Homogeneous invasion results in droplets smaller than 0.01 micrometers.
Small droplets require very high humidities to survive, typically above 12%, which is rare in clouds.
Droplets measuring between 0.1 and 0.01 micrometers may survive under certain conditions, while those smaller than 0.01 micrometers typically do not.
Smaller droplets have greater curvature, increasing evaporation likelihood.
Once droplets reach a size of less than 0.01 micrometers, their chances of survival are slim.
Homogeneous droplets do not typically form clouds; they evaporate almost immediately due to high curvature effects.
Heterogeneous nucleation requires condensation nuclei (cloud condensation nuclei).
Two types of condensation nuclei:
Hydrophilic (Guenopole): Attract water vapor.
Hygroscopic: Soluble in the resulting droplet, dissolves water, leading to lower saturation vapor pressure, enabling droplet formation at lower humidities (around 70%).
Curvature and solute effects impact droplet growth differently:
Curvature Effect: Can inhibit droplet survival due to increased evaporation.
Solute Effect: Promotes droplet growth through hygroscopic nuclei.
As droplets grow larger, their solute concentration decreases, and they behave more like pure water.
Homogeneous droplets: Freeze at temperatures below -4°C; can exist as supercooled water droplets down to -40°C.
Heterogeneous nucleation: Requires ice nuclei; droplets freeze between 0°C and -40°C, highlighting the necessity for both liquid water and ice crystals in cloud formation.
Vapor pressure over ice is lower than over water; it requires additional energy for sublimation from ice to water vapor vs. evaporation from liquid water.
This energy difference affects processes within clouds, such as the Bergeron model, where ice crystals grow at the expense of surrounding supercooled droplets.
Formation of clouds requires reaching the lifting condensation level by cooling air parcels to the dew point temperature.
Mechanisms for cooling include:
Convection: Air rises due to different heating surfaces.
Orographic Lifting: Air forced over mountains.
Frontal Lifting: Low-pressure areas cause air to rise as warm and cold fronts meet.
Divergence Aloft: Increased wind speeds in the upper atmosphere leading to low pressure and upward air movement.
Convergence at Surface: Air converging and ascending, resulting in low surface pressure.
Fog is essentially a cloud in contact with the ground, formed through:
Cooling: Example: Radiation fog forms from overnight surface cooling without rising air.
Mixing: Evaporation from rain can saturate the air and create fog.
Types of fog:
Upslope Fog: Caused by air moving up a topographic barrier.
Radiation Fog: Caused by surface cooling overnight, clearer skies favor formation.
Advection Fog: Warm, moist air moves over a cooler surface, leading to cooling.
Precipitation occurs when droplets or ice crystals grow large enough to overcome cloud updrafts and fall to the surface.
Rain is defined as any form reaching the ground; can include drizzle, sleet, freezing rain, and hail.
The size of droplets influences whether precipitation makes it to the ground without evaporating.
Distinction between cloud droplets (lower case, small) and raindrops (larger, several mm).
Collision and Coalescence:
Collisions between droplets can lead to larger droplet formation.
Efficiency for collisions and coalescence increases with larger collector droplets (over 20 micrometers).
Smaller droplets tend to be deflected rather than collide with larger ones.
Diverse droplet sizes within clouds increase the likelihood of collisions leading to coalescence.
In cold clouds containing ice crystals, precipitation mechanisms differ compared to warm clouds.
It is crucial for droplets to be large enough to fall to the ground and avoid evaporation on their descent.