chemistry

1. Fundamentals of Chemistry
1.1 Atoms, Elements, and Compounds
  • Atom: The smallest unit of an element that retains the chemical identity of that element. Composed of protons, neutrons, and electrons.

  • Elements: Pure substances consisting of only one type of atom. They cannot be broken down into simpler substances by chemical means. Represented by chemical symbols (e.g., HH, OO, FeFe).

  • Compounds: Substances formed when two or more different elements are chemically bonded together in fixed proportions (e.g., H2OH_2O, NaClNaCl).

  • Molecules: Two or more atoms held together by chemical bonds. Can be elements (e.g., O<em>2O<em>2) or compounds (e.g., CO</em>2CO</em>2).

1.2 Atomic Structure
  • Protons: Positively charged particles (+1+1) found in the nucleus. Determine the atomic number (ZZ).

  • Neutrons: Neutral particles (no charge) found in the nucleus. Contribute to the mass number but not the charge.

  • Electrons: Negatively charged particles (1-1) that orbit the nucleus in electron shells or orbitals. Determine an atom's chemical properties.

  • Atomic Number (ZZ): Number of protons in an atom. Defines the element.

  • Mass Number (AA): Total number of protons and neutrons in an atom's nucleus.

  • Isotopes: Atoms of the same element (same number of protons) but with different numbers of neutrons (different mass numbers).

1.3 Periodic Table
  • Organizes elements by increasing atomic number.

  • Periods: Horizontal rows (1-7), correspond to the number of electron shells.

  • Groups/Families: Vertical columns (1-18), elements in the same group have similar chemical properties due to the same number of valence (outermost shell) electrons.

    • Alkali Metals (Group 1): Highly reactive metals.

    • Alkaline Earth Metals (Group 2): Reactive metals.

    • Transition Metals (Groups 3-12): Diverse properties, often form colored compounds.

    • Halogens (Group 17): Highly reactive nonmetals, often form salts.

    • Noble Gases (Group 18): Unreactive, stable due to full valence shells.

2. Chemical Bonding
2.1 Types of Chemical Bonds
  • Ionic Bonds: Formed by the transfer of electrons between a metal (loses electrons to become a cation) and a nonmetal (gains electrons to become an anion). Results in electrostatic attraction (e.g., NaClNaCl).

  • Covalent Bonds: Formed by the sharing of electrons between two nonmetals.

    • Nonpolar Covalent: Equal sharing of electrons (e.g., O2O_2).

    • Polar Covalent: Unequal sharing of electrons due to differences in electronegativity, creating partial charges (e.g., H2OH_2O).

  • Metallic Bonds: Electrostatic attraction between positively charged metal ions and a "sea" of delocalized electrons.

2.2 Intermolecular Forces (IMFs)
  • Hydrogen Bonding: Strongest IMF, occurs when hydrogen is bonded to a highly electronegative atom (N, O, F) and attracted to another N, O, or F atom on a different molecule.

  • Dipole-Dipole Forces: Occur between polar molecules.

  • London Dispersion Forces (LDFs): Weakest IMF, present in all molecules (polar and nonpolar) due to temporary, induced dipoles.

3. Chemical Reactions and Stoichiometry
3.1 Chemical Equations
  • Represent chemical reactions, showing reactants (left) and products (right).

  • Must be balanced to obey the Law of Conservation of Mass (same number of each type of atom on both sides):
    2H<em>2(g)+O</em>2(g)2H2O(l)2H<em>2(g) + O</em>2(g) \rightarrow 2H_2O(l)

3.2 Types of Reactions
  • Synthesis (Combination): A+BABA + B \rightarrow AB

  • Decomposition: ABA+BAB \rightarrow A + B

  • Single Displacement: A+BCAC+BA + BC \rightarrow AC + B

  • Double Displacement: AB+CDAD+CBAB + CD \rightarrow AD + CB

  • Combustion: Reaction with oxygen, often producing heat and light (e.g., hydrocarbon + O<em>2CO</em>2+H2OO<em>2 \rightarrow CO</em>2 + H_2O).

  • Acid-Base (Neutralization): Acid + Base \rightarrow Salt + Water.

3.3 Stoichiometry
  • Mole: A unit of amount; 1 mole=6.022×10231 \text{ mole} = 6.022 \times 10^{23} particles (Avogadro's number).

  • Molar Mass: The mass of one mole of a substance (in g/molg/mol), numerically equal to its atomic/molecular weight.

  • Mole Ratios: Derived from the coefficients in a balanced chemical equation, used to convert between amounts of reactants and products.

  • Limiting Reactant: The reactant that is completely consumed in a reaction, determining the maximum amount of product that can be formed.

  • Theoretical Yield: The maximum amount of product that can be formed from given amounts of reactants.

  • Percent Yield: Actual YieldTheoretical Yield×100%\frac{\text{Actual Yield}}{\text{Theoretical Yield}} \times 100\%

4. States of Matter and Solutions
4.1 States of Matter
  • Solid: Fixed shape and volume, particles vibrate in fixed positions.

  • Liquid: Fixed volume but takes the shape of its container, particles can slide past each other.

  • Gas: No fixed shape or volume, particles are far apart and move randomly.

  • Phase Changes: Melting, freezing, vaporization, condensation, sublimation, deposition.

4.2 Solutions
  • Solution: A homogeneous mixture of two or more substances.

  • Solute: The substance present in the lesser amount, dissolved in the solvent.

  • Solvent: The substance present in the greater amount, dissolves the solute.

  • Concentration: Amount of solute in a given amount of solvent or solution.

    • Molarity (MM): Moles of solute per liter of solution (molL\frac{\text{mol}}{\text{L}})

5. Acids and Bases
5.1 Definitions
  • Arrhenius Acid: Produces H+H^+ ions in aqueous solution.

  • Arrhenius Base: Produces OHOH^- ions in aqueous solution.

  • Brønsted-Lowry Acid: Proton (H+H^+) donor.

  • Brønsted-Lowry Base: Proton (H+H^+) acceptor.

5.2 pH Scale
  • Measures the acidity or basicity of a solution.

  • pH=log[H+]pH = -log[H^+]

  • Acidic: pH < 7

  • Neutral: pH=7pH = 7

  • Basic (Alkaline): pH > 7

  • pOH=log[OH]pOH = -log[OH^-]

  • pH+pOH=14pH + pOH = 14 (at 25C25^{\circ}C)

6. Introduction to Organic Chemistry
  • Organic Chemistry: The study of carbon-containing compounds.

  • Hydrocarbons: Compounds composed solely of carbon and hydrogen.

    • Alkanes: Single bonds only (e.g., methane, CH4CH_4).

    • Alkenes: At least one carbon-carbon double bond (e.g., ethene, C<em>2H</em>4C<em>2H</em>4).

    • Alkynes: At least one carbon-carbon triple bond (e.g., ethyne, C<em>2H</em>2C<em>2H</em>2).

  • Functional Groups: Specific groups of atoms within a molecule that are responsible for its characteristic chemical reactions (e.g., alcohols (OH-OH), carboxylic acids (COOH-COOH), amines (NH2-NH_2)).