Definition: Ionic bonds are formed by attractions between oppositely charged ions (cations and anions).
Cations: Atoms with a positive charge.
Anions: Atoms with a negative charge.
Real-World Example: Sodium chloride (NaCl), commonly known as table salt, is formed through ionic bonding.
Comparison with Covalent Bonds
Covalent Bonds: Involve shared electrons between atoms, forming molecules with no overall charge.
Molecules: Groups of atoms bonded together; for example, water (H2O) illustrates covalent bonding with lines representing shared electron pairs.
Molecular Elements
Definition: Some elements exist as diatomic or polyatomic molecules rather than individual atoms.
Examples:
Hydrogen (H2): Exists as a diatomic molecule.
Oxygen (O2): Elemental form of oxygen.
Halogens: Fluorine (F2), Chlorine (Cl2), Bromine (Br2), and Iodine (I2) are also diatomic molecules.
Nitrogen (N2): Most abundant gas in the atmosphere.
Covalent vs. Ionic Solids
Ionic Solids: Composed of ions held together by ionic bonds.
Characteristics: Solid at room temperature, possess a defined crystal structure due to the regular arrangement of ions.
Example: Sodium chloride forms a crystalline structure where each sodium ion (Na+) is surrounded by chloride ions (Cl-), and vice versa, leading to a stable arrangement maximizing ionic attractions.
Stability of Ions
Sodium (Na+): The most stable ion of sodium in the s or p blocks is Na+.
Chlorine (Cl-): The most stable ion of chlorine is Cl- (gains one electron to achieve a full octet).
Structure of Sodium Chloride
Crystal Formation: In salt, sodium ions are surrounded by six chloride ions, packing together in a structured array; each chloride ion is also surrounded by sodium ions.
Subscripts in Formulas: Reflect the simplest ratio of ions. In NaCl, both ions are present in a 1:1 ratio, so the formula has no subscripts.
Recap and Quiz
Make sure to memorize:
The key features of ionic bonds.
The difference between covalent bonds and ionic compounds.
The list of molecular elements.
Example Question: Why are sodium cations (Na+) attracted to chloride anions (Cl-)?