Bio Ch 1
what is the relative size of atoms to other units of matter?
Smallest stable unit
what is the specificity of an atom?
Its charge correlates to its specific element
what are the 2 components of an atom’s structure?
Nucleus and orbitals
what is inside of an atom’s nucleus?
Protons and neutrons
what is the relative energy of the furthest orbital from the nucleus?
The furthest orbital has the most negative charge
what is in the furthest orbital from the nucleus
Valence electrons
what is the function of valence electrons?
Bind to the valence electrons of other atoms
why is 8 the magic number for valence electrons?
8 is the most valence electrons that can be in the valence orbital, and therefore the most amount of bonds that can be formed between atoms, and therefore makes for the most stable bond between atoms
What is an ion?
An atom that in unstable; has charge desu
Are ions stable?
nomeggies
What is a Cation?
positive
What is an anion?
negative
what are the 4 main elements of life?
Carbon, hydrogen, oxygen, nitrogen
what would happen without the main elements of life?
Life would not be able to survive cuz it wouldnt be able to produce anything
What makes carbon inorganic?
It is not naturally occurring but instead the product of a reaction
How is carbon produced?
Produced by photosynthesis by plants, released back into environment when animal dies
What is the function of carbon in terms of biomolecules?
Carbon is used to form bonds - has 4 valence electrons. Is therefore used to in EVERY BIOMOLECULE (carbs, proteins, lipids, nucleic acids)
What quality makes carbon so versatile in bonding?
Has 4 valence electrons
Should you look for “C” atoms in molecule structure?
Nomeggies, is implied desu
What makes nitrogen inorganic?
Not inherently in atmosphere
How is nitrogen produced?
Produced by DECOMPOSERS when an organism dies
What does nitrogen produce?
Nucleic acids, ALSO proteins
What does phosphorous produce?
Nucleic acids, PHOSPHOLIPIDS
Is phosphorous one of the 4 main elements of life?
no
What is electronegativity the measurement of?
How negative an element is, and therefore how much it attracts other electrons to it (valence electrons of other atoms)
What are the 2 important electronegative elements for biology?
Oxygen, nitrogen
What is electropositivity the measurement of?
Not how positive in charge an element, but how little electronegativity an element has, and therefore that elements ability to donate electrons to form anions of other elements
Are electropositive elements typically positive in charge?
No, still negative just less negative than others
What causes a covalent bond to form?
Just when 2 atoms share electrons
What happens to energy when a covalent bond is form?
Energy is stored
What happens to energy when a covalent bond is broken?
Energy is released
What causes an ionic bond to form?
Transfer of valence electrons from a metal to a non metal
Compared to covalent bonds, how strong are ionic bonds?
Relatively weak
What happens to ionic bonds in water?
They dissolve
Are ionic bonds common in biology?
no
What causes a molecule to be polar?
The unequal sharing of electrons across a covalent bond
Is a consequence of electronegativity when the element binding to the e. Neg element is either very small or very electropositive
Across what kind of bond does polarity occur?
Covalent bonds
What is polarity of a consequence of? (hint: is a consequence of a characteristic of a molecule)
electronegativity
So in total, what what kind of molecule binds what different kind of molecule to cause polarity?
Small molecules or electropositive molecules
What is the overall charge of a polar molecule?
neutral
What are the charges of the poles of a polar molecule?
Partially negative and partially positive
What does a partially negative element attract?
electrons
Therefore, is a partially negative element electronegative or electropositive?
negative
Are there many or few electrons surrounding a partially positive electron?
few
What are hydrogen bonds really?
Weak attractions
What 3 atoms can hydrogens bond together?
Oxygen, nitrogen, fluorine
Are hydrogens partially positive or negative?
POSITIVE
How does this partial charge of hydrogens allow hydrogen bonds to form?
Because O, N, and F are highly electronegative, and therefore partially POSITIVE hydrogens attract to them → remember that opposites attract here
If energy seems to have been lost in a reaction, what really happened to the energy?
It was given off as heat
Can a molecule lose atoms in a reaction?
nomeggies
How does water facilitate transport in the body?
It transports blood in animals, SAP in plants
What type of bonds is water made of? (think: H2O)
Hydrogen bonds
Is water polar or nonpolar? How does the structure of water prove this?
Polar, because it has a partial pos end of hydrogens and a partial neg end of oxygen
Can water form hydrogen bonds? If so, with what kinds of molecules can it bond with?
Yes, it forms h bonds w/ other polar molecules
What is cohesion?
When 2 water molecules bond to each other
What other water properties does cohesion allow for?
Capillary action, surface tension
What is adhesion?
When water sticks (attracts) to a molecule that is not water, like an object’s surface
What is an example of adhesion?
Water sticking to car window
What is capillary action?
When water is drawn up the roots of plants
What causes capillary action (2 answers, both needed)?
Cohesion and adhesion are both needed for water to “climb”
Where is capillary action used?
In the roots of plants
What is surface tension?
When water molecules attract to each other on the surface of a body of water
In surface tension, what water surface characteristic causes hydrogen bonds to strengthen?
cohesion
What characteristic of hydrogen bonds makes hydrogen bonds collectively strong on the surface of a body of water?
The constant breaking and reforming of hydrogen bonds allow for water to be resistant to breaking under the weight of light objects
What is high specific heat capacity?
The high temperature to which water can resist before changing in temperature
How do collective hydrogen bonds in water affect water’s heat resistance?
Because water molecules bind to each other and constantly break and reform, they are collectively strong → takes a lot of heat to break ALL of the bonds
What is temperature the measurement of?
The movement of molecules
What does it mean when a molecule has absorbed more heat, molecularly?
That the molecules are moving faster
What is high heat of vaporization?
That it takes a lot of heat to convert water into a gas
How do collective hydrogen bonds in water affect water evaporating?
Because water molecules bind together, it takes a lot of energy to convert all of them → collective strength
What is evaporation?
When water converts to a gas
What is evaporative cooling? (Think temperature-wise)
Temperature of water DECREASES when it converts to a gas
Why is ice less dense than water, in terms of hydrogen bond structure?
Because hydrogen bonds of ice dont move (form a lattice structure)
What is a solvent?
Something that dissolves substances
What makes water a good solvent of other molecules?
Because the hydrogen bonds overcome and replace ionic bonds, therefore breaking down and dissolving the bonds of that substance
Chemically, how does water break apart other molecules?
Replace ionic bonds with its own hydrogen bonds taht break asnd reform and repeat and therefore dissolve
What are the four main biomolecules?
Carbs, proteins, lipids, nu acids
What element of life are biomolecules made by (in part)?
carbon
Why is this element fit for biomolecules to be based with?
4 valence electrons - can form a lot of bonds
What are monomers?
Single subunit of a molecule
What are dimers?
Two bonded monomers
What are polymers?
Many monomers bonded together
What is biomolecular metabolism?
The breaking down and storing of biomolecules
What are the 2 functions of bio. Meta?
To store and release energy
What is a catabolic reaction?
release
What is an anabolic reaction?
store
How does hydrolysis occur?
Water is added to a substance to break it down
What kind of protein is required for hydrolysis to occur?
Enzymes add water into reaction of molecules
Is hydrolysis catabolic or anabolic?
catabolic
What is exogonic?
A reaction that involves a net release of energy
How does dehydration synthesis occur?
The removal of water from a substance, and therefore the bonding of molecules
What kind of protein is required for dehydration synthesis to occur?
Enzymes remove water
Is D.S/ catabolic or anabolic?
anabolic
What is endogonic?
A reaction involving the net investment of energy
What are the 4 macromolecules?
Carbs, proteins, lipids, nu acids
What are the monomers of carbohydrates?
monosaccharides
What are the bonds of carbohydrates?
Glycosidic bonds
Mono of lipids?
Fatty acids and glycerol
Bonds of lipids?
Ester bonds
Mono of proteins?
Amino acids
Bonds of proteins?
Peptide bonds
Mono of Nu Acid?
nucleotide
Bonds of Nu Acid?
Phosphodiester bonds
Monosaccharides make what biomolecule?
carbohydrates
What is the monosaccharide-specific name for bonds connecting monos? What type of bond is that?
Glycosidic bonds
What do multiple, bonded monosaccharides make up? (3 names, 1 already answered)
Carbohydrates, polysaccharides, complex sugars
How can we tell a molecule is a monosaccharide? (How as in its name)
ose
What is shape of a monosaccharide?
A carbon ring w/ oxygen and hydrogen
What 3 elements make a monosaccharide?
Carbon, oxygen, hydrogen
What is a hydronyl group?
hydrogen
What is a hydroxyl group?
Hydrogen and oxygen
At what element will glycosidic bonds meet?
oxygen
What are monosaccharides a major source of?
Cellular energy
Amino Acids make what biomolecule?
proteins
What is the structure of many, bonded amino acids? How are these structures unique?
They form long amino acid chains
What are the 3 components of an amino acid?
An amino group, a carboxyl group, and a unique R group
What elements make an amino group?
Nitrogen and hydrogen
What elements make up a carboxyl group?
Carbon, oxygen, hydrogen (carbon + a hydroxyl and hydronyl)
What kind of bond links amino acids in a protein?
Peptide bonds - is covalent
What is the function of an R group for a single amino acid?
It gives the amino acid its properties and unique characteristics
What are the possible characteristics of an R group?
Polar, nonpolar, negative, positive, uncharged, hydrophobic, hydrophilic
How does R group interactions contribute to a protein’s function?
The r groups of amino acids have unique interactions between their unique characteristics, making that protein unique by each of its interactions. One different amino acid means an entirely different protein. Therefore, these interactions make SPECIFIC STRUCTURE AND FUNCTION OF THE PROTEIN
Are lipids polar and hydrophilic, or are they nonpolar and hydrophobic?
Nonpolar and hydrophobic
What are the 3 types of lipids?
Fats, phospholipids, steroids
What monomers make lipids?
Fatty acids, glycerol
What bonds make lipids
Ester bonds
What is the structure of these combined monomers that make lipids?
They form long hydrocarbon chains
What makes a fatty acid saturated?
Its hydrocarbon chain is formed straight because the fatty acids only form SINGLE bonds with one another
What is the typical form of saturated fatty acids at room temperature? Why?
It is solid at room temperature because the straight structure makes the pack closer together
What makes a fatty acid unsaturated?
Chain bends because there is one more or more double bond between the fatty acids
What is the typical form of unsaturated fatty acids at room temperature? Why?
The bent structure makes them further apart, so they are liquid at room temperature
What type of lipid are triglycerides? (Triglycerides and this are synonymous)
fats
What is the structure of a triglyceride?
3 fatty acids + a glycerol acids
What determines whether a triglyceride is saturated or unsaturated?
The structure of the fatty acids it contains
What is the structure of a phospholipid?
Has a polar head and a nonpolar tail
What makes the tails of a phospholipid tail? What does this tell us about (insert previous answer)?
The hydrocarbon chain. This tells us that lipids and triglycerides are always nonpolar and hydrophobic
What monomers make up Nu. Acids?
nucleotides
What is the shape and structure of a Nucleotide?
Are made of a phosphate group (w/ hydroxyl group), a 5 carbon ring, and a nitrogenous base
What bonds make Nucleic acids?
Phosphodiester bonds that are covalent
What are the 4 nitrogenous bases?
Adenine, guanine, thymine, cytosine
What are the nitrogenous base pairings?
C to g, a to g
What are the 2 main Nucleic acids?
Dna and rna
What are the 3 components of a nucleotide?
P group, 5 carbon ring, nitrogen base
What links the 3 parts of a nucleotide?
Phosphodiester bonds
What makes nucleotides unique?
Their nitrogenous base
What is the function of a nucleotide?
Nucleotides store genetic material
What elements make up a nucleotide?
chonp
What is the shape of DNA (is this structure always)
Double helix
What polymers make up DNA? What monomers make up those polymers?
Nucleic acids
What bonds hold DNA together?
Phosphodiester bonds bind nucleotides to one another, hydrogen bonds join nitrogenous bases
How many carbons are in DNA?
5
How are the carbons of DNA numbered?
w/ directionality: from 5 prime to 1 prime
Where is and what is the function of the 5 prime?
The 5 prime is between the p group and the carbon ring, and bonds the carbon to the phosphate group
Where is and what is the function of the 3 prime?
The 3’ is at the hydroxyl group, and bonds to the p group of adjacent nucleotides
Where is and what is the function of the 1 prime?
Is at the carbon ring below the n base, bonding the ring to the base
What does it means that DNA is antiperallel?
That the double helix features one chain of nucleotides from 5’ to 1’, and an opposite, parallel chain from 1’ to 5’
What forms of the sugar backbone of a DNA strand?
The covalent bonds between nucleotides
What kind of bonds hold together the nitrogenous bases?
hydrogen
What kind of bonds hold together the nucleotides on the sugar backbone? What are these called for nucleotides, specifically?
Covalent - p.di.ester
What are the 2 base pairings?
A to T, C to G
What are the pyrimidines?
C, U, T
What are the purines?
A, G
Can a purine bind to a purine?
Nomeggies, purines bind to pyrimidines always
What is the the function of DNA?
Stores our genetic conde
What does “deoxyribose” refer to, chemically?
Sugar missing oxygen
Where is DNA made?
In the nucleus
Where is DNA made?
In the nucleus
Where is DNA found in Eukaryotes?
nucleus
Where is DNA found in Prokaryotes?
Cytoplasm floating around
What shape is DNA in Eukaryotes?
linear
What shape is DNA in Prokaryotes?
circular
What is the shape of RNA?
Single strand, not a double helix
What is the function of RNA?
Synthesizes proteins
What base does Uracil replace in RNA?
thymine
Where is RNA made?
In the nucleus
Were is RNA found?
cytoplasm
Which of the 4 elements of life breaks down into the most energy?
lipids
Which of the 4 elements of life break down into the same amount of energy?
Proteins and carbs
Which of the 4 elements of life break down into no energy?
Nu acids
What are the 3 functions of carbohydrates?
Store energy, form cell membrane, break down into energy
What are the 3 functions of lipids?
Store energy, form cell membrane, break down into energy
What are 3 functions of proteins?
Catalyze fractions, form cell membrane, break down into energy
What is the 1 function of Nucleic Acids?
Store genetic code for our traits → the acid is the code
What are proteins used for in cell functions?
everything
That makes the 20 amino acids different?
R groups
What elements are used to make all proteins?
chon
What binds together amino acids in proteins?
Peptide bonds
What is the shape of binded amino acids?
Amino group, carboxyl group, r group → form chains of a. acids
What is the polymer of amino acids?
proteins
What chemical process bonds amino acids?
dehydration synthesis forms peptide bonds
Between what components of two amino acids do bonds form?
Amino groups and carboxyl groups
Given the previous two questions, make an equation for peptide bonds.
Amino + carboxyl - water = bond
What does it mean that proteins have directionality?
Chains of amino acids start w/ N terminus and end w/ C terminus
What is the first amino acid called in an amino acid chain?
N terminus
What is the last amino acid called?
C terminus
Which amino acid component is vacant at the N-Terminus?
Amino group
Which amino acid component is vacant at the C-Terminus?
Carboxyl group
What is similar in all amino acids? (One structure and one molecule)
They all have the peptide backbone including the Amino group and carboxyl group, also all have a central carbon
What is different in all amino acids?
R group
What monomers make up polysaccharides?
monosaccharides
What bonds those monomers?
Glycosidic bonds
What is the structure of many of these bonded monomers?
Form chains that either linear or branches
What is a linear polysaccharide?
Straight line
What is the function of a linear polysaccharide?
Form structure of organism like cellulose in a plant
What is a branched polysaccharide?
The chain branches off from its side
What is the function of a branched polysaccharide?
Branched = stores energy
What are the 4 structures of a protein?
Primary, secondary, tertiary, quaternary
How do these structures determine the function of a protein?
Interactions of amino acids at these different levels dtermine the proteins function
What is the shape of a protein’s primary structure?
A chain of amino acids
What causes the primary structure of a protein?
The order of the amino acids
To what extent has a protein folded during primary structure?
Not at all
What monosaccharide component determines the protein’s folding at following structures?
The r group interactions of the the acids
What does the previous answer tell us about what molecular characteristics influence a protein’s folding?
Proteins form different shapes while folding due to the pulls of their characteristics such as polarity, charge, and interactions w/ water
What occurs during the secondary structure?
The protein begins to fold
Why does this occur?
Due to hydrogen bonding between amino acid backbones - the part w/o the R group
What kind of bonding occurs?
H bond
What is the amino acid backbone?
w/ no r group
What two kinds of folding occurs in secondary structure?
Alpha helixes and B sheets
What is the shape of a protein in tertiary structure?
Begins to fold in polypeptides
What causes tertiary structure to occur?
Interactions between alpha helixes and beta sheets
How does secondary structure proteins influence tertiary structure shape?
The different characteristics of the helixes and sheets due to the r groups that make up the acids bonding them determine how the protein begins forming in tertiary structure
To what extent are quaternary proteins functional?
They can be fully functional here
What is it called when environmental factors change the shape of a protein, and therefore disable it’s function?
denaturation
How the previous answer affecting R groups can be damaging to Tertiary structure proteins?
If the R groups can’t interact due to a change in environment and therefore lose function, the protein will lose function
What causes quaternary structure to occur?
Interactions between polypeptides
Can quaternary structure proteins denature like tertiary structure proteins can?
yes
Do all proteins reach quaternary structure?
no