Chapter 3: Chemical Formulas and Composition
1. How do you determine the empirical formula of a compound?
- Convert the given mass or percentage of each element to moles.
- Divide by the smallest number of moles to get a simple whole-number ratio.
- If needed, multiply by a factor to obtain whole numbers.
2. How do you convert an empirical formula to a molecular formula?
- Determine the molar mass of the empirical formula.
- Divide the given molar mass of the compound by the empirical formula mass.
- Multiply each subscript in the empirical formula by the obtained factor.
3. How do you calculate the percent composition of an element in a compound?
- Use the formula:
\text{Percent composition} = \left(\frac{\text{Mass of element in one mole of compound}}{\text{Molar mass of compound}}\right) \times 100
Chapter 4: Chemical Reactions and Stoichiometry
4. What are the different types of chemical reactions and how are they identified?
- Synthesis: Two or more substances combine to form one product.
- Decomposition: A single compound breaks down into simpler substances.
- Single Displacement: An element replaces another in a compound.
- Double Displacement: Two compounds exchange ions.
- Combustion: A hydrocarbon reacts with oxygen to form CO₂ and H₂O.
5. How do you balance a chemical reaction?
- Adjust coefficients to ensure the same number of atoms for each element on both sides.
6. How do you perform stoichiometric calculations for reactants and products?
- Convert given mass to moles.
- Use the balanced equation to find the mole ratio.
- Convert moles back to mass if needed.
7. How do you determine the limiting reactant, theoretical yield, and percent yield?
- Limiting Reactant: Compare the mole ratio of reactants. The one that produces the least product is limiting.
- Theoretical Yield: Use the limiting reactant to calculate the expected amount of product.
- Percent Yield:
\text{Percent Yield} = \left(\frac{\text{Actual Yield}}{\text{Theoretical Yield}}\right) \times 100
8. How do you predict a combustion reaction?
- A hydrocarbon reacts with O₂, producing CO₂ and H₂O.
9. Why does potassium (K) react more vigorously with water than lithium (Li)?
- Potassium has a lower ionization energy and larger atomic radius, making it more reactive.
10. How do halogens react with other elements?
- Halogens undergo displacement reactions, where a more reactive halogen replaces a less reactive one in a compound.
Chapter 5: Solutions and Aqueous Reactions
11. What are solute, solvent, and solution?
- Solute: The substance dissolved in a solution.
- Solvent: The substance that dissolves the solute.
- Solution: A homogeneous mixture of solute and solvent.
12. How do you differentiate between dilute and concentrated solutions?
- Dilute: Low amount of solute per solvent.
- Concentrated: High amount of solute per solvent.
13. How do you calculate molarity (M)?
-
M = \frac{\text{Moles of solute}}{\text{Liters of solution}}
14. How is molarity used in solution stoichiometry?
- It allows conversion between volume and moles using
\text{Moles} = M \times \text{Volume (L)}
15. What is the difference between an electrolyte and a non-electrolyte solution?
- Electrolytes: Conduct electricity (strong acids, bases, and salts).
- Non-electrolytes: Do not conduct electricity (covalent compounds like sugar).
16. How do acids and bases behave in water, and how is pH calculated?
- Acids: Release H⁺ ions.
- Bases: Release OH⁻ ions.
- pH Calculation:
\text{pH} = -\log[\text{H}^+]
17. What are strong and weak electrolytes?
- Strong Electrolytes: Fully dissociate in water (e.g., NaCl, HCl).
- Weak Electrolytes: Partially dissociate (e.g., HF, CH₃COOH).
18. How do you determine solubility of ionic compounds in water?
- Use solubility rules to determine if a compound dissolves or precipitates.
19. What is a precipitation reaction, and how is it identified?
- A reaction where an insoluble solid (precipitate) forms from two aqueous solutions.
20. How do you write total and net ionic equations?
- Total Ionic Equation: Shows all strong electrolytes as ions.
- Net Ionic Equation: Eliminates spectator ions, showing only species that participate.
21. What are spectator ions?
- Ions that do not participate in the reaction and remain unchanged.
22. What are acid-base and gas evolution reactions?
- Acid-Base Reaction: Acid reacts with a base to form water and a salt.
- Gas Evolution Reaction: A reaction that produces a gas as a product.
23. Why is HCl a stronger acid than HF?
- HCl dissociates completely, while HF forms hydrogen bonds and only partially dissociates.
24. What is acid-base titration, and how is the equivalence point determined?
- A technique to determine the concentration of an acid or base using a neutralization reaction.
- Equivalence Point: When moles of acid = moles of base.
25. What are oxidation-reduction (redox) reactions?
- Reactions involving the transfer of electrons.
26. How do you identify oxidizing and reducing agents?
- Oxidizing Agent: Gains electrons (is reduced).
- Reducing Agent: Loses electrons (is oxidized).
27. How do you assign oxidation numbers?
- Use oxidation number rules (e.g., O = -2, H = +1 in most compounds).
28. How do you determine which element can displace another in a reaction?
- Use the reactivity series: A more reactive element displaces a less reactive one.