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5) Simple Molecular Substances:

What are Simple Molecular Substances?

Simple molecular substances are made up of molecules containing a few atoms joined together by covalent bonds. These substances typically have simple molecular structures.


Examples of Simple Molecular Substances

  1. Chlorine (Cl₂):

    • Each chlorine atom needs one more electron to complete its outer shell.

    • Two chlorine atoms share a pair of electrons, forming a single covalent bond.

  2. Hydrogen (H₂):

    • Hydrogen atoms have one electron and need one more to complete their first shell.

    • They form single covalent bonds, either with other hydrogen atoms or other elements.

  3. Oxygen (O₂):

    • Oxygen atoms need two more electrons to fill their outer shell.

    • Two oxygen atoms share two pairs of electrons, creating a double covalent bond.

  4. Nitrogen (N₂):

    • Nitrogen atoms need three more electrons to fill their outer shell.

    • Two nitrogen atoms share three pairs of electrons, forming a triple covalent bond.

  5. Water (H₂O):

    • Oxygen shares a pair of electrons with two hydrogen atoms, forming two single covalent bonds.

  6. Methane (CH₄):

    • Carbon has four outer electrons and can form four covalent bonds with hydrogen atoms to fill its outer shell.

  7. Hydrogen Chloride (HCl):

    • Hydrogen and chlorine each need one more electron to complete their outer shells.

    • They share a pair of electrons to form a single covalent bond.


Properties of Simple Molecular Substances

  • Weak Intermolecular Forces:

    • Atoms within molecules are held together by strong covalent bonds.

    • However, the forces of attraction between molecules are weak.

  • Low Melting and Boiling Points:

    • To melt or boil a simple molecular compound, only the weak intermolecular forces need to be broken, not the covalent bonds.

    • This results in low melting and boiling points, as the molecules are easily separated.

  • States at Room Temperature:

    • Most simple molecular substances are gases or liquids at room temperature.

  • Increasing Size and Intermolecular Forces:

    • As molecules get bigger, the strength of the intermolecular forces increases, requiring more energy to break them.

    • This leads to higher melting and boiling points.

  • Electrical Conductivity:

    • Molecular compounds do not conduct electricity because they aren't charged — they have no free electrons or ions.