Minerals, Rocks and Rock Cycle - Vocabulary Flashcards (ENGLISH)
Minerals
Definition of minerals
Naturally occurring in nature
Solid
Inorganic (not a product of living tissue)
Definite chemical composition (unique chemical composition)
Crystalline structure (atoms arranged in orderly patterns)
Example: NaCl (Halite)
Special examples/exceptions
Naturally occurring ice is a mineral; man-made ice and water are not minerals
Amber (C{10}H{16}O) is not a mineral
Magnetite (Fe{3}O{4}) formed by certain bacteria is a mineral
Question 1: Which of the following substances is not considered a mineral?
A. coal • B. diamond • C. gypsum • D. rock
Atomic composition and occurrence
An atom is a fundamental form of matter that cannot be broken into simpler substances by ordinary chemical processes.
A total of 88 elements out of 118 identified occur naturally in the Earth’s crust.
Only the 8 most abundant elements make up 98.59\% of the Earth’s crust.
Composition of Minerals
The Earth’s crust is built from a limited set of elements, with trace amounts of many others contributing to mineral diversity.
Structure of the atom
An atom consists of a positively charged nucleus and a cloud of negatively charged electrons.
The nucleus is made up of neutrons and positively charged protons.
Question 2: Melting of minerals breaks chemical bonds; which bond is the strongest?
A. ionic • B. covalent • C. metallic • D. Van der Waals
Chemical bonds in minerals
Cations are positively charged; anions are negatively charged.
Atoms or ions are held together by chemical bonds in definite proportions to form minerals.
Types of chemical bonds:
Ionic bond: formed when one or more electrons are removed from one atom and attached to another.
Covalent bond: formed when one or more pairs of electrons are shared by two atoms (strongest).
Metallic bond: some electrons are loose and not associated with a particular atom.
Van der Waals bond: a weak type of bond that does not share or transfer electrons.
Crystal structure and the nature of crystals
Crystalline structure: Atoms in a mineral are specifically ordered based on atomic patterns.
Glass: a solid with disordered atoms.
A crystal is a single, continuous piece of a crystalline solid.
Crystal faces: flat surfaces of a crystal grown without obstructions.
Law of constancy of interfacial angles: angles between the same faces on crystals of the same substance are equal.
Regular, orderly, and periodically repeated arrangement of atoms constitutes the crystal structure of a mineral.
Question 2 (revisited): Boldest bonds
The strongest chemical bond is covalent.
Polymorphs
Polymorphs: minerals with the same chemical composition but different crystal structures.
Conditions such as temperature (T) and pressure (P) determine the crystal structure.
Question 3: Aragonite (density \rho=2.9\ \text{g/cm}^3) has the same chemical composition as calcite (\rho=2.7\ \text{g/cm}^3). Which is more likely formed under high pressure?
Answer: Aragonite
Mineral formation
Crystallization from melt (igneous rocks)
Precipitation from water (chemical sedimentary rocks, hydrothermal ore deposits)
Biological activity (biochemical sedimentary rocks)
Change to a more stable state (weathering, metamorphism, diagenesis)
Precipitation from vapor (not common, but can occur around volcanic vents)
Crystal growth
Crystals grow as atoms bond to mineral surfaces starting from a central seed.
Growth expands outward as atoms accumulate.
Modes of growth:
Solidification from a melt
Precipitation from solution
Solid-state diffusion
Larger crystals require longer growth time.
Question 4: Quartz can be formed by cooling of felsic magma. The quartz crystals will be large for:
A. slowly cooling magma • B. fast cooling magma • C. magma cooled under water • D. magma cooled in the air
Physical properties of minerals (identification)
Properties depend on chemical composition and crystal structure (bonding).
Some properties are diagnostic; each mineral has a unique set of physical properties.
Colors & examples
Color: color or color range as seen in reflected light.
Quartz: colorless, white, pink, purple, brown, green, blue (range of colors).
Pyrite: typically gold in color.
Corundum: ruby and sapphire varieties.
Streak
Color of a mineral in powdered form.
Streak may differ from the mineral’s bulk color.
Hematite: may be silver/gray in bulk but leaves a reddish-brown streak.
Pyrite: gold in bulk but leaves a black streak.
Luster
How a mineral’s surface reflects light:
Metallic vs non-metallic.
Non-metallic subtypes: Vitreous (glassy), Satiny, Silky, Resinous, Pearly, Earthy (dull), Adamantine (brilliant).
Hardness
Resistance to scratching.
Mohs hardness scale (reference set).
Tests can use common objects (fingernail, copper penny, nail, glass).
Specific Gravity
How heavy a mineral is for its size; defined as mass divided by volume.
Example comparison: Pyrite vs Calcite.
\text{Specific Gravity} = \frac{\text{mass}}{\text{volume}}
Crystal habit
The ideal shape of crystal faces.
Related to the structural arrangement of atoms.
Requires ideal growth conditions.
Common forms: cubes, blades, hexagonal prisms, dodecahedra, rhombohedra, octahedra; compound forms like tetragonal prisms.
Cleavage
Tendency to break along flat surfaces (planes of weakness in crystal structure).
Produces flat, shiny surfaces.
The number of cleavage planes and the angles between them aid identification (e.g., amphibole, feldspar, mica).
Fracture
Irregular breakage.
Some minerals lack planes of lattice weakness and thus do not cleave; they fracture.
Conchoidal fracture: typical of quartz and obsidian.
Other properties
Magnetism (e.g., magnetite)
Reaction to acid (e.g., calcite, dolomite)
Taste (e.g., halite)
Flexibility (e.g., gypsum – flexible in thin sheets)
Feel (e.g., talc)
Question 5: Describe a strategy to prove that an unknown clear calcite crystal is not the same mineral as a known clear crystal of quartz.
Mineral classification by anions
Minerals are commonly classified by their anions:
Oxides (e.g., magnetite, hematite)
Silicates (e.g., olivine, pyroxene)
Carbonates (e.g., calcite, dolomite)
Sulfides (e.g., pyrite, galena)
Halides (e.g., halite, fluorite)
Native elements (e.g., gold, copper, diamond)
Major groups of minerals and the silicate framework
Silicates – contain ext{SiO}_4^{4-} (e.g., quartz, feldspar, olivine; pyroxene, mica)
Carbonates – contain ext{CO}3^{2-} (e.g., calcite, aragonite, dolomite – ext{CaCO}3)
Sulfates – contain ext{SO}4^{2-} (e.g., gypsum – ext{CaSO}4\cdot 2\text{H}_2 ext{O})
Sulfides – contain ext{S}^{2-} (no O) (e.g., pyrite – ext{FeS}_2; galena – ext{PbS})
Phosphates – contain ext{PO}4^{3-} (e.g., apatite, ext{Ca}10( ext{PO}4)6( ext{OH, F, Cl})_2)
Oxides – contain ext{O}^{2-} but not bonded to Si, C, or S (e.g., hematite – ext{Fe}2 ext{O}3; magnetite – ext{Fe}3 ext{O}4)
Halide – contain ext{Cl}^{-} or ext{F}^{-} (e.g., halite – ext{NaCl}; fluorite – ext{CaF}_2)
Native elements – composed entirely of one element (e.g., diamond – ext{C}; gold – ext{Au})
Silicate minerals and the crystal structure families
Silicate minerals dominate Earth’s crust and are known as the rock-forming minerals.
Silica tetrahedron: ext{SiO}_4^{4-}; 4 oxygen atoms bonded to 1 silicon atom.
Silica tetrahedra link together by sharing oxygen.
Silicate structures (family overview)
Independent tetrahedron: no oxygen sharing; linked by cations (e.g., olivine).
Single-chain silicates: chains bonded with Fe and Mg (e.g., pyroxene).
Double-chain silicates: varied cations (e.g., amphibole).
Sheet silicates: two-dimensional sheets of linked tetrahedra (e.g., mica, clay minerals like muscovite).
Framework silicates: all four oxygens are shared; includes feldspar and quartz (SiO$_2$-group).
Rocks and the rock cycle
Rocks definition: a coherent naturally occurring solid, consisting of an aggregate of minerals or a mass of glass.
Clastic rocks: grains cemented together.
Crystalline rocks: crystals interlock with one another.
Three basic rock types: igneous, sedimentary, metamorphic.
The Rock Cycle
A series of processes that causes rock to change from one type to another, driven by plate tectonics and climate interactions.
Sedimentary path: Weathering → Transportation → Deposition → Lithification → Sedimentary Rocks.
Metamorphic path: Metamorphism → Metamorphic Rocks.
Uplift and exposure bring rocks to the surface.
Melting produces magma; cooling/crystallization forms Igneous Rocks (extrusive vs. intrusive).
Igneous rocks can weather to form sedimentary rocks, or be buried and metamorphosed to metamorphic rocks; metamorphic rocks can melt again to start the cycle over.
Diagrammatic flow (conceptual)
Weathering and erosion transport material to depositional environments, where lithification forms sedimentary rocks.
Subduction and deep burial induce metamorphism; uplift exposes rocks to surface processes.
Heating and partial melting produce magma; magma crystallizes to form igneous rocks (intrusive or extrusive).
Take-home messages
Know what minerals are and the five defining characteristics.
Minerals are organized by properties that reflect differences in chemical composition and bonding.
Know the seven diagnostic properties used to identify minerals and the diagnostic properties of common minerals.
Understand the silicate tetrahedron and how it creates different silicate structures.
Recognize some common groups of minerals besides silicates.
Explain how one type of rock transforms into another through the rock cycle.
Connections and key reminders
The origin and evolution of the marine environment ties into mineral formation, silicate minerals, and the rock cycle through hydrothermal processes, sedimentation, and tectonic activity.
Crystal structure and bonding principles help explain mineral properties like hardness, cleavage, and color.
The four major rock types and the cycle provide a framework to understand landscape evolution and resource formation (e.g., ore deposits linked to hydrothermal activity).
Practical implications include resource exploration (ore deposits, fossil fuels in sedimentary sequences) and interpretation of geological records.
Quick reference formulas and constants
Earth crust elemental composition reference (approximate):
88 elements occur naturally in the crust, out of 118 identified.
The 8 most abundant elements make up about 98.59\% of the crust.
Silicate tetrahedron: ext{SiO}_4^{4-}
Rocks and processes are described in terms of common units (g/cm³ for density; hardness scales; etc.).
Example questions recap (from transcript)
Mineral definition questions and examples (ice, amber, magnetite relevance).
Bond strength question: covalent > ionic > metallic > van der Waals.
Density-based high-pressure inference: higher-density polymorphs often indicate high-pressure formation (e.g., aragonite vs calcite).
Crystal growth and cooling rate: slower cooling yields larger crystals (quartz on felsic magma).
Proven strategies for mineral identification using multiple diagnostic properties (e.g., calcite vs quartz test).