Some_Basic_Concepts_of_Chemistry_Shobhit_Nirwan

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  • Title: Shobhit Nirwan's Designed Some Basic Concepts of Chemistry

  • Type: New Notes for Class 11, 2022 Exams

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  • Overview of Chapter Topics:

    • Importance of Chemistry

    • Nature of Matter

      • Solid, Liquid, Gas

      • Mixtures

        • Homogeneous Mixtures

        • Heterogeneous Mixtures

      • Pure Substances

        • Elements

        • Compounds

    • Properties of Matter and Measurements

      • Physical Properties

      • Chemical Properties

      • SI Units: mass, volume, density, temperature

    • Uncertainty in Measurement

      • Scientific Notation

      • Operations with Significant Figures

      • Dimensional Analysis

    • Laws of Chemical Combination

      • Conservation of Mass

      • Definite Proportions

      • Multiple Proportions

      • Gay Lussac’s Law

      • Avogadro's Law

    • Dalton's Atomic Theory

    • Atomic & Molecular Masses

    • Mole Concept & Molar Masses

    • Percentage Composition

    • Stoichiometry and Calculations

    • Reactions in Solutions

      • Mass Percent

      • Mole Fraction

      • Molarity

      • Molality

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  1. Importance of Chemistry:

    • Vital for weather patterns, brain function, and chemical industries (fertilizers, drugs).

    • Life-saving drugs: Cisplatin, Taxol for cancer; AZT for AIDS.

  2. Nature of Matter:

    • Solids: Particles closely packed, definite shape and volume.

    • Liquids: Particles close but can move, definite volume, shape of container.

    • Gases: Particles far apart, easy movement, no definite volume or shape.

    • Mixtures: Combination of 2+ substances.

      • Homogeneous: uniform composition (e.g., air).

      • Heterogeneous: non-uniform composition (e.g., salt and sugar).

    • Pure Substances: Fixed composition, can be elements or compounds.

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  1. Properties of Matter & Measurements:

    • Physical Properties: Measured without changing substance (e.g., color, density).

    • Chemical Properties: Changes identity (e.g., acidity, combustibility).

    • SI Units:

      • Mass: kg

      • Volume: m3 (commonly cm3 or dm3)

      • Temperature: K, °C, °F

      • Density: mass/volume

  2. Uncertainty in Measurement:

    • Scientific Notation: Expressing numbers in powers of 10.

    • Operations (addition, multiplication) must consider significant figures.

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  • Significant Figures: Determine based on reliability and uncertainty in measurement. Rules include:

    • Non-zero digits are significant.

    • Leading zeros are not significant.

    • Zeros between significant digits are significant.

    • Trailing zeros in decimal numbers are significant.

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  1. Laws of Chemical Combination:

    • Conservation of Mass: Matter cannot be created or destroyed.

    • Definite Proportions: Fixed proportions by weight in compounds (Proust).

    • Multiple Proportions: Ratios of masses of elements in compounds are small whole numbers (Dalton).

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  • Gay Lussac's Law: Gases react in simple ratios by volume.

  • Avogadro's Law: Equal volumes of gases contain equal molecules (at same temperature and pressure).

  • Dalton’s Atomic Theory: Atoms are indivisible; compounds form from fixed ratios.

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  1. Atomic & Molecular Masses:

    • Atomic mass unit (amu) based on carbon-12 standard.

    • Average atomic masses and molecular mass calculations based on atomic contributions.

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  1. Mole Concept & Molar Masses:

    • One mole equals 6.022 x 10²³ particles.

    • Molar mass: mass of one mole of a substance in grams.

  2. Percentage Composition:

    • Mass % = (mass of element in compound / molar mass of compound) × 100.

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  1. Empirical & Molecular Formulas:

  • Empirical: simplified ratio of elements.

  • Molecular: exact number of atoms in the molecule.

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  1. Balancing Chemical Equations:

  • Must follow conservation of mass with equal number of atoms on both sides.

  • Example balancing with metals and non-metals reactions.

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  1. Stoichiometry:

  • Relationships between quantities of reactants and products in chemical reactions.

  • Balanced equations describe mole relationships.

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Limiting Reagent:

  • Reactant that is fully consumed and limits product formation.

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Reactions in Solutions:

  • Mass Percent:

    • = (mass of solute / mass of solution) × 100.

  • Mole Fraction: Ratio of moles of component to total moles.

  • Molarity: Moles of solute in one liter of solution.

  • Molality: Moles of solute per kg of solvent.

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