Topic 4 Atomic Structure - AQA Physics GCSE
Atomic Structure:
Positively charged nucleus surrounded by negatively charged electrons.
Subatomic particles:
Proton: Relative mass = 1, Relative charge = +1.
Neutron: Relative mass = 1, Relative charge = 0.
Electron: Relative mass = 0 (0.0005), Relative charge = -1.
Typical radius of an atom: 1 × 10−10 metres.
Radius of the nucleus is 10,000 times smaller.
Most of the mass of the atom is concentrated at the nucleus.
Electron Arrangement:
Electrons lie at different distances from the nucleus (different energy levels).
Electron arrangements may change with the interaction with EM radiation.
Isotopes and Elements:
All atoms of the same element have the same number of protons.
Neutral atoms have the same number of electrons and protons.
Isotopes are atoms of the same element with different masses.
Isotopes have the same number of protons but different number of neutrons.
Example: Carbon-12, Carbon-13, and Carbon-14.
How and why the atomic model has changed over time:
1800: Dalton proposed that everything was made of tiny spheres (atoms) that could not be divided.
1897: JJ Thomson discovered the electron, leading to the Plum Pudding Model.
1911: Rutherford realized most of the atom was empty space through the Gold Foil Experiment.
1913: Rutherford Model with a positive nucleus at the center and negative electrons in a cloud around it.
1913: Bohr produced the final model of the atom.
Positive charge of the nucleus could be subdivided into smaller particles called protons.
James Chadwick provided evidence for the existence of neutrons.
Some atomic nuclei are unstable and give out radiation as they change to become more stable.
Radioactive decay is a random process.
Activity is the rate at which a source of unstable nuclei decays, measured in Becquerel (Bq).
Count-rate is the number of decays recorded by a detector per second.
Forms of decay: Alpha (α), Beta Minus (β), Gamma (γ), Neutrons.
Nuclear equations are used to represent radioactive decay.
Electrons exist in fixed 'orbitals' to prevent the collapse of the atom.
Emission of different types of nuclear radiation may cause a change in the mass and/or charge of the nucleus.
Alpha Decay: Decreases both the mass and charge of the nucleus.
Beta Decay: Does not change the mass but increases the charge of the nucleus.
Gamma Decay: Does not cause a change in mass or charge.
Half-Life:
The time taken for half the nuclei in a sample to decay or for the activity/count rate to decay by half.
It cannot be predicted when any one nucleus will decay.
Short half-life: Less long-term risk, quickly becomes less radioactive.
Long half-life: Remains weakly radioactive for a long period of time.
Example: Americium has a half-life of 432 years, used in smoke alarms.
The number of atoms over time tends to 0.
Calculate the ratio of net decline of radioactive nuclei after X half-lives
Half the initial number of nuclei, and keep doing so X number of times
Formula: 𝐍𝐍𝐞𝐞𝐞 𝐃𝐃𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞 = 𝐢𝐢 𝐧𝐧𝐧𝐧𝐧𝐧 𝐧𝐧 − 𝐧𝐧𝐧𝐧𝐧𝐧 𝐧𝐧 𝐚𝐚 𝐗𝐗 𝐡𝐡 𝐥𝐥 𝐥𝐥 𝐢𝐢 𝐧𝐧𝐧𝐧𝐧𝐧 𝐧𝐧
Lasts for a long period of time
The source of the radiation is transferred to an object
Unwanted presence of radioactive atoms on other materials
Hazard is the decaying of the contaminated atoms releasing radiation
Example: radioactive dust settling on your skin (your skin becomes contaminated)
Lasts only for a short period of time
The source emits radiation, which reaches the object
Exposing an object to nuclear radiation, but does not make it radioactive
Example: radioactive dust emitting beta radiation, which "irradiates" your skin
Medical items are irradiated sometimes to kill bacteria on its surface, but not to make the medical tools themselves radioactive
Peer review is essential for studies on the effects of radiation on humans
Incorrect measurements in initial studies can lead to safety levels that may cause harm
Weak radiation that can be detected from natural/external sources
Sources include cosmic rays, radiation from underground rocks, nuclear fallout, and medical rays
Occupation and location can affect the level of background radiation and radiation dose
Measurement of Radiation Dose: Sieverts (Sv)
Uses of Radiation: Tracers
Technetium is used as a medical tracer
It has a half-life of 6 hours and decays into a safe isotope that can be excreted by the body
It is injected/swallowed and can flow through the body and be detected before it decays away
It is a gamma emitter, so it can pass through body tissue without being absorbed
Gamma emitters are used to emit gamma rays onto certain areas of the body with cancerous cells
Gamma rays are absorbed by the cancerous cells, causing them to die and controlling the disease
It is also used to control other unwanted tissue
Surrounding healthy cells may also be irradiated, causing unhealthy side effects
Nuclear fission is the splitting of a large and unstable nucleus (e.g., uranium or plutonium)
Spontaneous fission is rare, usually requires the absorption of a neutron by the unstable nucleus
The unstable nucleus splits into two smaller nuclei, emitting two or three neutrons and gamma rays
Energy is released by the fission reaction
This neutron may collide with another radioactive nucleus, causing it to split and release more energy
This chain reaction can increase at an exponential rate if not controlled, as in a nuclear weapon
Uranium nuclei are used in nuclear fission
Two small nuclei fuse to form a heavier nucleus, releasing a large amount of energy
The sum of the masses of the two nuclei is more than the mass of the heavier nucleus
Some of the mass is converted into energy, released as radiation
The sun is a natural fusion reactor
Fusion is a more efficient way of producing energy compared to fission, but no design has achieved
Atomic Structure:
Positively charged nucleus surrounded by negatively charged electrons.
Subatomic particles:
Proton: Relative mass = 1, Relative charge = +1.
Neutron: Relative mass = 1, Relative charge = 0.
Electron: Relative mass = 0 (0.0005), Relative charge = -1.
Typical radius of an atom: 1 × 10−10 metres.
Radius of the nucleus is 10,000 times smaller.
Most of the mass of the atom is concentrated at the nucleus.
Electron Arrangement:
Electrons lie at different distances from the nucleus (different energy levels).
Electron arrangements may change with the interaction with EM radiation.
Isotopes and Elements:
All atoms of the same element have the same number of protons.
Neutral atoms have the same number of electrons and protons.
Isotopes are atoms of the same element with different masses.
Isotopes have the same number of protons but different number of neutrons.
Example: Carbon-12, Carbon-13, and Carbon-14.
How and why the atomic model has changed over time:
1800: Dalton proposed that everything was made of tiny spheres (atoms) that could not be divided.
1897: JJ Thomson discovered the electron, leading to the Plum Pudding Model.
1911: Rutherford realized most of the atom was empty space through the Gold Foil Experiment.
1913: Rutherford Model with a positive nucleus at the center and negative electrons in a cloud around it.
1913: Bohr produced the final model of the atom.
Positive charge of the nucleus could be subdivided into smaller particles called protons.
James Chadwick provided evidence for the existence of neutrons.
Some atomic nuclei are unstable and give out radiation as they change to become more stable.
Radioactive decay is a random process.
Activity is the rate at which a source of unstable nuclei decays, measured in Becquerel (Bq).
Count-rate is the number of decays recorded by a detector per second.
Forms of decay: Alpha (α), Beta Minus (β), Gamma (γ), Neutrons.
Nuclear equations are used to represent radioactive decay.
Electrons exist in fixed 'orbitals' to prevent the collapse of the atom.
Emission of different types of nuclear radiation may cause a change in the mass and/or charge of the nucleus.
Alpha Decay: Decreases both the mass and charge of the nucleus.
Beta Decay: Does not change the mass but increases the charge of the nucleus.
Gamma Decay: Does not cause a change in mass or charge.
Half-Life:
The time taken for half the nuclei in a sample to decay or for the activity/count rate to decay by half.
It cannot be predicted when any one nucleus will decay.
Short half-life: Less long-term risk, quickly becomes less radioactive.
Long half-life: Remains weakly radioactive for a long period of time.
Example: Americium has a half-life of 432 years, used in smoke alarms.
The number of atoms over time tends to 0.
Calculate the ratio of net decline of radioactive nuclei after X half-lives
Half the initial number of nuclei, and keep doing so X number of times
Formula: 𝐍𝐍𝐞𝐞𝐞 𝐃𝐃𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞𝐞 = 𝐢𝐢 𝐧𝐧𝐧𝐧𝐧𝐧 𝐧𝐧 − 𝐧𝐧𝐧𝐧𝐧𝐧 𝐧𝐧 𝐚𝐚 𝐗𝐗 𝐡𝐡 𝐥𝐥 𝐥𝐥 𝐢𝐢 𝐧𝐧𝐧𝐧𝐧𝐧 𝐧𝐧
Lasts for a long period of time
The source of the radiation is transferred to an object
Unwanted presence of radioactive atoms on other materials
Hazard is the decaying of the contaminated atoms releasing radiation
Example: radioactive dust settling on your skin (your skin becomes contaminated)
Lasts only for a short period of time
The source emits radiation, which reaches the object
Exposing an object to nuclear radiation, but does not make it radioactive
Example: radioactive dust emitting beta radiation, which "irradiates" your skin
Medical items are irradiated sometimes to kill bacteria on its surface, but not to make the medical tools themselves radioactive
Peer review is essential for studies on the effects of radiation on humans
Incorrect measurements in initial studies can lead to safety levels that may cause harm
Weak radiation that can be detected from natural/external sources
Sources include cosmic rays, radiation from underground rocks, nuclear fallout, and medical rays
Occupation and location can affect the level of background radiation and radiation dose
Measurement of Radiation Dose: Sieverts (Sv)
Uses of Radiation: Tracers
Technetium is used as a medical tracer
It has a half-life of 6 hours and decays into a safe isotope that can be excreted by the body
It is injected/swallowed and can flow through the body and be detected before it decays away
It is a gamma emitter, so it can pass through body tissue without being absorbed
Gamma emitters are used to emit gamma rays onto certain areas of the body with cancerous cells
Gamma rays are absorbed by the cancerous cells, causing them to die and controlling the disease
It is also used to control other unwanted tissue
Surrounding healthy cells may also be irradiated, causing unhealthy side effects
Nuclear fission is the splitting of a large and unstable nucleus (e.g., uranium or plutonium)
Spontaneous fission is rare, usually requires the absorption of a neutron by the unstable nucleus
The unstable nucleus splits into two smaller nuclei, emitting two or three neutrons and gamma rays
Energy is released by the fission reaction
This neutron may collide with another radioactive nucleus, causing it to split and release more energy
This chain reaction can increase at an exponential rate if not controlled, as in a nuclear weapon
Uranium nuclei are used in nuclear fission
Two small nuclei fuse to form a heavier nucleus, releasing a large amount of energy
The sum of the masses of the two nuclei is more than the mass of the heavier nucleus
Some of the mass is converted into energy, released as radiation
The sun is a natural fusion reactor
Fusion is a more efficient way of producing energy compared to fission, but no design has achieved