion back to grams for final yield determination.
Example: If 100 grams of hydrogen has a molar mass of 2 g/mol, it converts to 50 moles, leading to further calculations to find the yield.
Final Yield Analysis:
Summary of calculated yields based on limiting reagents and stoichiometry.
Reinforce understanding of how to determine the limiting reagent in complex reactions.
Emphasize the process of balancing equations and performing stoichiometric calculations in practical scenarios.