Thapar Institute of Engineering & Technology
School of Energy & Environment (SEE)
Course: UEN008 - Energy and Environment
Topic: Water Pollution
Continuation of coursework regarding the water cycle as it pertains to water pollution.
Further detailing the issue of water pollution under the same course.
Definition: Water pollution is the contamination of water bodies mainly due to human activities.
Water Bodies Affected: Includes lakes, rivers, aquifers, and groundwater.
Cause: Results from excess concentrations of contaminants introduced into the environment, leading to a loss of beneficial uses of water caused by changes in its composition due to human activity.
Physical Characteristics:
Solids, temperature, color, odor, turbidity, oil and grease, conductivity.
Chemical Characteristics:
Organics: Proteins, carbohydrates, lipids, surfactants, phenols, pesticides, etc.
Inorganics: pH, chlorides, alkalinity, nitrogen, phosphorus, and heavy metals.
Gases: Oxygen, hydrogen sulfide, methane.
Biological Characteristics:
Pathogens, indicators, viruses, and invertebrates.
Point Sources: Single, identifiable sources of pollution.
Non-Point Sources: Diffuse source of pollution, such as:
General runoff of sediments.
Pesticide spraying.
Fertilizer runoff from farms.
Overview of the classification and differences between point and non-point sources of water pollution.
Identifying significant water pollutants and understanding their origin.
Key Contaminants:
Biodegradable organic matter.
Suspended, colloidal, and dissolved solids.
Nutrients, pathogens, soaps, detergents, pesticides.
Acidic, basic, and ionic species; as well as thermal and radioactive materials.
Fund Pollutants:
Those with some absorptive capacity in the environment.
Examples:
Degradable (organic residues) broken down by bacteria.
Thermal (heat injection) and Eutrophic (excess nutrients like nitrogen and phosphorus).
Stock Pollutants:
Have little or no absorptive capacity. Ex: Heavy metals, synthetic chemicals.
Overview of wastewater characteristics.
Importance: A critical measure of water quality.
Key characteristics:
Oxygen solubility is inversely proportional to temperature; max DO at 16°C is 10 mg/L.
Obtained through diffusion from air, aeration, and photosynthesis.
Stress for aquatic life occurs below 5 mg/L.
Classification of water quality based on DO levels:
8–9 mg/L: Good
6.7–8 mg/L: Slightly polluted
4.5–6.7 mg/L: Moderately polluted
4–4.5 mg/L: Heavily polluted
Below 4 mg/L: Gravely polluted
Aggregate organics including:
Total Organic Carbon (TOC)
Chemical Oxygen Demand (COD)
Biochemical Oxygen Demand (BOD)
Chemical and physical constituents affecting water quality:
Organics, Inorganics, Gases.
Total oxygen required to oxidize a known compound to CO2 and H2O.
Illustrated by stoichiometric calculations with organic compounds.
Measures the pollution potential of organic matter.
Higher COD values than BOD, as it does not differentiate between degradable and non-degradable matter.
Measured using potassium dichromate.
Procedure: Measured by the amount of potassium dichromate reduced during a controlled reaction.
Formula used for COD calculation:
COD(mg/l as O2) based on volumes of FAS in blank and sample samples.
Problem description involving estimation of COD in wastewater.
Calculated COD based on given data and formula:
Result: 12000 mg/L.
Definition: Indicator of organic matter concentration in wastewater.
Determined based on aerobic biological decomposition of organic waste.
Known as BOD5, measures DO before and after 5 days incubation at 20°C.
Not a specific pollutant measure but a gauge of oxygen needed by microorganisms.
Influences include temperature, time, and light conditions.
Illustration of BOD decay over time.
BOD determination using initial and final DO measurements, dilution factor applied.
The dilution factor used in BOD calculations.
Formula to calculate BODt over time based on decay.
Example problem involving calculations of BOD at different temperatures.
Discussion on correcting BOD values based on temperature variations.
Relationship noted: COD > BOD, indicating biodegradable versus non-biodegradable particles present.
Indicates pollution load through carbon content.
Tested using TOC analyzers.
Overview of solids in water including TSS, TDS, TVS, and their measurement methods.
Additional categories of suspended and dissolved solids.
Definition: Light transmission property of water.
Measurement technique: Nephelometry; units are NTU.
Colour: Measured by spectrophotometer in PCU.
Temperature: Key in chemical reactions.
Electrical Conductivity: Indicates water's capacity to conduct electricity related to TDS.
Summary of chemical constituents affecting water quality including alkalinity, nitrogen, phosphorus, etc.
Alkalinity from hydroxides, crucial for biological treatment.
Nitrogen compounds measured include NH3, NO3, etc.
Importance of phosphorus as a nutrient and effects of metals like cadmium, mercury as priority pollutants.
Stages of treatment:
Primary: Removes solids.
Secondary: Targets organics.
Tertiary: Nutrient removal.
Overview of typical operations within a treatment plant.
Focus on the suspended growth process in these treatments.
First operation in treatment focused on removing objects that may damage equipment.
Types of screens included: coarse, medium, and fine.
Process of gravity separation to remove suspended solids and organic material.
Use of scrapers in circular clarifiers.
Basics of enzymatic reactions involved in biological treatment.
Environmental factors affecting microbial growth described.
Description of ASP as an aerobic treatment method utilizing biomass to degrade organic matter.
Further details on the functioning of activated sludge processes (ASPs).
Explanation of trickling filters as aerobic treatment systems for biodegrading organic matter.
Summary and visual representation of the trickling filter process.
Further information detailing the trickling filter treatment process.
Combination of suspended and attached growth processes in a treatment method.
Describes the partial destruction of pathogens, key characteristics of ideal disinfectants.
Overview of physical and chemical methods used for disinfection in water treatment.
Describes how different disinfectants interact with pathogens and factors affecting their efficacy.
Closing slide thanking the audience.