Periodic Table Group 2: Alkaline Earth Metals - JEE Comprehensive Study Guide
Please create a comprehensive test/flashcard set titled 'Periodic Table Group 2: Alkaline Earth Metals - JEE' with the following specifications:
Include a mix of:
- Facts and definitions
- JEE Main and JEE Advanced previous year questions (PYQs)
- Conceptual MCQs
- Assertion-reason questions
- Higher-order thinking questions
- Mix Knowt's auto-generated questions with custom ones
- The test should reflect JEE Main and Advanced level difficulty
DETAILED CONTENT TO COVER:
1. GROUP 2 ELEMENTS:
- Beryllium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), Radium (Ra)
- Electronic configuration: [Noble gas] ns²
- General properties and position in periodic table
2. PHYSICAL PROPERTIES:
- Atomic and ionic radii trends (increase down the group)
- Ionization energies (decrease down the group)
- First and second ionization energies
- Metallic character increases down the group
- Density trends
- Melting and boiling points
- Hardness decreases down the group
3. CHEMICAL PROPERTIES:
- Oxidation state: +2 (most stable)
- Reducing nature increases down the group
- Reactivity with water, acids, and oxygen
- Formation of ionic compounds
- Electronegativity decreases down the group
4. COMPOUNDS AND THEIR PROPERTIES:
Oxides (MO):
- Basic nature increases down the group
- BeO is amphoteric
- Thermal stability increases down the group
- Solubility in water
Hydroxides [M(OH)₂]:
- Be(OH)₂ is amphoteric
- Mg(OH)₂ is weakly basic
- Ca(OH)₂, Sr(OH)₂, Ba(OH)₂ are strongly basic
- Solubility increases down the group
- Thermal decomposition
Halides (MX₂):
- Ionic character increases down the group
- BeF₂, BeCl₂ are covalent
- Hydration enthalpies
- Solubility trends in water
- Thermal stability
Carbonates (MCO₃):
- Thermal stability increases down the group
- BeCO₃ doesn't exist in solid state
- Solubility decreases down the group
- Decomposition temperatures
Sulphates (MSO₄):
- Thermal stability increases down the group
- Solubility decreases down the group
- BeSO₄, MgSO₄ are highly soluble
- BaSO₄ is insoluble (used in qualitative analysis)
5. ANOMALOUS BEHAVIOR OF BERYLLIUM:
- Small size and high charge density
- Covalent bonding tendency
- Amphoteric oxide and hydroxide
- Does not form solid bicarbonate
- BeF₂ forms polymeric chains
- Diagonal relationship with aluminum
6. IMPORTANT REACTIONS:
- With water: M + 2H₂O → M(OH)₂ + H₂
- With acids: M + 2HCl → MCl₂ + H₂
- With oxygen: 2M + O₂ → 2MO
- Thermal decomposition of carbonates: MCO₃ → MO + CO₂
- Thermal decomposition of hydroxides: M(OH)₂ → MO + H₂O
7. FLAME COLORS:
- Calcium: Brick red
- Strontium: Crimson red
- Barium: Apple green
- Magnesium: Brilliant white
- Beryllium: No color
8. BIOLOGICAL SIGNIFICANCE:
- Magnesium in chlorophyll
- Calcium in bones and teeth
- Role in enzyme activation
9. INDUSTRIAL APPLICATIONS:
- Mg alloys in aerospace
- Ca in steel production
- Ba in X-ray imaging
- Be in nuclear reactors
10. QUALITATIVE ANALYSIS:
- Group II cations identification
- Precipitation reactions
- Confirmatory tests
INSTRUCTION FOR AI:
Create questions that test understanding of trends, exceptions, applications, and numerical problems. Include questions on lattice energies, hydration energies, and Born-Haber cycles. Generate assertion-reason questions comparing properties within the group and with other groups. Create higher-order questions involving multiple concepts and real-world applications suitable for JEE Main and Advanced levels.