Electron Microscopy and Probe Microscopy

Electron Microscopy Overview

  • Electron microscopy utilizes electrons instead of light to obtain high-resolution images of samples.

    • Very small wavelength of electrons allows for high resolution.

  • Electron microscopes do not use traditional glass lenses.

    • Instead, they use magnets (specifically electromagnets) to direct the electron beams.

  • Key Limitations:

    • Cannot examine live samples due to the vacuum environment necessary for operation, which is incompatible with living organisms.

Types of Electron Microscopy

  • There are two main types of electron microscopy:

    1. Scanning Electron Microscopy (SEM)

    • Provides three-dimensional images of the surface of samples.

    • Think of "scanning" as focusing on the surface.

    1. Transmission Electron Microscopy (TEM)

    • Offers images of the internal structure of samples.

    • Remember "transmission" as it transmits information into the inner workings of a cell.

  • Additional Category:

    • Probe Microscopy: Another category of microscopy that will be discussed in detail.

Probe Microscopy

  • Probe microscopy utilizes a probe that operates similarly to a record player’s needle, but with significantly greater precision.

    • Probes are typically made from tungsten.

    • The diameter of the probe tip is only one atom wide, allowing for extremely detailed imaging.

  • Two main types of probe microscopy are:

    1. Scanning Tunneling Microscope (STM)

    • Invented in 1980 by scientists who were awarded the Nobel Prize in 1986.

    • Capable of examining live samples as the probe does not touch the sample.

    • Mechanism: The tip of the probe does not physically contact the sample; rather, there is an exchange of electrons. The current generated from this interaction is measured by a computer, which converts it to create an image.

    • Key Takeaways:

      • STM is a probe microscope.

      • No contact with the sample, only electron exchange.

      • Current measurement enables image creation.

      • "Scanning" refers to examining the surface; "tunneling" refers to the electronic current.

    1. Atomic Force Microscope (AFM)

    • Developed by IBM scientists in 1982.

    • Unlike STM, the probe physically contacts the sample during examination.

    • Mechanism: The probe is attached to a cantilevered arm. As the probe moves across the uneven surface of the sample, it rises and falls with variations in height. A laser shines on the end of the cantilever, with the angles of reflection providing data to create an image.

    • Both STM and AFM rely significantly on computer technology for image processing and creation.

    • Note: You cannot distinguish between STM and AFM images based solely on appearance; examples will not be provided in exams.

    • Key Target Areas:

      • AFM shows physical contact with the sample, unlike STM.

Examples of Imaging with Probe Microscopy

  • The images produced via STM and AFM could depict atomic-level details:

    • E.g., Pure Gold Surface: shows gold atoms arranged in specific formations.

    • E.g., Nanosellulose: an artificially created substance viewed at the molecular level.

  • Additional images discussed in class may illustrate different atomic arrangements, but specific elements were not clearly defined.

Final Notes on Microscopy

  • Slides following the lecture will provide additional clarity on various types of light microscopes alongside the discussed electron microscopes.

    • One additional type, two-photon microscopy, was mentioned but is not required for the exam review.

    • Focus on the electron microscopy types and the distinctions made between STM and AFM as key concepts to grasp during study sessions.

  • Reiterate differences based on functionality, sample compatibility, and imaging technique between the various microscopies.