Mass Spec and PES Lecture
Mass Calculation
Isotopes of Bromine: 78.92 amu (50.69%), 80.92 amu (49.31%)
78.92 (0.5092)+ 80.92 (0.4931)= 79.91 amu
Electrons in an Atoms Orbit
Electronegativity helps with the attractiveness of electrons
The nucleus (ZEFF) has a positive charge which helps to attract negative electrons
Columb’s Law: the relationship and distance between particles
Adding electrons increases size and repulsion forces which need extra space: if ZEEF doesn’t change the size increases= less force
Mass Spec
Use isotopes and abundance values to determine what element is given
Gas is more spread out, less attraction is formed, so more data is gathered by the spectrometer
The mass of the isotope is determined by how many times particles hit a certain area (higher= lighter lower= heavier)
Photoelectron Spectroscopy
Graphs electrons and their binding energy/ ionization energy (mJ/mol)
S: 1s2 2s2 2p6 3s2 3p4 [Xe] 3s2 3p4
The farther the electron is away from the nucleus the weaker the bond
Adding more electrons will increase the number of electrons and decrease the amount of binding energy on the valence shell
More protons cause more pull in the binding energy
Mass Calculation
Isotopes of Bromine: 78.92 amu (50.69%), 80.92 amu (49.31%)
78.92 (0.5092)+ 80.92 (0.4931)= 79.91 amu
Electrons in an Atoms Orbit
Electronegativity helps with the attractiveness of electrons
The nucleus (ZEFF) has a positive charge which helps to attract negative electrons
Columb’s Law: the relationship and distance between particles
Adding electrons increases size and repulsion forces which need extra space: if ZEEF doesn’t change the size increases= less force
Mass Spec
Use isotopes and abundance values to determine what element is given
Gas is more spread out, less attraction is formed, so more data is gathered by the spectrometer
The mass of the isotope is determined by how many times particles hit a certain area (higher= lighter lower= heavier)
Photoelectron Spectroscopy
Graphs electrons and their binding energy/ ionization energy (mJ/mol)
S: 1s2 2s2 2p6 3s2 3p4 [Xe] 3s2 3p4
The farther the electron is away from the nucleus the weaker the bond
Adding more electrons will increase the number of electrons and decrease the amount of binding energy on the valence shell
More protons cause more pull in the binding energy