Redox Reactions
Oxidation Numbers
- Oxidation numbers, also known as oxidation states, are used to track electron transfer in chemical reactions.
- The overall charge of a neutral compound is zero.
- The oxidation number of an atom in its elemental form is zero. Examples include , , and .
Identifying Redox Reactions
- A redox reaction involves both reduction and oxidation processes.
- If the oxidation number of a substance increases, it is oxidized. The substance loses electrons.
- If the oxidation number of a substance decreases, it is reduced. The substance gains electrons.
- If the oxidation number of an element does not change during a reaction, it is neither oxidized nor reduced.
Oxidation
- Oxidation is the process where a substance loses electrons, resulting in an increase in its oxidation number.
- A substance being oxidized is a reducing agent because it causes another substance to be reduced.
Reduction
- Reduction is the process where a substance gains electrons, resulting in a decrease in its oxidation number.
- A substance being reduced is an oxidizing agent because it causes another substance to be oxidized.
Activity Series of Metals
- Metals higher in the activity series are more easily oxidized.
- Metals lower in the activity series are more easily reduced.
- The metal that needs to be oxidized must be higher in the series than the metal being reduced.
- The reading on a voltmeter will be lower than , but higher than .
Examples and Equations
- Example: is reduced, and something else (Mnt) is oxidized. gains
- is an example of reduction. is being reduced.
- Oxidation number:
- The total number of electrons lost must equal the total number of electrons gained in all redox reactions.
- Number of electrons lost = Number of electrons gained.
- Number of electrons for element oxidized = number of electrons for element reduced.
Atom Examples
- Is an atom present? Examples: