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Le Chatelier's Principle

  • A system will remain at equilibrium as long as rate of forward and reverse reaction are equal

  • A system will no longer be at equilibrium if a change in reaction conditions, or ‘stress’, unequally affects these rates

  • Le Chatelier’s principle states if a dynamic equilibrium is disturbed by a change in the reaction conditions, the balance between the forward and reverse processes will shift to counteract the change and return the system to equilibrium

Stress #1: Change in Concentration

  • you can increase/ decrease reactants

  • you can increase/ decrease products

In terms of concentration, the systems will build/destroy molecules until they are at equilibrium

If you…

the reaction will…

increase reactants

shift right/favour forward reaction o produce products

SM

Le Chatelier's Principle

  • A system will remain at equilibrium as long as rate of forward and reverse reaction are equal

  • A system will no longer be at equilibrium if a change in reaction conditions, or ‘stress’, unequally affects these rates

  • Le Chatelier’s principle states if a dynamic equilibrium is disturbed by a change in the reaction conditions, the balance between the forward and reverse processes will shift to counteract the change and return the system to equilibrium

Stress #1: Change in Concentration

  • you can increase/ decrease reactants

  • you can increase/ decrease products

In terms of concentration, the systems will build/destroy molecules until they are at equilibrium

If you…

the reaction will…

increase reactants

shift right/favour forward reaction o produce products

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