Lewis Dot Structure Notes
Lewis Dot Structures
Valence Electrons
- Valence electrons are the number of electrons in the outermost shell.
- The number of valence electrons for elements in a group is consistent (Helium is an exception).
- Group 1 elements have one valence electron.
- Group 2 elements have two valence electrons.
- Group 18 elements have eight valence electrons (except Helium, which has two).
- Metals usually do not participate in covalent bonds.
- Non-metals (in green) usually participate in covalent bonds.
Hydrogen (H₂)
- Hydrogen has one valence electron.
- Hydrogen needs one more electron to have a stable outermost shell, like helium (two electrons).
- Hydrogen shares its one valence electron.
- Two hydrogen atoms share their electrons to form a covalent bond.
- Lewis dot structure: H-H (a single line represents a bond between two electrons).
Oxygen (O₂)
- Oxygen has six valence electrons.
- Oxygen needs two more electrons to satisfy the octet rule (eight electrons in the outermost shell).
- Oxygen shares two electrons.
- Two oxygen atoms each with six valence electrons, share two electrons to form two bonds.
- Lewis dot structure includes showing lone pairs (non-bonding electrons).
- The final Lewis structure for O2 is O=O with two lone pairs on each oxygen atom.
Nitrogen (N₂)
- Nitrogen has five valence electrons.
- Nitrogen needs three more electrons to satisfy the octet rule.
- Nitrogen shares three electrons.
- Two nitrogen atoms, each with five valence electrons, share three electrons to form a triple bond.
- Final Lewis structure for N2 is N≡N, with one lone pair on each nitrogen.
Water (H₂O)
- Oxygen is the central atom because hydrogen is always on the side.
- Oxygen has six valence electrons and shares two.
- Each hydrogen has one valence electron and shares one.
- Final Lewis structure: Oxygen is bonded to two hydrogen atoms with two lone pairs on the oxygen atom.
Ammonia (NH₃)
- Nitrogen is the central atom (hydrogen is always on the side).
- Nitrogen has five valence electrons.
- Each hydrogen shares one electron to form a single bond with nitrogen.
- Lewis structure: Nitrogen is bonded to three hydrogen atoms, with one lone pair on the nitrogen atom.
Carbon Dioxide (CO₂)
- Carbon has four valence electrons and needs four more.
- Carbon is the central atom because it is the leftmost element on the periodic table compared to oxygen.
- Each oxygen atom needs to share two electrons.
- Carbon forms a double bond with each oxygen atom.
- Final Lewis structure: O=C=O, with two lone pairs on each oxygen atom.