Focus on Power Cycles:
Heat engines operate in cycles producing net work.
Defined as power cycles.
Categories:
Vapor Power Cycle: Working fluid exists in vapor and liquid phases.
Gas Power Cycle: Working fluid remains in gaseous phase.
Example: Steam power plant.
Key Processes in Steam Power Plant:
Process 1-2: Heat energy from fuel vaporizes water into steam in the boiler.
Process 2-3: Steam expands in turbine/engine producing work.
Process 3-4: Vapor condenses in condenser.
Process 4-1: Condensed steam is pumped back to boiler, completing the cycle.
Characteristics:
Alternation between vaporization and condensation.
Considered a closed vapor power cycle.
Importance of Ideal Cycle for Analysis:
Actual vapor power cycles have irreversible and non-quasi-equilibrium processes.
Apply thermodynamics principles to reversible and quasi-equilibrium processes.
Utilize idealized vapor power cycle for performance analysis (theoretical).
The Carnot cycle:
Most efficient cycle between two temperature limits.
Processes:
Process 4-1: Constant pressure heat addition in the boiler.
Saturated liquid to dry saturated steam.
Heat added: qA = hg,1 – hf,4.
Process 1-2: Isentropic expansion in turbine.
Dry saturated steam expands to wet steam, doing work.
Steam turbine work: wt = hg,1 – h2.
Process 2-3: Heat rejection in condenser.
Exhaust steam condensed by rejecting heat qR.
Heat rejected: qR = h2 – h3.
Process 3-4: Isentropic compression in pump.
Pumping from wet steam to saturated liquid.
Pump work: wp = hf,4 – h3.
Net Work Done (wnet):
wnet = Heat added (qA) – heat rejected (qR).
Expressed in terms of turbine and pump work.
Thermal Efficiency:
Carnot cycle indicates the maximum possible efficiency but is impractical.
Overcomes Carnot Cycle Limitations:
Complete condensation of vapor eliminates issues with wet steam.
Processes in Rankine Cycle:
Boiler:
Water converted to steam by heating.
Heat addition: qA = hg,1 – hsub,4.
Steam Turbine:
Dry saturated steam expands, producing work.
Steam turbine work: wt = hg,1 – h2.
Condenser:
Exhaust steam condensed by heat rejection.
Total heat rejected: qR = h2 – hf,3.
Feed Pump:
Pumps condensate to boiler pressure.
Pump work: wp = hsub,4 – hf,3.
Thermal Efficiency:
Rankine cycle efficiency ranges from 35% to 45%.
Pump work can often be neglected due to its small size.
Definition:
Homogeneous composition, aggregation; does not change despite phase changes.
Phases of Pure Substance:
Solid, Liquid, Gas.
Important Terms as Applied to Steam:
Wet Steam: Contains moisture.
Dry Saturated Steam: No moisture content.
Superheated Steam: Heated beyond saturation temperature.
Quality of Steam: Ratio of mass of dry steam to total mass; x (0 to 1).
Critical Point: No distinct vaporization process; saturated states are identical.
Triple Point: States with the same pressure and temperature.
Sensible Heat: Heat to raise temperature at constant pressure (hf).
Latent Heat: Heat for phase change at saturation temperature (hfg).
Total Heat or Enthalpy: Combination of sensible and latent heat.