Title: Shobhit Nirwan's Designed Some Basic Concepts of Chemistry
Type: New Notes for Class 11, 2022 Exams
Overview of Chapter Topics:
Importance of Chemistry
Nature of Matter
Solid, Liquid, Gas
Mixtures
Homogeneous Mixtures
Heterogeneous Mixtures
Pure Substances
Elements
Compounds
Properties of Matter and Measurements
Physical Properties
Chemical Properties
SI Units: mass, volume, density, temperature
Uncertainty in Measurement
Scientific Notation
Operations with Significant Figures
Dimensional Analysis
Laws of Chemical Combination
Conservation of Mass
Definite Proportions
Multiple Proportions
Gay Lussac’s Law
Avogadro's Law
Dalton's Atomic Theory
Atomic & Molecular Masses
Mole Concept & Molar Masses
Percentage Composition
Stoichiometry and Calculations
Reactions in Solutions
Mass Percent
Mole Fraction
Molarity
Molality
Importance of Chemistry:
Vital for weather patterns, brain function, and chemical industries (fertilizers, drugs).
Life-saving drugs: Cisplatin, Taxol for cancer; AZT for AIDS.
Nature of Matter:
Solids: Particles closely packed, definite shape and volume.
Liquids: Particles close but can move, definite volume, shape of container.
Gases: Particles far apart, easy movement, no definite volume or shape.
Mixtures: Combination of 2+ substances.
Homogeneous: uniform composition (e.g., air).
Heterogeneous: non-uniform composition (e.g., salt and sugar).
Pure Substances: Fixed composition, can be elements or compounds.
Properties of Matter & Measurements:
Physical Properties: Measured without changing substance (e.g., color, density).
Chemical Properties: Changes identity (e.g., acidity, combustibility).
SI Units:
Mass: kg
Volume: m3 (commonly cm3 or dm3)
Temperature: K, °C, °F
Density: mass/volume
Uncertainty in Measurement:
Scientific Notation: Expressing numbers in powers of 10.
Operations (addition, multiplication) must consider significant figures.
Significant Figures: Determine based on reliability and uncertainty in measurement. Rules include:
Non-zero digits are significant.
Leading zeros are not significant.
Zeros between significant digits are significant.
Trailing zeros in decimal numbers are significant.
Laws of Chemical Combination:
Conservation of Mass: Matter cannot be created or destroyed.
Definite Proportions: Fixed proportions by weight in compounds (Proust).
Multiple Proportions: Ratios of masses of elements in compounds are small whole numbers (Dalton).
Gay Lussac's Law: Gases react in simple ratios by volume.
Avogadro's Law: Equal volumes of gases contain equal molecules (at same temperature and pressure).
Dalton’s Atomic Theory: Atoms are indivisible; compounds form from fixed ratios.
Atomic & Molecular Masses:
Atomic mass unit (amu) based on carbon-12 standard.
Average atomic masses and molecular mass calculations based on atomic contributions.
Mole Concept & Molar Masses:
One mole equals 6.022 x 10²³ particles.
Molar mass: mass of one mole of a substance in grams.
Percentage Composition:
Mass % = (mass of element in compound / molar mass of compound) × 100.
Empirical & Molecular Formulas:
Empirical: simplified ratio of elements.
Molecular: exact number of atoms in the molecule.
Balancing Chemical Equations:
Must follow conservation of mass with equal number of atoms on both sides.
Example balancing with metals and non-metals reactions.
Stoichiometry:
Relationships between quantities of reactants and products in chemical reactions.
Balanced equations describe mole relationships.
Limiting Reagent:
Reactant that is fully consumed and limits product formation.
Reactions in Solutions:
Mass Percent:
= (mass of solute / mass of solution) × 100.
Mole Fraction: Ratio of moles of component to total moles.
Molarity: Moles of solute in one liter of solution.
Molality: Moles of solute per kg of solvent.